HZB paper appears in special anniversary edition of the Journal of Physics D: Applied Physics


<p></p>
<p>One example from the paper: <em>operando</em> radiography (A)- (C) shows how sulphur compounds (black features) are deposited on the carbon cathode (gray) of a lithium-sulphur cell during charging and discharging.

One example from the paper: operando radiography (A)- (C) shows how sulphur compounds (black features) are deposited on the carbon cathode (gray) of a lithium-sulphur cell during charging and discharging. © HZB

A paper on X-ray tomography of various types of batteries has been published as a highlight in the exclusive special edition of the Journal of Physics D: Applied Physics. Two groups at the HZB along with a team from Justus Liebig University in Giessen, Germany, contributed to the article.

“We selected this article for inclusion because of its novelty, scientific impact, and broadness of appeal”, writes Executive Editor Tom Miller. The work has now been additionally published in a special issue (Synchrotron- and FEL-based X-ray Methods for Battery Studies) celebrating the journal’s 50-year history. The contribution really demonstrates that X-ray tomography is applicable in many ways and promises a substantial leap in knowledge for research on various types of batteries.

X-ray computer tomography combines X-ray images with three-dimensional methods of representation. It shows what processes within the interior of materials take place. Transport processes and chemical reactions in novel battery systems can be investigated in this way. These processes have been insufficiently understood thus far, which is why it is difficult to achieve specific improvements.

The researchers not only present in the article the utility of X-ray tomography for research on batteries in general, they also present numerous concrete examples illustrating the power of tomographic representation. These examples include zinc-air batteries, sodium-air batteries, and metal-sulphur batteries. They show what processes limit the storage capacity of each battery type and why performance falls with the number of charging cycles.

The article title: “In operando x-ray tomography for next-generation batteries: a systematic approach to monitor reaction product distribution and transport processes”.

D. Schroder, C. L. Bender, T. Arlt, M. Osenberg, A. Hilger, S. Risse, M. Ballauff, I. Manke and J. Janek

 

Published September 9, 2016

http://iopscience.iop.org/article/10.1088/0022-3727/49/40/404001?fromSearchPage=true

DOI

https://doi.org/10.1088/0022-3727/49/40/404001

arö


You might also be interested in

  • BESSY II: How pulsed charging enhances the service time of batteries
    Science Highlight
    08.04.2024
    BESSY II: How pulsed charging enhances the service time of batteries
    An improved charging protocol might help lithium-ion batteries to last much longer. Charging with a high-frequency pulsed current reduces ageing effects, an international team demonstrated. The study was led by Philipp Adelhelm (HZB and Humboldt University) in collaboration with teams from the Technical University of Berlin and Aalborg University in Denmark. Experiments at the X-ray source BESSY II were particularly revealing.
  • Fuel Cells: Oxidation processes of phosphoric acid revealed by tender X-rays
    Science Highlight
    03.04.2024
    Fuel Cells: Oxidation processes of phosphoric acid revealed by tender X-rays
    The interactions between phosphoric acid and the platinum catalyst in high-temperature PEM fuel cells are more complex than previously assumed. Experiments at BESSY II with tender X-rays have decoded the multiple oxidation processes at the platinum-electrolyte interface. The results indicate that variations in humidity can influence some of these processes in order to increase the lifetime and efficiency of fuel cells. 
  • Best Innovator Award 2023 for Artem Musiienko
    News
    22.03.2024
    Best Innovator Award 2023 for Artem Musiienko
    Dr. Artem Musiienko has been awarded a special prize for his groundbreaking new method for characterising semiconductors. At the recent annual conference of the Marie Curie Alumni Association (MCAA) in Milan, Italy, he received the MCAA Award for the best innovation. Since 2023, Musiienko has been carrying out his research project with a postdoctoral fellowship from the Marie Sklodowska Curie Actions in Antonio Abate's department, Novel Materials and Interfaces for Photovoltaic Solar Cells (SE-AMIP).