HZB Newsroom

Inorganic perovskite solar cells made of CsPbI₃ are stable over the long term and achieve good efficiencies. A team led by Prof. Antonio Abate has now analysed surfaces and interfaces of CsPbI₃ films, produced under different conditions, at BESSY II. The results show that annealing in ambient air does not have an adverse effect on the optoelectronic properties of the semiconductor film, but actually results in fewer defects. This could further simplify the mass production of inorganic perovskite solar cells.

A team at HZB has investigated a new, simple method at BESSY II that can be used to create stable radial magnetic vortices in magnetic thin films.

An improved charging protocol might help lithium-ion batteries to last much longer. Charging with a high-frequency pulsed current reduces ageing effects, an international team demonstrated. The study was led by Philipp Adelhelm (HZB and Humboldt University) in collaboration with teams from the Technical University of Berlin and Aalborg University in Denmark. Experiments at the X-ray source BESSY II were particularly revealing.

The interactions between phosphoric acid and the platinum catalyst in high-temperature PEM fuel cells are more complex than previously assumed. Experiments at BESSY II with tender X-rays have decoded the multiple oxidation processes at the platinum-electrolyte interface. The results indicate that variations in humidity can influence some of these processes in order to increase the lifetime and efficiency of fuel cells. 

The travelling salesman problem is considered a prime example of a combinatorial optimisation problem. Now a Berlin team led by theoretical physicist Prof. Dr. Jens Eisert of Freie Universität Berlin and HZB has shown that a certain class of such problems can actually be solved better and much faster with quantum computers than with conventional methods.

At the end of February 2024, a team at HZB published an article in Synchrotron Radiation News (SRN). They describe the next development goals for the light source as well as the BESSY II+ upgrade programme and the successor source BESSY III.

Hafnium oxide thin films are a fascinating class of materials with robust ferroelectric properties in the nanometre range. While their ferroelectric behaviour is extensively studied, results on piezoelectric effects have so far remained mysterious. A new study now shows that the piezoelectricity in ferroelectric Hf_0.5Zr_0.5O₂ thin films can be dynamically changed by electric field cycling. Another ground-breaking result is a possible occurrence of an intrinsic non-piezoelectric ferroelectric compound. These unconventional features in hafnia offer new options for use in microelectronics and information technology.

An HZB physicist has developed a new method for the comprehensive characterisation of semiconductors in a single measurement. The "Constant Light-Induced Magneto-Transport (CLIMAT)" is based on the Hall effect and allows to record 14 different parameters of transport properties of negative and positive charge carriers. The method was tested now on twelve different semiconductor materials and will save valuable time in assessing new materials for optoelectronic applications such as solar cells.

Sodium-ion batteries still have a number of weaknesses that could be remedied by optimising the battery materials. One possibility is to dope the cathode material with foreign elements. A team from HZB and Humboldt-Universität zu Berlin has now investigated the effects of doping with Scandium and Magnesium. The scientists collected data at the X-ray sources BESSY II, PETRA III, and SOLARIS to get a complete picture and uncovered two competing mechanisms that determine the stability of the cathodes.

Carboxylic acid dianions (fumarate, maleate and succinate) play a role in coordination chemistry and to some extent also in the biochemistry of body cells. An HZB team at BESSY II has now analysed their electronic structures using RIXS in combination with DFT simulations. The results provide information not only on electronic structures but also on the relative stability of these molecules which can influence an industry's choice of carboxylate dianions, optimizing both the stability and geometry of coordination polymers.

High-entropy alloys can withstand extreme heat and stress, making them suitable for a variety of specific applications. A new study at the X-ray synchrotron radiation source BESSY II has now provided deeper insights into the ordering processes and diffusion phenomena in these materials. The study involved teams from HZB, the Federal Institute for Materials Research and Testing, the University of Latvia and the University of Münster.

A team at HZB has developed a new measurement method that, for the first time, accurately detects tiny temperature differences in the range of 100 microkelvin in the thermal Hall effect. Previously, these temperature differences could not be measured quantitatively due to thermal noise. Using the well-known terbium titanate as an example, the team demonstrated that the method delivers highly reliable results. The thermal Hall effect provides information about coherent multi-particle states in quantum materials, based on their interaction with lattice vibrations (phonons).

The production of green hydrogen requires catalysts that control the process of splitting water into oxygen and hydrogen. However, the structure of the catalyst changes under electrical tension, which also influences the catalytic activity. A team from the universities of Duisburg-Essen and Twente has investigated at BESSY II and elsewhere how the transformation of surfaces in perovskite oxide catalysts controls the activity of the oxygen evolution reaction. 

Anodes for the electrolytic splitting of water are usually iridium-based materials. In order to increase the stability of the iridium catalyst, a team at HZB and a group at HI-ERN have now produced a so-called material library: a sample in which the concentration of iridium and titanium oxides is systematically varied. Analyses of the individual sample segments at BESSY II in the EMIL laboratory showed that the presence of titanium oxides can increase the stability of the iridium catalyst significantly.

The Highlights 2022 report on a selection of the most important research results and events at HZB.

Molybdenum disulphide (MoS₂) is a highly versatile material that can function, for example, as a gas sensor or as a photocatalyst in green hydrogen production. Although the understanding of a material usually starts from investigating its bulk crystalline form, for MoS₂ much more studies have been devoted to mono and few layer nanosheets. The few studies conducted thus far show diverse and irreproducible results for the electronic properties of cleaved bulk MoS₂ surfaces, highlighting the need for a more systematic study.

It sounds like magic: photoelectrodes could convert the greenhouse gas CO₂ back into methanol or N2 molecules into valuable fertiliser – using only the energy of sunlight. An HZB study has now shown that diamond materials are in principle suitable for such photoelectrodes. By combining X-ray spectroscopic techniques at BESSY II with other measurement methods, Tristan Petit’s team has succeeded for the first time in precisely tracking which processes are excited by light as well as the crucial role of the surface of the diamond materials.

Freeze casting processes can be used to produce highly porous and hierarchically structured materials that have a large surface area. They are suitable for a wide variety of applications, as electrodes for batteries, catalyst materials or in biomedicine. A team led by Prof. Ulrike G. K. Wegst, Northeastern University, Boston, MA, USA and Dr. Francisco García Moreno from the Helmholtz-Zentrum Berlin have used the newly developed X-ray tomoscopy technique. At the Swiss Light Source of the Paul Scherrer Institute they observed in real time and at high resolution how the process of structure formation takes place during freezing. A sugar solution served as the model system.

With increasing size and complexity, quantum computers become a sort of black box. Using methods from mathematical physics, a team has now succeeded in deriving concrete numbers from random, data sequences that can serve as a benchmark for the performance of a quantum computer system. Experts from Helmholtz-Zentrum Berlin, Freie Universität Berlin, Qusoft Research Centre Amsterdam, the University of Copenhagen and the Technology Innovation Institute Abu Dhabi were involved in the work, which has now been published in Nature Communications.

Magnetic skyrmions are tiny vortices of magnetic spin textures. In principle, materials with skyrmions could be used as spintronic devices, for example as very fast and energy-efficient data storage devices. But at the moment it is still difficult to control and manipulate skyrmions at room temperature. A new study at BESSY II analyses the formation of skyrmions in ferrimagnetic thin films of dysprosium and cobalt in real time and with high spatial resolution. This is an important step towards characterising suitable materials with skyrmions more precisely in the future.

In a special issue on the liquid jet method, a team reports on reactions of water molecules on the surfaces of metal oxide particles. The results are relevant for the development of efficient photoelectrodes for the production of green hydrogen.

X-ray microscopy (cryo-SXT) enables high-resolution insights into cells and cell organelles - in three dimensions. Until now, the 3D data sets have been analysed manually, which is very time-consuming. A team from Freie Universität Berlin has now developed a self-learning algorithm based on a convolutional neural network. In collaboration with experts in cell biology (FU Berlin) and X-ray microscopy at the Helmholtz Zentrum Berlin, this algorithm has now been used for the first time to analyse cell components in cryo-SXT data sets. It identified cell organelles and produced highly detailed, complex 3D images within a few minutes.

In theory, metal oxides are ideally suited as photoelectrodes for the direct generation of hydrogen with sunlight. Now, for the first time, a team at Helmholtz-Zentrum Berlin has succeeded in determining the transport properties of the charge carriers in different metal oxides over a time range of nine orders of magnitude.

The world's best tandem solar cells, consisting of a silicon bottom cell and a perovskite top cell, can today convert around one-third of incident solar radiation into electrical energy. These are record values, especially for a potentially very low-cost technology. A team at HZB is now providing the scientific data for the first time and describing how this development was achieved in the renowned journal Science. 

Photoelectrolysers and electrolysis cells can produce green hydrogen or fossil-free carbon compounds – but they require ion-exchange membranes. An HZB team has now studied the transport of ions through the membrane in a hybrid liquid gas electrolyzer at the X-ray source BESSY II. Contrary to expectations, however, concentration differences hardly drive electric field ions. Diffusion is therefore the decisive process. This finding could help in the development of highly efficient and significantly more environmentally friendly membrane materials.

Magnetic domains walls are known to be a source of electrical resistance due to the difficulty for transport electron spins to follow their magnetic texture. This phenomenon holds potential for utilization in spintronic devices, where the electrical resistance can vary based on the presence or absence of a domain wall. A particularly intriguing class of materials are half metals such as La_2/3Sr_1/3MnO₃ (LSMO) which present full spin polarization, allowing their exploitation in spintronic devices. Still the resistance of a single domain wall in half metals remained unknown. Now a team from Spain, France and Germany has generated a single domain wall on a LSMO nanowire and measured resistance changes 20 times larger than for a normal ferromagnet such as Cobalt.

A new quasiparticle with interesting properties has appeared in solid-state physics - but so far only in the theoretical modelling of solids with certain magnetic properties. An international team from HZB and Freie Universität Berlin has now shown that, contrary to expectations, quantum fluctuations do not make the quasiparticle appear more clearly, but rather blur its signature.

Researchers have discovered a Lifshitz-transition in TiC, driven by a graphene overlayer, at the photon source BESSY II. Their study sheds light on the exciting potential of 2D materials such as graphene and the effects they can have on neighboring materials through proximity interactions.

In April, Dr. Jie Wei started his research work in the Helmholtz Young Investigator Group Nanoscale Operando CO₂ Photo-Electrocatalysis at Helmholtz-Zentrum Berlin (HZB) and Fritz Haber Institute (FHI) of the Max Planck Society. Wei received one of the highly competitive Humboldt postdoctoral research fellowships and will pursue his two-year project under the guidance of the academic hosts Dr. Christopher Kley and Prof. Dr. Beatriz Roldan Cuenya.

The greenhouse gas carbon dioxide can be converted into useful hydrocarbons by electrolysis. The design of the electrolysis cell is crucial in this process. The so-called zero-gap cell is particularly suitable for industrial processes. But there are still problems: The cathodes clog up quickly. At the HZB, Matthew Mayer and his team has now investigated what causes this and how this undesirable process can be prevented.

Lighter, more flexible and adaptable – the innovation platform Solar TAP develops innovative solutions for photovoltaic applications. The aim is to make surfaces already used in agriculture, the building sector and transport additionally usable for the expansion of solar energy with printed solar cells.

Cocoa beans can absorb toxic heavy metals such as cadmium from the soil. Some cultivation areas, especially in South America, are polluted with these heavy metals, in some cases considerably. In combining different X-ray fluorescence techniques, a team at BESSY II has now been able to non-invasively measure for the first time where cadmium accumulates exactly in cocoa beans: Mainly in the shell. Further investigations show that the processing of the cocoa beans can have a great influence on the concentration of heavy metals.

Solid-state Lithium-Sulfur batteries offer the potential for much higher energy densities and increased safety, compared to conventional lithium-ion batteries. However, the performance of solid-state batteries is currently lacking, with slow charging and discharging being one of the primary causes. Now, a new study from HZB shows that sluggish lithium ion transport within a composite cathode is the cause of this slow charging and discharging.

Sunlight can be used to produce green hydrogen directly from water in photoelectrochemical (PEC) cells. So far, systems based on this "direct approach" have not been energetically competitive. However, the balance changes as soon as some of the hydrogen in such PEC cells is used in-situ for a catalytic hydrogenation reaction, resulting in the co-production of chemicals used in the chemical and pharmaceutical industries. The energy payback time of photoelectrochemical "green" hydrogen production can be reduced dramatically, the study shows.

Solar cells made from metal halide perovskites achieve high efficiencies and their production from liquid inks requires only a small amount of energy. A team led by Prof. Dr. Eva Unger at Helmholtz-Zentrum Berlin is investigating the production process. At the X-ray source BESSY II, the group has analyzed the optimal composition of precursor inks for the production of high-quality FAPbI₃ perovskite thin films by slot-die coating. The solar cells produced with these inks were tested under real life conditions in the field for a year and scaled up to mini-module size.

MXenes are able to store large amounts of electrical energy like batteries and to charge and discharge rather quickly like a supercapacitor. They combine both talents and thus are a very interesting class of materials for energy storage. The material is structured like a kind of puff pastry, with the MXene layers separated by thin water films. A team at HZB has now investigated how protons migrate in the water films confined between the layers of the material and enable charge transport. Their results have been published in the renowned journal Nature Communications and may accelerate the optimisation of these kinds of energy storage materials.

A further development in atomic force microscopy now makes it possible to simultaneously image the height profile of nanometre-fine structures as well as the electric current and the frictional force at solid-liquid interfaces. A team from the Helmholtz-Zentrum Berlin (HZB) and the Fritz Haber Institute (FHI) of the Max Planck Society has succeeded in analysing electrocatalytically active materials and gaining insights that will help optimise catalysts. The method is also potentially suitable for studying processes on battery electrodes, in photocatalysis or on active biomaterials.

A team led by Dr. Prashanth W. Menezes (HZB/TU-Berlin) has now gained insights into the chemistry of one of the most active anode catalysts for green hydrogen production. They examined a series of Cobalt-Iron Oxyhydroxides at BESSY II and were able to determine the oxidation states of the active elements in different configurations as well as to unveil the geometrical structure of the active sites. Their results might contribute to the knowledge based design of new highly efficient and low cost catalytical active materials.

Perovskite semiconductors promise highly efficient and low-cost solar cells. However, the semi-organic material is very sensitive to temperature differences, which can quickly lead to fatigue damage in normal outdoor use. Adding a dipolar polymer compound to the precursor perovskite solution helps to counteract this. This has now been shown in a study published in the journal Science by an international team led by Antonio Abate, HZB. The solar cells produced in this way achieve efficiencies of well above 24 %, which hardly drop under rapid temperature fluctuations between -60 and +80 Celsius over one hundred cycles. That corresponds to about one year of outdoor use.

Water not only has some well-known anomalies, but is still full of surprises. The first issue 2023 of the Bunsen Magazine is dedicated to molecular water research, from the ocean to processes in electrolysis. The issue presents contributions from researchers cooperating within the framework of a European research initiative in the "Centre for Molecular Water Science" (CMWS). A team at HZB presents results from the synchrotron spectroscopy of water. Modern X-ray sources can be used to study molecular and electronic processes in water in detail.

Experimental data is often not only highly dimensional, but also noisy and full of artefacts. This makes it difficult to interpret the data. Now a team at HZB has designed software that uses self-learning neural networks to compress the data in a smart way and reconstruct a low-noise version in the next step. This enables to recognise correlations that would otherwise not be discernible. The software has now been successfully used in photon diagnostics at the FLASH free electron laser at DESY. But it is suitable for very different applications in science.

The current world record of tandem solar cells consisting of a silicon bottom cell and a perovskite top cell is once again at HZB. The new tandem solar cell converts 32.5 % of the incident solar radiation into electrical energy. The certifying institute European Solar Test Installation (ESTI) in Italy measured the tandem cell and officially confirmed this value which is also included in the NREL chart of solar cell technologies, maintained by the National Renewable Energy Lab, USA.

Nanodiamond materials have potential as low-cost photocatalysts. But until now, such carbon nanoparticles required high-energy UV light to become active. The DIACAT consortium has therefore produced and analysed variations of nanodiamond materials. The work shows: If the surface of the nanoparticles is occupied by sufficient hydrogen atoms, even the weaker energy of blue sunlight is sufficient for excitation. Future photocatalysts based on nanodiamonds might be able to convert CO₂ or N₂ into hydrocarbons or ammonia with sunlight.

Until now, it has been extremely tedious to perform measurements with high sensitivity and high spatial resolution using X-ray light in the tender energy range of 1.5 - 5.0 keV. Yet this X-ray light is ideal for investigating energy materials such as batteries or catalysts, but also biological systems. A team from HZB has now solved this problem: The newly developed monochromator optics increase the photon flux in the tender energy range by a factor of 100 and thus enable highly precise measurements of nanostructured systems. The method was successfully tested for the first time on catalytically active nanoparticles and microchips.

Solid-state batteries enable even higher energy densities than lithium-ion batteries with high safety. A team led by Prof. Philipp Adelhelm and Dr. Ingo Manke succeeded in observing a solid-state battery during charging and discharging and creating high-resolution 3D images. This showed that cracking can be effectively reduced through higher pressure.

Quantum computers promise significantly shorter computing times for complex problems. But there are still only a few quantum computers worldwide with a limited number of so-called qubits. However, quantum computer algorithms can already run on conventional servers that simulate a quantum computer. A team at HZB has succeeded to calculate the electron orbitals and their dynamic development on the example of a small molecule after a laser pulse excitation. In principle, the method is also suitable for investigating larger molecules that cannot be calculated using conventional methods.

Photoelectrodes based on BiVO₄ are considered top candidates for solar hydrogen production. But what exactly happens when they come into contact with water molecules? A study in the Journal of the American Chemical Society has now partially answered this crucial question:  Excess electrons from dopants or defects aid the dissociation of water which in turn stabilizes so-called polarons at the surface. This is shown by data from experiments conducted at the Advanced Light Source at Lawrence Berkeley National Laboratory. These insights might foster a knowledge-based design of better photoanodes for green hydrogen production.

Tandem solar cells, which combine two different perovskite semiconductors, promise high efficiencies and can be produced with very little energy input. Such modules could even be bendable. Together with partners from industry and research, HZB expert Prof. Steve Albrecht is working to realise this vision. His team recently succeeded in producing an all-perovskite tandem solar cell with a certified efficiency of 27.2 %. A conversation about the opportunities and challenges of the perovskite-perovskite technology.

The market for rechargeable batteries is growing rapidly, but the necessary raw materials are limited. Sodium-ion batteries, for example, could offer an alternative. A joint research group from HZB and Humboldt-Universität zu Berlin has investigated new combinations of electrolyte solutions and electrode materials for this purpose.

By the end of 2021, teams at HZB had presented perovskite silicon tandem solar cells with an efficiency close to 30 percent. This value was a world record for eight months, a long time for this hotly contested field of research. In the renowned journal Nature Nanotechnology, the scientists describe how they achieved this record value with nanooptical structuring and reflective coatings.

Information on complex magnetic structures is crucial to understand and develop spintronic materials. Now, a new instrument named ALICE II is available at BESSY II. It allows magnetic X-ray scattering in reciprocal space using a new large area detector. A team at HZB and Technical University Munich has demonstrated the performance of ALICE II by analysing helical and conical magnetic states of an archetypal single crystal skyrmion host. ALICE II is now available for guest users at BESSY II.

High-entropy alloys (HEAs) are promising materials for catalysis and energy storage, and at the same time they are extremely hard, heat resistant and demonstrate great variability in their magnetic behaviour. Now, a team at BESSY II in collaboration with Ruhr University Bochum, BAM, Freie Universität Berlin and University of Latvia has gained new insights into the local environment of a so-called high-entropy Cantor alloy made of chromium, manganese, iron, cobalt and nickel, and has thus also been able to partially explain the magnetic properties of a nanocrystalline film of this alloy.

In order to produce green hydrogen, water can be split up via electrocatalysis, powered by renewable sources such as sun or wind. A review article in the journal Angewandte Chemie Int. Ed. shows how modern X-ray sources such as BESSY II can advance the development of suitable electrocatalysts. In particular, X-ray absorption spectroscopy can be used to determine the active states of catalytically active materials for the oxygen evolution reaction. This is an important contribution to developing efficient catalysts from inexpensive and widely available elements.

Transition metals have many applications in engineering, electrochemistry and catalysis. To understand their properties, the interplay between atomic localisation and delocalisation of the outer electrons in the d orbitals is crucial. This insight is now provided by a special end station at BESSY II with highest precision, as demonstrated by a study of copper, nickel and cobalt with interesting quantitative results. The Royal Society of Chemistry has selected the paper as a HOT Article 2022.

Graphene is an extremely exciting material. Now a graphene variant shows another talent: rhombohedral graphite made of several layers slightly offset from each other could enlighten the hidden physics in quantum magnets.

The transition metal dichalcogenide (TMD) series are a family of promising candidate materials for spintronics. A study at lightsource BESSY II has unveiled that in one of those materials even simple linear polarised light is sufficient to selectively manipulate spins of different orientations. This result provides an entirely new route for the generation of spin-polarised currents and is a milestone for the development of spintronic and opto-spintronic devices.

C₆₀ molecules on a gold substrate appear more complex than their graphene counterparts, but have much more ordinary electronic properties. This is now shown by measurements with ARPES at BESSY II and detailed calculations.

Oxidation states of transition metals describe how many electrons of an element are already engaged in bonding, and how many are still available for further reactions. Scientists from Berlin and Freiburg have now discovered the highest oxidation state of rhodium, indicating that rhodium can involve more of its valence electrons in chemical bonding than previously thought. This finding might be relevant for the understanding of catalytic reactions involving highly-oxidized rhodium. The result was recognized as a „very important paper“ in Angewandte Chemie.

Liquids are more difficult to describe than gases or crystalline solids. An HZB team has now mapped the potential energy surfaces of water molecules in liquid water under ambient conditions for the first time at the Swiss Light Source SLS of the Paul Scherrer Institute, Switzerland. This contributes to a better understanding of the chemistry of water and in aqueous solutions. These investigations can soon be continued at the newly built METRIXS station at the X-ray source BESSY II.

Germanium telluride is a strong candidate for use in functional spintronic devices due to its giant Rashba-effect. Now, scientists at HZB have discovered another intriguing phenomenon in GeTe by studying the electronic response to thermal excitation of the samples. To their surprise, the subsequent relaxation proceeded fundamentally different to that of conventional semimetals. By delicately controlling the fine details of the underlying electronic structure, new functionalities of this class of materials could be conceived. 

High-entropy alloys of 3d metals have intriguing properties that are interesting for applications in the energy sector. An international team at BESSY II has now investigated the local order on an atomic scale in a so-called high-entropy Cantor alloy of chromium, manganese, iron, cobalt and nickel. The results from combined spectroscopic studies and statistical simulations expand the understanding of this group of materials.

With conventional methods, it is extremely time-consuming to calculate the spectral fingerprint of larger molecules. But this is a prerequisite for correctly interpreting experimentally obtained data. Now, a team at HZB has achieved very good results in significantly less time using self-learning graphical neural networks.

Teams from Helmholtz-Zentrum Berlin (HZB) and University College London (UCL) have visualised the water distribution in a fuel cell in three dimensions and in real time for the first time by evaluating neutron data from the Berlin Experimental Reactor shut down in 2019. The analysis opens new possibilities for more efficient and thus more cost-effective fuel cells.

New energy-efficient IT components often only operate stably at extremely low temperatures. Therefore, very good thermal insulation of such elements is crucial, which requires the development of materials with extremely low thermal conductivity. A team at HZB has now used a novel sintering process to produce nanoporous silicon aluminium samples in which pores and nanocrystallites impede the transport of heat and thus drastically reduce thermal conductivity. The researchers have developed a model for predicting the thermal conductivity, which was confirmed using experimental data on the microstructure of the samples and their thermal conductivity. Thus, for the first time, a method is available for the targeted development of complex porous materials with ultra-low thermal conductivity.

Magnetic nanostructures are promising tools for medical applications.  Incorporated into biological structures, they can be steered via external magnetic fields inside the body to release drugs or to destroy cancer cells. However, until now, only average information on the magnetic properties of those nanoparticles could be obtained, thus limiting their successful implementations in therapies. Now a team at HZB conceived and tested a new method to assess the characteristic parameters of every single magnetic nanoparticle.

The HZB Institute for Electronic Structure Dynamics, newly founded on 1 May, develops experimental techniques and infrastructures to investigate the dynamics of elementary microscopic processes in novel material systems. This will help to optimise functional materials for sustainable technologies.

A team at the EPR4Energy joint lab of HZB and MPI CEC has developed a new THz EPR spectroscopy method to study the catalytic activation of molecular oxygen by copper complexes. The method allows insights into previously inaccessible spin-spin interactions and the function of novel catalytic and magnetic materials.

In order to explain the particularly favourable properties of perovskite semiconductors for solar cells, various hypotheses are circulating. Polarons or a giant Rashba effect, for example, are thought to play a major role. A team at BESSY II has now experimentally disproved these hypotheses. In doing so, they further narrow down the possible causes for the transport properties and enable better approaches for the targeted optimisation of this class of materials.

Producing low-cost metal-oxide thin films with high electronic quality for solar water splitting is not an easy task. Especially since quality improvements of the upper metal oxide thin films need thermal processing at high temperatures, which would melt the underlying glass substrate. Now, a team at HZB-Institute for Solar Fuels has solved this dilemma: A high intensity and rapid light pulse directly heats the semiconducting metal-oxide thin film, allowing to achieve the optimal heating conditions without damaging the substrate.

A team at HZB has developed a method of experimentally unravelling tautomeric mixtures. Based on resonant inelastic X-ray scattering (RIXS) at BESSY II, not only proportions of the tautomers can be deduced, but the properties of each individual tautomer can be studied selectively. This method could yield to detailed information on the properties of molecules and their biological function. In the present study, now advertised on the cover of “The Journal of Physical Chemistry Letters” the technique was applied to the prototypical keto-enol equilibrium.

Collaborative Research projects as “Sonderforschungsbereiche” funded by Deutsche Forschungsgemeinschaft enable universities to build up their own research capacities. In the Transregio Sonderforschungsbereich 227 Ultrafast Spin Dynamic, the Freie Universität Berlin and the University in Halle-Wittenberg have also included HZB as a partner. The slicing facility of BESSY II plays a central role in this collaboration. With excellent results from the first phase, the Transregio-SFB 227 has completed its first interim review and is now preparing for the challenges ahead. A conversation with the two HZB physicists Niko Pontius and Christian Schüßler-Langeheine about the importance of such funding programmes for the research field.

Many semiconducting materials are possible candidates for solar cells. In recent years, perovskite semiconductors in particular have attracted attention, as they are both inexpensive and easy to process and enable high efficiencies. Now a study with 15 participating research institutions shows how terahertz (TRTS) and microwave spectroscopy (TRMC) can be used to reliably determine the mobility and lifetime of the charge carriers in new semiconducting materials. Using these measurement data it is possible to predict the potential efficiency of the solar cell in advance and to classify the losses in the finished cell.  

So-called PERC cells are used in mass production of silicon solar cells, they are considered the workhorses of photovoltaics, dominating the market. Now two teams from HZB and the Institute for Solar Energy Research in Hamelin (ISFH) have shown that such standard silicon cells are also suitable as a basis for tandem cells with perovskite top cells. Currently, the efficiency of the tandem cell is still below that of optimised PERC cells alone, but could be increased to up to 29.5% through targeted optimisation. The research was funded by the German Federal Ministry of Economics as part of a joint project.

Lithium-sulphur (Li/S) batteries have significantly higher energy densities than conventional lithium-ion batteries, but age very quickly. Now, for the first time, a team at HZB has investigated Li/S batteries in the industry-relevant pouch cell format with different electrolytes during operation. Teams from TU Dresden and the Fraunhofer IWS were also involved in the study. With a specially developed measuring cell, impedance, temperature and pressure can be recorded at different times and combined with radiographic images. The evaluation shows how the electrolyte affects the formation of unwanted sulphur particles and polysulphides. The study has been published in the renowned journal Advanced Energy Materials.

Highly efficient (electro-)catalysts are essential for the production of green hydrogen, the chemical industry, fertiliser production and other sectors of the economy. In addition to transition metals, a variety of other metallic or non-metallic elements have now moved into the focus of research. In a review article, experts from CatLab and Technische Universität Berlin present an overview on current knowledge and a perspective on future research questions.

Turning a scientific question into a product is the requirement that the winners of the HZB Technology Transfer Prize should fulfil. The team led by Tobias Henschel, Bernd Stannowski and Sebastian Neubert won more than just a prize.

Researchers from Innovation Lab HySPRINT at Helmholtz-Zentrum Berlin (HZB) and Humboldt Universität zu Berlin (HU) have used an advanced inkjet printing technique to produce a large range of photodetector devices based on a hybrid perovskite semiconductor. By mixing of only three inks, the researchers were able to precisely tune the semiconductor properties during the printing process. Inkjet printing is already an established fabrication method in industry, allowing fast and cheap solution processing. Extending the inkjet capabilities from large area coating towards combinatorial material synthesis opens the door for new possibilities for the fabrication of different kind of electronic components in a single printing step.

An international team of experts has collected data on metal halide perovskite solar cells from more than 15,000 publications and developed a database with visualisation options and analysis tools. The database is open source and provides an overview of the rapidly growing knowledge as well as the open questions in this exciting class of materials. The study was initiated by HZB scientist Dr. Eva Unger and implemented and coordinated by her postdoc Jesper Jacobsson.

Superconducting coupling between two regions separated by a one micron wide ferromagnetic compound has been proved by an international team. This macroscopic quantum effect, known as Josephson effect, generates an electrical current within the ferromagnetic compound made of superconducting Cooper-pairs. Magnetic imaging of the ferromagnetic region at BESSY II has contributed to demonstrate that the spin of the electrons forming the Cooper pairs are equal. These results pave the way for low-power consumption superconducting spintronic-applications where spin-polarized currents can be protected by quantum coherence.

Using data from the British neutron source ISIS from the year 2000, research teams have now demonstrated the viability of a “quantum entanglement witness” capable of proving the presence of entanglement between magnetic particles, or spins, in a quantum material. A team from HZB led by Prof. Bella Lake was also involved in the analysis.

Three HZB teams led by Prof. Christiane Becker, Prof. Bernd Stannowski and Prof. Steve Albrecht have jointly managed to increase the efficiency of perovskite silicon tandem solar cells fabricated completely at HZB to a new record value of 29.80 %. The value has now been officially certified and is documented in the NREL-charts. This brings the 30 percent mark within reach.

Dr. Antonio Abate investigates perovskite semiconductors for low-cost and highly efficient solar cells and heads a large research group at the Helmholtz Centre Berlin. Now he has accepted a W2 professorship in the Department of Chemistry at Bielefeld University.

An international team has detected at HZB's vector magnet facility VEKMAG an unusual ferromagnetic property in a two-dimensional system, known as “easy-plane anisotropy”. This could foster new energy efficient information technologies based on spintronics for data storage, among other things. The team has published its results in the renowned journal Science.

Magnetic solids can be demagnetized quickly with a short laser pulse, and there are already so-called HAMR (Heat Assisted Magnetic Recording) memories on the market that function according to this principle. However, the microscopic mechanisms of ultrafast demagnetization remain unclear. Now, a team at HZB has developed a new method at BESSY II to quantify one of these mechanisms and applied it to the rare-earth element Gadolinium, whose magnetic properties are caused by electrons on both the 4f and the 5d shells. This study is completing a series of experiments done by the team on Nickel, Iron-Nickel Alloys. Understanding these mechanisms is useful for developing ultrafast data storage devices.

Annette Pietzsch has many jobs: the physicist develops instruments for BESSY II that researchers can use to observe how molecules interact with each other. She mostly prefers to use the instruments to do her own research. This is what brought her from Sweden to HZB ten years ago.

An international team at HZB and Charles University Prague has investigated how charge carriers in so called MAPI-perovskite semiconductors interact with different defects. They show that a large proportion of defects quickly releases trapped charge carriers. These results could help to further improve the properties of perovskite solar cells.

What happens to ferroelectric materials when their dimensions are greatly reduced? A team of researchers at HZB has now been able to show how this question can be answered in a detailed way.

For decades, particle accelerators have been getting bigger and bigger. In the meantime, ring accelerators with circumferences of many kilometres have reached a practical limit. Linear accelerators in the GHz range also require very long construction lengths. For some years now, however, an alternative is explored: "tabletop particle accelerators" based on the laser excitation of charge waves in plasmas (laser wakefield). Such compact particle accelerators would be particularly interesting for future accelerator-driven light sources, but are also being investigated for high-energy physics. A team from Helmholtz-Zentrum Berlin (HZB) and the Physikalisch-Technische Bundesanstalt (PTB) has developed a method to precisely measure the cross-section of electron bunches accelerated in this way.  This brings applications of these new accelerator technologies for medicine and research closer.

Tomoscopy is an imaging method in which three-dimensional images of the inside of materials are calculated in rapid succession. Now a team led by HZB physicist Francisco García Moreno has achieved a new world record at the TOMCAT beamline of the Swiss Light Source at the Paul Scherrer Institute: with 1000 tomograms per second, it is now possible to non-destructively document very fast processes and developments in materials on the micrometre scale, such as the burning of a sparkler or the foaming of a metal alloy for the production of stable lightweight materials. 

Interfaces in semiconductor components or solar cells play a crucial role for functionality. Nevertheless, until now it has often been difficult to investigate adjacent thin films separately using spectroscopic methods. An HZB team at BESSY II has combined two different spectroscopic methods and used a model system to demonstrate how well they can be distinguished.

Quantum effects are most noticeable at extremely low temperatures, which limits their usefulness for technical applications. Thin films of MnSb₂Te₄, however, show new talents due to a small excess of manganese. Apparently, the resulting disorder provides spectacular properties: The material proves to be a topological insulator and is ferromagnetic up to comparatively high temperatures of 50 Kelvin, measurements at BESSY II show.  This makes this class of material suitable for quantum bits, but also for spintronics in general or applications in high-precision metrology.

Tiny formations inside lithium batteries can severely limit the operating life of an energy storage device. A research team at the Helmholtz-Zentrum Berlin (HZB) has now investigated the process behind these formations in greater detail. Their results provide anchor points for the future development of longer-lasting and safer lithium batteries.

Synchrotron light sources provide brilliant light with a focus on the X-ray region and have enormously expanded the possibilities for characterising materials. In the Reviews of Modern Physics, an international team now gives an overview of elastic and inelastic X-ray scattering processes, explains the theoretical background and sheds light on what insights these methods provide in physics, chemistry as well as bio- and energy related themes.

Crystalline cobalt arsenide is a catalyst that generates oxygen during electrolytic water splitting in the production of hydrogen. The material is considered to be a model system for an important group of catalysts whose performance increases under certain conditions in the course of electrolysis. Now a HZB-team headed by Marcel Risch has observed at BESSY II how two simultaneous mechanisms are responsible for this. The catalytic activity of the individual catalysis centres decreases in the course of electrolysis, but at the same time the morphology of the catalyst layer also changes. Under favourable conditions, considerably more catalysis centres come into contact with the electrolyte as a result, so that the overall performance of the catalyst increases.

An international team has observed an amazing phenomenon in a nickel oxide material during cooling: Instead of freezing, certain fluctuations actually increase as the temperature drops. Nickel oxide is a model system that is structurally similar to high-temperature superconductors. The experiment shows once again that the behaviour of this class of materials still holds surprises.

Under normal conditions, pure water is an almost perfect insulator. Water only develops metallic properties under extreme pressure, such as exists deep inside of large planets. Now, an international collaboration has used a completely different approach to produce metallic water and documented the phase transition at BESSY II. The study is published now in Nature.

Tin halide perovskites are currently considered the best alternative to their lead-containing counterparts, which are, however, still significantly less efficient and stable. Now, a team led by Prof. Antonio Abate from HZB has analysed the chemical processes in the perovskite precursor solution and the fluoride compounds in detail. Using a clever combination of measurement methods at BESSY II and with NMR at the Humboldt-University Berlin, they were able to show that fluoride prevents the oxidation of tin and leads to a more homogeneous film formation with fewer defects, increasing the quality of the semiconductor layer.

A team led by HZB physicist Dr. Jaime Sánchez-Barriga has gained new insights into the ultrafast response of topological states of matter to femtosecond laser excitation. Using time- and spin-resolved methods at BESSY II, the physicists explored how, after optical excitation, the complex interplay in the behavior of excited electrons in the bulk and on the surface results in unusual spin dynamics. The work is an important step on the way to spintronic devices based on topological materials for ultrafast information processing.

A team from the Helmholtz-Zentrum Berlin, Ulm University, and Heidelberg University has now investigated how hydrogen can be produced at the South Pole using sunlight, and which method is the most promising. Their conclusion: in extremely cold regions, it can be considerably more efficient to attach the PV modules directly to the electrolyser, i.e. to thermally couple them. This is because the waste heat from the PV modules increases the efficiency of electrolysis in this environment. The results of this study, which has now been published in Energy & Environmental Science, are also relevant for other cold regions on Earth, such as Alaska, Canada, and high mountain regions, for example. In these places, solar hydrogen could replace fossil fuels such as oil and petrol.

Information by the German Committee Research with Synchrotron Radiation (KFS).

Synchrotron light sources were originally built to study particles. Today, they are even used in the fight against COVID-19. The projects are as diverse as the fields of the synchrotron users, who come from universities, research institutions and companies like BioNTech.

Using small-angle scattering at the PTB X-ray beamline of BESSY II, an HZB team was able to experimentally investigate the colloidal chemistry of perovskite precursor solutions used for solar cell production. The results contribute to the targeted and systematic optimization of the manufacturing process and quality of these exciting semiconductor materials.

A group at HZB has worked out theoretically how the communication between two quantum dots can be influenced with light.  The team led by Annika Bande also shows ways to control the transfer of information or energy from one quantum dot to another. To this end, the researchers calculated the electronic structure of two nanocrystals, which act as quantum dots. With the results, the movement of electrons in quantum dots can be simulated in real time.

From June 2021, Dr. Renske van der Veen is setting up a new research group at HZB. The chemist is an expert in time-resolved X-ray spectroscopy and electron microscopy and studies catalytic processes that enable the conversion of solar energy into chemical energy.

The evaluation of X-ray measurements on methylammonium perovskite semiconductors now shows what role hydrogen bonds play in these materials. In addition, the HZB team showed that radiation damage by soft X-rays to this sensitive class of materials occurs even faster than often expected. Both results provide important information for perovskites materials research for solar cells.

Battery electrodes, storage devices for gases, and some catalyst materials have tiny functional pores that can accommodate atoms, ions, and molecules. How these guest atoms are absorbed into or released from the pores is crucial to understanding the porous materials' functionality. However, usually these processes can only be observed indirectly. A team from the Helmholtz Zentrum Berlin (HZB) has employed two experimental approaches using the ASAXS instrument at the PTB X-ray beamline of the HZB BESSY II synchrotron to directly observe the adsorption process of atoms in a mesoporous model system. The work lays the foundations for new insights into these kinds of energy materials.

Metal oxides such as rust are intriguing photoelectrode materials for the production of green hydrogen with sunlight. They are cheap and abundant, but in spite of decades of research, progress has been limited. A team at HZB, together with partners from Ben Gurion University and the Technion, Israel, has now analysed the optoelectronic properties of rust (haematite) and other metal oxides in unprecedented detail. Their results show that the maximum achievable efficiency of haematite electrodes is significantly lower than previously assumed. The study demonstrates ways to assess new photoelectrode materials more realistically.

At DESY's high-brilliance X-ray light source PETRA III, a team from more than 30 research institutions has identified several candidates for active substances against the coronavirus SARS-CoV-2. They bind to an important protein of the virus and could thus be the basis for a drug against Covid-19. The MX team from HZB examined part of the measurement data with special analysis algorithms in order to identify suitable active substances. The study has now been published in the renowned journal Science.

In photovoltaics, organic-inorganic hybrid perovskites have made a rapid career. But many questions about the crystalline structure of this surprisingly complex class of materials remain unanswered. Now, a team at HZB has used four-dimensional modelling to interpret structural data of methylammonium lead bromide (MAPbBr₃), identifying incommensurable superstructures and modulations of the predominant structure. The study is published in the ACS Journal of Physical Chemistry Letters and was selected by the editors as an Editor's Choice.

Solar cells made of crystalline silicon achieve peak efficiencies, especially in combination with selective contacts made of amorphous silicon (a-Si:H). However, their efficiency is limited by losses in these contact layers. Now, for the first time, a team at Helmholtz-Zentrum Berlin (HZB) and the University of Utah, USA, has experimentally shown how such contact layers generate loss currents on the nanometre scale and what their physical origin is. Using a conductive atomic force microscope, they scanned the solar cell surfaces in ultra-high vacuum and detected tiny, nanometre-sized channels for the detrimental dark currents, which are due to disorder in the a-Si:H layer.

Thin films of molybdenum and sulfur belong to a class of materials that can be considered for use as photocatalysts. Inexpensive catalysts such as these are needed to produce hydrogen as a fuel using solar energy. However, they are still not very efficient as catalysts. A new instrument at the Helmholtz-Berlin Zentrum’s BESSY II now shows how a light pulse alters the surface properties of the thin film and activates the material as a catalyst.

An international team has shown through a sensational experiment how diverse the possibilities for employing synchrotron light sources are. Accelerator experts from the Helmholtz-Zentrum Berlin (HZB), the German federal metrology institute Physikalisch-Technische Bundesanstalt (PTB), and Tsinghua University in Beijing have used a laser to manipulate electron bunches at PTB's Metrology Light Source so that they emitted intense light pulses having a laser-like character. Using this method, specialised synchrotron radiation sources would potentially be able to fill a gap in the arsenal of available light sources and offer a prototype for industrial applications. The work was published on 24 February 2021 in the leading scientific publication Nature.

A long-cherished dream of materials researchers is a solar cell that converts sunlight into electrical energy as efficiently as silicon, but that can be easily and inexpensively fabricated from abundant materials. Scientists at the Helmholtz-Zentrum Berlin have now come a step closer to achieving this. They have improved a process for vertically depositing a solution made from an inexpensive perovskite solute onto a moving substrate below. Not only have they discovered the crucial role played by one of the solvents used, but they have also taken a closer look at the aging and storage properties of the solution.

The electronic structure of complex molecules and their chemical reactivity can be assessed by the method of resonant inelastic X-ray scattering (RIXS) at BESSY II. However, the evaluation of RIXS data has so far required very long computing times. A team at BESSY II has now developed a new simulation method that greatly accelerates this evaluation. The results can even be calculated during the experiment. Guest users could use the procedure like a black box.

Photoanodes made of metal oxides are considered to be a viable solution for the production of hydrogen with sunlight. α-SnWO₄ has optimal electronic properties for photoelectrochemical water splitting with sunlight, but corrodes easily. Protective layers of nickel oxide prevent corrosion, but reduce the photovoltage and limit the efficiency. Now a team at HZB has investigated at BESSY II what happens at the interface between the photoanode and the protective layer. Combined with theoretical methods, the measurement data reveal the presence of an oxide layer that impairs the efficiency of the photoanode.

In synchrotron light sources, an electron accelerator brings electron bunches to almost the speed of light so that they can emit the special "synchrotron light". The electron bunches get their enormous energy and their special shape from a standing electromagnetic alternating field in so-called cavities. With high electron currents, as required in the bERLinPro project, the power needed for the stable excitation of this high-frequency alternating field is enormous. The coupling of this high power is achieved with special antennas, so-called couplers, and is considered a great scientific and technical challenge. Now, a first measurement campaign with optimised couplers at bERLinPro shows that the goal can be achieved.

An HZB team has published a report in the journal Science on the development of its current world record of 29.15% efficiency for a tandem solar cell made of perovskite and silicon. The tandem cell provided stable performance for 300 hours – even without encapsulation. To accomplish this, the group headed by Prof. Steve Albrecht investigated physical processes at the interfaces to improve the transport of the charge carriers.

For the production of high-quality metal-halide perovskite thin-films for large area photovoltaic modules often optimized inks are used which contain a mixture of solvents. An HZB team at BESSY II has now analysed the crystallisation processes within such mixtures. A model has also been developed to assess the kinetics of the crystallisation processes for different solvent mixtures. The results are of high importance for the further development of perovskite inks for industrial-scale deposition processes of these semiconductors.

Scientists at HZB have printed and explored different compositions of caesium based halide perovskites (CsPb(Br_xI_1−x)₃ (0 ≤ x ≤ 1)). In a temperature range between room temperature and 300 Celsius, they observe structural phase transitions influencing the electronic properties. The study provides a quick and easy method to assess new compositions of perovskite materials in order to identify candidates for applications in thin film solar cells and optoelectronic devices.

For the first time, a team at HZB has identified the atomic substructure of amorphous silicon with a resolution of 0.8 nanometres using X-ray and neutron scattering at BESSY II and BER II. Such a-Si:H thin films have been used for decades in solar cells, TFT displays, and detectors. The results show that three different phases form within the amorphous matrix, which dramatically influences the quality and lifetime of the semiconductor layer. The study was selected for the cover of the actual issue of Physical Review Letters.

A joint research group led by Prof. Jens Eisert of Freie Universität Berlin and Helmholtz-Zentrum Berlin (HZB) has shown a way to simulate the quantum physical properties of complex solid state systems. This is done with the help of complex solid state systems that can be studied experimentally. The study was published in the renowned journal Proceedings of the National Academy of Sciences of the United States of America (PNAS).

As part of an international collaboration, a team at the HZB has examined the corrosion processes of high-quality BiVO₄ photoelectrodes using different state-of-the-art characterisation methods. The result is the first operando stability study of high-purity BiVO₄ photoanodes during the photoelectrochemical oxygen evolution reaction (OER). This work shows how the stability of photoelectrodes and catalysts can be compared and enhanced in the future.

A team from Helmholtz-Zentrum Berlin (HZB) used cryo electron microscopy to detect regular, two-dimensional structures in the form of Pascal triangles in a shock frozen protein material.  The samples have been synthesized by a Chinese research group. The method of cryo electron microscopy has the potential for new insights into energy materials as well.

Solar cells based on hybrid halide perovskites achieve high efficiencies. These mixed organic-inorganic semiconductors are usually produced as thin films of microcrystals. An investigation with the Laue camera at the neutron source BER II could now clarify that twinning occurs during crystallisation even at room temperature. This insight is helpful for optimising production processes of halide perovskites. 

The region of the spectrum that can be utilised for producing electrical energy can be considerably extended by converting low-energy (longer wavelength) photons into high-energy (shorter wavelength) photons. But so far, this has only been possible at high intensities of light. Now for the first time, scientists from the Helmholtz-Zentrum Berlin (HZB) and the Federal Institute for Materials Research and Testing (BAM) have been able to produce a usable effect from relatively weak light by combining certain nanoparticles with what is known as a meta-surface. This paves the way for future applications in photovoltaics, for the detection of biological substances, and for electrical-field sensors.

Researchers at the Technische Universität Berlin (TUB) have created a new family of semiconductors, the properties of which were investigated by the Helmholtz-Zentrum Berlin (HZB). The researchers christened the first member “TUB75”. The material belongs to the class called metal-organic frameworks, or MOFs for short, and could open up new opportunities for energy storage. The work was published in Advanced Materials.

Many quantum materials have been nearly impossible to simulate mathematically because the computing time required is too long. Now a joint research group at Freie Universität Berlin and the Helmholtz-Zentrum Berlin (HZB) has demonstrated a way to considerably reduce the computing time. This could accelerate the development of materials for energy-efficient IT technologies of the future.

Using silicon as a material for electrodes in lithium-ion batteries promises a significant increase in battery amp-hour capacity.The shortcoming of this material is that it is easily damaged by the stress caused by charging and discharging.Scientists at the Helmholtz-Zentrum Berlin für Materialien und Energie (HZB) have now succeeded for the first time in observing this process directly on crystalline silicon electrodes in detail.Operando experiments using the BESSY II synchrotronprovided new insights into how fractures occur in silicon – and also how the material can nevertheless be utilised advantageously.

In order to accelerate the systematic development of drugs, the MX team at the Helmholtz-Zentrum Berlin (HZB) and the Drug Design Group at the University of Marburg have established a new substance library. It consists of 1103 organic molecules that could be used as building blocks for new drugs. The MX team has now validated this library in collaboration with the FragMAX group at MAX IV. The substance library of the HZB is available for research worldwide and also plays a role in the search for substances active against SARS-CoV-2.

The latest generation of magnetic hard drives is made of magnetic thin films, which are invar materials. They allow extremely robust and high data storage density by local heating of ultrasmall nano-domains with a laser, so called heat assisted magnetic recording or HAMR. The volume in such invar materials hardly expands despite heating. A technologically relevant material for such HAMR data memories are thin films of iron-platinum nanograins. An international team led by the joint research group of Prof. Dr. Matias Bargheer at HZB and the University of Potsdam has now observed experimentally for the first time how a special spin-lattice interaction in these iron-platinum thin films cancels out the thermal expansion of the crystal lattice. The study has been published in Science Advances.

A team of researchers from the Helmholtz-Zentrum Berlin (HZB) and Humboldt-Universität zu Berlin has succeeded for the first time in producing light-emitting diodes (LEDs) from a hybrid perovskite semiconductor material using inkjet printing.This opens the door to broad application of these materials in manufacturing many different kinds of electronic components.The scientists achieved the breakthrough with the help of a trick: "inoculating" (or seeding) the surface with specific crystals.

An international team has developed a sophisticated experimental technique at BESSY II to observe the formation of a metallic conduction band in electrolytes. To accomplish this, the team first prepared cryogenic solutions of liquid ammonia containing different concentrations of alkali metals. The colour of the solutions changes with concentration from blue to golden as the individual atoms of metal in solution transition to a metallic compound. The team then examined these liquid jets using soft X-rays at BESSY II and subsequently has been able to analyse this process in detail from the data they acquired combined with theoretical predictions. The work has been published in Science and appears even on the cover.

Regeneratively produced hydrogen is considered the ecological raw material of the future. In order to produce it efficiently by electrolysis of water, researchers today also investigate perovskite oxides. The Journal of Physics: Energy invited Dr. Marcel Risch from the Helmholtz-Zentrum Berlin (HZB) to outline the current state of research.

The promising halide perovskite materials for solar energy conversion show high efficiencies, but this comes at a cost: The best perovskite materials incorporate toxic lead which poses a hazard to the environment. To replace lead by less toxic elements is not easy since lead-free perovskites show lower stability and poor efficiencies. Now, an international collaboration has engineered a new hybrid perovskite material with promising efficiency and stability.

Quantum Spin Liquids are candidates for potential use in future information technologies. So far, Quantum Spin Liquids have usually only been found in one or two dimensional magnetic systems only. Now an international team led by HZB scientists has investigated crystals of PbCuTe₂O₆ with neutron experiments at ISIS, NIST and ILL. They found spin liquid behaviour in 3D, due to a so called hyper hyperkagome lattice. The experimental data fit extremely well to theoretical simulations also done at HZB.

A special branch in the famous NREL-chart for solar cell world records refers to a newly developed tandem solar cell by HZB teams. The world-record cell combines the semiconductors perovskite and CIGS to a monolithic "two-terminal" tandem cell. Due to the thin-film technologies used, such tandem cells survive much longer in space and can even be produced on flexible films. The new tandem cell achieves a certified efficiency of 24.16 percent.

90 years ago, the physicist Hans Bethe postulated that unusual patterns, so-called Bethe strings, appear in certain magnetic solids. Now an international team has succeeded in experimentally detecting such Bethe strings for the first time. They used neutron scattering experiments at various neutron facilities including the unique high-field magnet of BER II* at HZB. The experimental data are in excellent agreement with the theoretical prediction of Bethe and prove once again the power of quantum physics.

At the BESSY II storage ring, a joint team of accelerator physicists, undulator experts and experimenters has shown how the helicity of circularly polarized synchrotron radiation can be switched faster - up to a million times faster than before. They used an elliptical double-undulator developed at HZB and operated the storage ring in the so-called two-orbit mode. This is a special mode of operation that was only recently developed at BESSY II and provides the basis for fast switching. The ultra-fast change of light helicity is particularly interesting to observe processes in magnetic materials and has long been expected by a large user community.

Two dimensional titanium carbides, so-called MXenes, are being discussed as candidates for the rapid storage of electrical energy. Like a battery,MXenes can store large amounts of electrical energy through electrochemical reactions- but unlike batteries,can be charged and discharged in a matter of seconds. In collaboration with Drexel University, a team at HZB showed that the intercalation of urea molecules between the MXene layers can increase the capacity of such "pseudo-capacitors" by more than 50 percent. At BESSY II they have analysed how changes of the MXene surface chemistry after urea intercalation are responsible for this.

Last week a new detector was installed at one of the three MX beamlines at HZB. Compared to the old detector the new one is better, faster and more sensitive. It allows to acquire complete data sets of complex proteins within a very short time.

Nanoparticles easily enter into cells. New insights about how they are distributed and what they do there are shown for the first time by high-resolution 3D microscopy images from the lightsources BESSY II and ALBA. For example, certain nanoparticles accumulate preferentially in certain organelles of the cell. This can increase the energy costs in the cell. "The cell looks like it has just run a marathon, apparently, the cell requires energy to absorb such nanoparticles" says lead author James McNally.

High magnetic fields have a potential to modify the microscopic arrangement of magnetic moments because they overcome interactions existing in zero field. Usually, high fields exceeding a certain critical value force the moments to align in the same direction as the field leading to ferromagnetic arrangement. However, a recent study showed that this is not always the case. The experiments took place at the high-field magnet at HZB's neutron source BER II, which generates a constant magnetic field of up to 26 Tesla. This is about 500,000 times stronger than the Earth's magnetic field. Further experiments with pulsed magnetic fields up to 45 Tesla were performed at the Helmholtz-Zentrum Dresden-Rossendorf (HZDR). 

An international team has used neutron and X-ray tomography to investigate the dynamic processes that lead to capacity degradation at the electrodes in lithium batteries. Using a new mathematical method, it was possible to virtually unwind electrodes that had been wound into the form of a compact cylinder, and thus actually observe the processes on the surfaces of the electrodes. The study was published in Nature Communications.

Experts from 51 research institutions have now agreed on the procedures for measuring the stability of perovskite solar cells and assessing their quality. The consensus statement was published in Nature Energy and is considered a milestone for the further development of this new type of solar cell on its way to industrial application.

In the race for ever higher efficiency levels, an HZB development team has once again pulled ahead. The groups of Steve Albrecht and Bernd Stannowski have developed a tandem solar cell made of the semiconductors perovskite and silicon, that converts 29.15 per cent of the incident light into electrical energy. This value has been officially certified by the CalLab of the Fraunhofer Institute for Solar Energy Systems (ISE) and means that surpassing the 30 per cent efficiency mark is now within reach.

Lead from metal-organic perovskite compounds can be absorbed particularly easily by plants. The bioavailability is significantly higher than that of lead from inorganic compounds as found in batteries. This is shown in a study by HZB researcher Antonio Abate with partners in China and Italy, published in Nature communications.

New experiments with magnetically doped topological insulators at BESSY II have revealed possible ways of lossless signal transmission that involve a surprising self-organisation phenomenon. In the future, it might be possible to develop materials that display this phenomenon at room temperature and can be used as processing units in a quantum computer, for example. The study has been published in the renowned journal Nature.

Using crystallographic analyses at the Diamond Light Source (DLS) synchrotron in the United Kingdom, an HZB team has demonstrated that hybrid halide perovskites crystallise without inversion centre. Interactions between the organic molecules and adjacent iodine atoms can lead to the formation of ferroelectric domains, which, indirectly, can result in higher solar-cell efficiencies. The formation of these ferroelectric domains cannot occur in purely inorganic perovskites.

Tiny magnetic vortices known as skyrmions form in certain magnetic materials, such as Cu₂OSeO₃. These skyrmions can be controlled by low-level electrical currents – which could facilitate more energy-efficient data processing. Now a team has succeeded in developing a new technique at the VEKMAG station of BESSY II for precisely measuring these vortices and observing their three different predicted characteristic oscillation modes (Eigen modes).

A team headed by Prof. Steve Albrecht from the HZB will present a new world-record tandem solar cell at EU PVSEC, the world's largest international photovoltaic and solar energy conference and exhibition, in Marseille, France on September 11, 2019. This tandem solar cell combines the semiconducting materials perovskite and CIGS and achieves a certified efficiency of 23.26 per cent. One reason for this success lies in the cell’s intermediate layer of organic molecules: they self-organise to cover even rough semiconductor surfaces. Two patents have been filed for these layers.

An HZB team has for the first time precisely analysed how nanoparticles of lithium sulphide and sulphur precipitate onto battery electrodes during the course of the charging cycle. The results can help increase the service life of lithium-sulphur batteries.

For the first time, an HZB team has derived analytically how corkscrew-shaped nano-antennas interact with light. The mathematical tool can be used to calculate the geometry that a nano-antenna must have for specific applications in sensor technology or information technology.

An international research team at the Swiss Light Source (SLS) has set a new tomography world record using a rotary sample table developed at the HZB. With 208 three-dimensional tomographic X-ray images per second, they were able to document the dynamic processes involved in the foaming of liquid aluminium. The method is presented in the journal Nature Communications.

Christiane Becker uses microscopic structures to increase the amount of light captured in solar cells and is currently scaling up the technology for industrial application. “On top of everything else, there’s this spirit at HZB that we are working on the renewable energies of the future, and that is incredibly inspiring,” she relates in portrait.

Plastics are excellent materials: extremely versatile and almost eternally durable. But this is also exactly the problem, because after only about 100 years of producing plastics, plastic particles are now found everywhere – in groundwater, in the oceans, in the air, and in the food chain.

In modern synchrotron sources and free-electron lasers, superconducting radio-frequency cavity resonators are able to supply electron bunches with extremely high energy. These resonators are currently constructed of pure niobium. Now an international collaboration has investigated the potential advantages a niobium-tin coating might offer in comparison to pure niobium.

Transition-metal complexes in dye-based solar cells are responsible for converting light into electrical energy. A model of spatial charge separation within the molecule has been used to describe this conversion. However, an analysis at BESSY II shows that this description of the process is too simple. For the first time, a team there has investigated the fundamental photochemical processes around the metal atom and its ligands. The study has now been published in “Angewandte Chemie, international Edition” and is displayed on the cover.

How fast can a magnet switch its orientation and what are the microscopic mechanisms at play ? These questions are of first importance for the development of data storage and computer chips. Now, an HZB team at BESSY II has for the first time been able to experimentally assess the principal microscopic process of ultra-fast magnetism. The methodology developed for this purpose can also be used to investigate interactions between spins and lattice oscillations in graphene, superconductors or other (quantum) materials.

Teams from Humboldt-Universität and the Helmholtz-Zentrum Berlin have explored a new material in the carbon-nitride family. Triazine-based graphitic carbon nitride (TGCN) is a semiconductor that should be highly suitable for applications in optoelectronics. Its structure is two-dimensional and reminiscent of graphene. Unlike graphene, however, the conductivity in the direction perpendicular to its 2D planes is 65 times higher than along the planes themselves.

Several research institutions are developing a miniaturized electron paramagnetic resonance (EPR) device with industrial partner Bruker to investigate semiconductor materials, solar cells, catalysts and electrodes for fuel cells and batteries. The Federal Ministry of Education and Research (BMBF) is funding the "EPR-on-a-Chip" or EPRoC project with 6.7 million euros. On June 3, 2019, the kick-off meeting took place at the Helmholtz-Zentrum Berlin.

Solar cells and photocathodes made of copper oxide might in theory attain high efficiencies for solar energy conversion. In practice, however, large losses occur. Now a team at the HZB has been able to use a sophisticated femtosecond laser experiment to determine where these losses take place: not so much at the interfaces, but instead far more in the interior of the crystalline material. These results provide indications on how to improve copper oxide and other metal oxides for applications as energy materials.

Lithium batteries lose amp-hour capacity over time. Microstructures can form on the electrodes with each new charge cycle, which further reduces battery capacity. Now an HZB team together with battery researchers from Forschungszentrum Jülich, the University of Munster, and partners in China have documented the degradation process of lithium electrodes in detail for the first time. They achieved this with the aid of a 3D tomography process using synchrotron radiation at BESSY II (HZB) as well at the Helmholtz-Zentrum Geesthacht (HZG). Their results have been published open access in the scientific journal "Materials Today".

A team at the Helmholtz-Zentrum Berlin has succeeded in producing inorganic perovskite thin films at moderate temperatures using co-evaporation – making post-tempering at high temperatures unnecessary. The process makes it much easier to produce thin-film solar cells from this material. In comparison to metal-organic hybrid perovskites, inorganic perovskites are more thermally stable. The work has been published in Advanced Energy Materials.

Tin selenide might considerably exceed the efficiency of current record holding thermoelectric materials made of bismuth telluride. However, it was thought its efficiency became enormous only at temperatures above 500 degrees Celsius. Now measurements at the BESSY II and PETRA III synchrotron sources show that tin selenide can also be utilised as a thermoelectric material at room temperature – so long as high pressure is applied.

A research team from the University of Greifswald and Helmholtz-Zentrum-Berlin (HZB) has solved the molecular structure of the important enzyme MHETase at BESSY II. MHETase was discovered in bacteria and together with a second enzyme - PETase - is able to break down the widely used plastic PET into its basic building blocks. This 3D structure already allowed the researchers to produce a MHETase variant with optimized activity in order to use it, together with PETase, for a sustainable recycling of PET. The results have been published in the research journal Nature Communications.

Efficient and inexpensive catalysts will be required for production of hydrogen from sunlight. Molybdenum sulphides are considered good candidates. A team at HZB has now explained what processes take place in molybdenum sulphides during catalysis and why amorphous molybdenum sulphide works best. The results have been published in the journal ACS Catalysis.

In the new special issue of the "Philosophical Transactions of the Royal Society of London", internationally renowned experts report on new developments in X-ray sources and ultrafast time-resolved experiments. HZB physicists have also been invited to contribute.

Nanostructures made of carbon are extremely versatile: they can absorb ions in batteries and supercapacitors, store gases, and desalinate water. How well they cope with the task at hand depends largely on the structural features of the nanopores. A new study from the HZB has now shown that structural changes that occur due to morphology transition with increasing temperature of the synthesis can also be measured directly – using small-angle X-ray scattering. The results have now been published in the journal Carbon.

In order to explain the known anomalies in water, some researchers assume that water consists of a mixture of two phases even under ambient conditions. However, new X-ray spectroscopic analyses at BESSY II, ESRF and Swiss Light Source show that this is not the case. At room temperature and normal pressure, the water molecules form a fluctuating network with an average of 1.74 ± 2.1% donor and acceptor hydrogen bridge bonds per molecule each, allowing tetrahedral coordination between close neighbours.

Data storage in today’s magnetic media is very energy consuming. Combination of novel materials and the coupling between their properties could reduce the energy needed to control magnetic memories thus contributing to a smaller carbon footprint of the IT sector. Now an international team led by HZB has observed at the HZB lightsource BESSY II a new phenomenon in iron nanograins: whereas normally the magnetic moments of the iron grains are disordered with respect each other at room temperature, this can be changed by applying an electric field: This field induces locally a strain on the system leading to the formation of a so-called superferromagnetic ordered state.

An HZB team has fabricated and characterised a thin-film tandem solar cell made of perovskite and CIGSe. They relied on a simple, robust fabrication process that is also suitable for scaling up to large surface areas. The tandem solar cell is a fully thin film device with an impressive efficiency of 21.6 %. With further improvements it might reach efficiencies above 30 %.

In theory, silicon anodes could store ten times more lithium ions than graphite anodes, which have been used in commercial lithium batteries for many years. However, the amp-hour capacity of silicon anodes so far has been declining sharply with each additional charge-discharge cycle. Now an HZB team at BER II of the HZB in Berlin and the Institut Laue-Langevin in Grenoble has utilised neutron experiments to establish what happens at the surface of the silicon anode during charging and what processes reduce this capacity.

If CO₂ emissions do not fall fast enough, then CO₂ will have to be removed from the atmosphere in the future to limit global warming. Not only could planting new forests and biomass contribute to this, but new technologies for artificial photosynthesis as well. An HZB physicist and a researcher at the University of Heidelberg have estimated how much surface area such solutions would require. Although artificial photosynthesis could bind CO₂ more efficiently than the natural model, there are still no large modules that are stable over the long term. The team published their calculations in "Earth System Dynamics".

A team at the HZB has improved the manufacturing process of photocathodes and can now provide photocathodes with high quantum efficiency for bERLinPro.

A team at the HZB has discovered a new method for producing efficient contact layers in perovskite solar cells. It is based on molecules that organise themselves into a monolayer. The study was published in Advanced Energy Materials and appeared on the front cover of the journal.

A team at BESSY II has investigated how various iron-complex compounds process energy from incident light. They were able to show why certain compounds have the potential to convert light into electrical energy. The results are important for the development of organic solar cells. The study has now been published in the journal PCCP, and its illustration selected for the cover.

Using microstructured layers, an HZB team has been able to increase the efficiency of perovskite-silicon tandem solar cells, achieving 25.5 %, which is the highest published value to date. At the same time, computational simulations were utilized to investigate light conversion in various device designs with different nanostructured surfaces. This enabled optimization of light management and detailed energy yield analyses. The study has now been published in Energy & Environmental Science.

Scientists at HZB have found evidence that double layers of graphene have a property that may let them conduct current completely without resistance. They probed the bandstructure at BESSY II with extremely high resolution ARPES and could identify a flat area at a surprising location.

Frederike Lehmann from the HZB Department Structure and Dynamics of Energy Materials received a poster award at an international conference, the ICTMC-21 in Boulder, Colorado, USA. She presented her results on the synthesis and characterization of hybrid perovskite materials, which are considered interesting candidates for novel solar cells.

Diamond nanomaterials are considered hot candidates for low-cost photocatalysts. They can be activated by light and can then accelerate certain reactions between water and CO₂ and produce carbon-neutral "solar fuels". The EU project DIACAT has now doped such diamond materials with boron and shown at BESSY II how this could significantly improve the photocatalytic properties.

Until recently, the existence of "blue" phosphorus was pure theory: Now an HZB team was able to examine samples of blue phosphorus at BESSY II for the first time and confirm via mapping of their electronic band structure that this is actually this exotic phosphorus modification. Blue phosphorus is an interesting candidate for new optoelectronic devices. The results have been published in Nano Letters.

With a newly developed neutron tomography technique, an HZB team has been able to map for the first time magnetic field lines inside materials at the BER II research reactor. Tensorial neutron tomography promises new insights into superconductors, battery electrodes, and other energy-related materials.

The efficiency of a solar cell is one of its most important parameters. It indicates what percentage of the solar energy radiated into the cell is converted into electrical energy. The theoretical limit for silicon solar cells is 29.3 percent due to physical material properties. In the journal Materials Horizons, researchers from Helmholtz-Zentrum Berlin (HZB) and international colleagues describe how this limit can be abolished. The trick: they incorporate layers of organic molecules into the solar cell. These layers utilise a quantum mechanical process known as singlet exciton fission to split certain energetic light (green and blue photons) in such a way that the electrical current of the solar cell can double in that energy range.

Photonic nanostructures can be used for many applications, not just in solar cells, but also in optical sensors for cancer markers or other biomolecules, for example. A team at HZB using computer simulations and machine learning has now shown how the design of such nanostructures can be selectively optimised. The results are published in Communications Physics.

A team of researchers from the Helmholtz-Zentrum Berlin (HZB) and the University of Potsdam has investigated heat transport in a model system comprising nanometre-thin metallic and magnetic layers. Similar systems are candidates for future high-efficiency data storage devices that can be locally heated and rewritten by laser pulses (Heat-Assisted Magnetic Recording). Measurements taken with extremely short X-ray pulses have now shown that the heat is distributed a hundred times slower than expected in the model system. The results are published in Nature Communications.

An HZB team has developed an ingenious precision rotary table at the EDDI beamline at BESSY II and combined it with particularly fast optics. This enabled them to document the formation of pores in grains of metal during foaming processes at 25 tomographic images per second - a world record.

In perovskite solar cells, charge carriers are mainly lost through recombination occurring at interface defect sites. In contrast, recombination at defect sites within the perovskite layer does not limit the performance of the solar cells at present. Teams from the University of Potsdam and the Helmholtz-Zentrum Berlin (HZB) were able to reach this interesting conclusion through extremely accurate quantitative measurements on 1 cm² perovskite cells using photoluminescence. Their results contribute to improving  perovskite solar cells and have now been published in Nature Energy.

An international team has made a breakthrough at BESSY II. For the first time, they succeeded in investigating electronic states of a transition metal in detail and drawing reliable conclusions on their catalytic effect from the data. These results are helpful for the development of future applications of catalytic transition-metal systems. The work has now been published in Chemical Science, the Open Access journal of the Royal Society of Chemistry.

A team of researchers at Helmholtz-Zentrum Berlin (HZB) and European Spallation Source (ESS) has now published a comprehensive overview of neutron-based imaging processes in the renowned journal Materials Today (impact factor 21.6). The authors report on the latest developments in neutron tomography, illustrating the possible applications using examples of this non-destructive method. Neutron tomography has facilitated breakthroughs in so diverse areas such as art history, battery research, dentistry, energy materials, industrial research, magnetism, palaeobiology and plant physiology.

Specific changes in the composition of kesterite-type semiconductors make it possible to improve their suitability as absorber layers in solar cells. As a team at the Helmholtz-Zentrum Berlin showed, this is particularly true for kesterites in which tin was replaced by germanium. The scientists examined the samples using neutron diffraction at BER II and other methods. The work was selected for the cover of the journal CrystEngComm.

Polymeric carbon nitrides exhibit a catalytic effect in sunlight that can be used for the production of hydrogen from solar energy. However, the efficiency of these metal-free catalysts is extremely low. A team at the Tianjin University in China, in collaboration with a group at the Helmholtz-Zentrum Berlin, has increased the catalytic efficiency of these polymeric carbon nitrides by a factor eleven through a simple process resulting in a larger surface area. The paper was published in the journal Energy & Environmental Science.

A team at the HZB has succeeded in growing nanocrystals of gallium arsenide on tiny columns of silicon and germanium. This enables extremely efficient optoelectronic components for important frequency ranges to be realised on silicon chips.

Thermoelectric materials can use thermal differences to generate electricity. Now there is an inexpensive and environmentally friendly way of producing them with the simplest of components: a normal pencil, photocopy paper, and conductive paint are sufficient to convert a temperature difference into electricity via the thermoelectric effect. This has now been demonstrated by a team at the Helmholtz-Zentrum Berlin.

An international team at BESSY II headed by Prof. Oliver Rader has shown that the puzzling properties of samarium hexaboride do not stem from the material being a topological insulator, as it had been proposed to be. Theoretical and initial experimental work had previously indicated that this material, which becomes a Kondo insulator at very low temperatures, also possessed the properties of a topological insulator. The team has now published a compelling alternative explanation in Nature Communications, however.

Experiments at BESSY II reveal why even inhomogeneous perovskite films are highly functional 

HZB scientists have identified a mechanism with which it may be possible to develop a form of magnetic storage that is faster and more energy-efficient. They compared how different forms of magnetic ordering in the rare-earth metal named dysprosium react to a short laser pulse. They discovered that the magnetic orientation can be altered much faster and with considerably less energy if the magnetic moments of the individual atoms do not all point in the same direction (ferromagnetism), but instead point are rotated against each other (anti-ferromagnetism). The study was published in Physical Review letters on 6. November 2017 and on the cover of the print edition.

HZB-Physicists at BESSY II have investigated a class of materials that exhibit characteristics of topological insulators. During these studies they discovered a transition between two different topological phases, one of which is ferroelectric, meaning a phase in the material that exhibits spontaneous electric polarisation and can be reversed by an external electric field. This could also lead to new applications such as switching between differing conductivities.

Graphene possesses extreme properties and can be utilised in many ways. Even the spins of graphene can be controlled through use of a trick. This had already been demonstrated by a HZB team some time ago: the physicists applied a layer of graphene onto a nickel substrate and introduced atoms of gold in between (intercalation). The scientists now show why this has such a dramatic influence on the spins in a paper published in 2D Materials. As a result, graphene can also be considered as a material for future information technologies that are based on processing spins as units of information.

For the first time an international team realized direct writing of silver nanostructures using an electron beam applied to a substrate. Silver nanostructures have the potential to concentrate visible light at the nanoscale. Potential applications include sensor design to detect extremely small traces of specific molecules, as well as devices for optical information processing.

Helmholtz-Zentrum Berlin has expanded its series of CoreLabs for energy materials research. In addition to the five established CoreLabs, it has now set up a CoreLab for Quantum Materials. A research team from the HZB Institute for Quantum Phenomena in New Materials is responsible for the CoreLab and its modern equipment. The CoreLab is also open to experimenters from other research institutes. 

The Helmholtz-Zentrum Berlin (HZB) is establishing a joint lab together with the Max Planck Society (MPS) to study electrochemical phenomenon at solid/liquid interfaces. The Berlin Joint Lab for Electrochemical Interfaces, or BElChem for short, will employ X-rays from BESSY II to analyse materials for renewable energy production.

A team at the Helmholtz-Zentrum Berlin (HZB) has for the first time fabricated a nanomaterial made from nanoparticles of a titanium oxide compound (Ti₄O₇) that is characterised by an extremely large surface area, and tested it as a cathode material in lithium-sulphur batteries. The highly porous nanomaterial possesses high storage capacity that remains nearly constant over many charging cycles.

A team at the Helmholtz-Zentrum Berlin (HZB) together with researchers in Sweden and the USA has analysed a mecanism which protects biomolecules such as the DNA against damage by light. They observed how the energy of incoming photons can be absorbed by the molecule without destroying important bonds. The experiments took place at the Linac Coherent Light Source (LCLS) free-electron laser in California as well as the BESSY II synchrotron source at the HZB in Berlin, where with resonant inelastic X-ray-diffraction a very sensitive method is available.

Nanoparticles at the back help harvesting the light.

The storage of excess solar and wind power is one of the greatest challenges in Germany’s energy transition. To address this, the German Federal Ministry for Education and Research (BMBF) has created the “Power-to-X” (P2X) project under its Kopernikus programme. P2X will advance research into converting electrical energy from the sun and wind into basic chemical compounds, gaseous energy media, and fuels. A total of 17 research institutions, 26 industrial enterprises, as well as three non-governmental organisations are involved, and the BMBF is funding the first development phase of the project at a level of 30 million Euros. The Helmholtz-Zentrum Berlin will participate in the planned research, using the advanced synthesis capabilities and the BESSY II synchrotron-based X-ray characterization tools at the recently inaugurated EMIL@BESSY II laboratory complex.

Particularly in the soft X-ray range experimentalists are lacking a broadband method to correlate ultrashort X-ray and laser pulses in space and time. Only recently, a team from Helmholtz-Zentrum Berlin and the University of Potsdam was able to achieve this by utilizing a standard molybdenum-silicon (Mo/Si) multilayer mirror at the FemtoSpeX facility at BESSY II. They use femtosecond laser pulses to modulate the multilayer period under the Bragg condition on a sub-picosecond up to nanosecond timescale which in turn strongly affects the mirror’s X-ray reflectivity. The presented Mo/Si cross-correlator works for the soft up to the hard X-ray regime as well as for a broad range of laser pump wavelengths (mid-IR to UV) and renders this technique as an easy to implement and versatile timing tool for various synchrotron- and lab-based pump-probe experiments. The results are published in the journal of "Structural Dynamics".

An HZB team has developed a new approach to conduct photoemission spectroscopy of molecules in solution. This has been difficult up to now because the sample needed to be situated in vacuum – but liquids evaporate. The work has now demonstrated it is feasible to replace the solvent with an ionic liquid of low vapor pressure, which does not perturb the sample characteristics.  This allows the molecules to be excited with a laser pulse and to record the behaviour of the excited energy states. It provides insight into the physical and chemical processes of novel liquid energy materials that might be employed in organic solar cells or catalysts, for instance.

An international collaboration at BESSY II has discovered a new method to inscribe exotic magnetic patterns such as magnetic monopoles into thin ferromagnetic films. Such unconventional orientation of magnetic domains might open a new path for the design of energy efficient data storage. The new materials system consists of regular arrays of superconducting YBaCuO-dots covered with an extremely thin permalloy film. A shortly applied external magnetic field leads to the creation of supercurrents within the superconducting dots. These currents produce a complex magnetic field pattern, which is inscribed into the permalloy film above. The results are published in Advanced Science.

Nano-sized metallic wires are attracting increasing attention as conductive elements for manufacturing transparent electrodes, which are employed in solar cells and touch screen panels. In addition to high electric conductivity, excellent optical transmittance is one of the important parameters for an electrode in photovoltaic applications. An international team headed by HZB scientist Prof. Michael Giersig has recently demonstrated for these applications that networks of metallic mesh possessing fractal-like nano-features surpass other metallic networks in utility. These findings have now been published in the most recent edition of the renowned journal Nature Communications.

Near the museum island, in the heart of Berlin, the International Conference "Dynamic Pathways in Multidimensional Landscapes 2016" has taken place last week. More than 100 international experts met at the Magnus-Haus of the German Physical Society from 12 -16 September 2016.

The capacity of lithium-ion batteries might be increased theoretically by six times by using anodes made of silicon instead of graphite. A team from the Helmholtz-Zentrum Berlin (HZB) Institute of Soft Matter and Functional Materials has observed for the first time in detail how lithium ions migrate into thin films of silicon. It was shown that extremely thin layers of silicon would be sufficient to maximise the load of lithium. The results are published in the journal ACSnano.

Two Freigeist Fellows are conducting research at the HZB Institute for Methods of Material Development through support received from the Volkswagen Foundation. Theoretical chemist Dr. Annika Bande is modelling fast electron processes, while Dr. Tristan Petit is investigating carbon nanoparticles. Annika Bande has now been awarded an ancillary grant of an additional 150,000 Euros from the Volkswagen Foundation to fund another doctoral student position for three years. The doctoral research will connect the two Freigeist research projects with one another.

A novel and rare state of matter known as a quantum spin liquid has been empirically demonstrated in a monocrystal of the compound calcium-chromium oxide by team at HZB. What is remarkable about this discovery is that according to conventional understanding, a quantum spin liquid should not be possible in this material. A theoretical explanation for these observations has now also been developed. This work deepens our knowledge of condensed matter and might also be important for future developments in quantum information. The results have just been published in Nature Physics.

Graphene on silicon carbide could be an interesting candidate for future spintronik components. Squeezing gold atoms between the semiconducting substrate and graphene does enhance spin-orbit interaction at hot spots and shows ways to controll the spins. First results at BESSY II are now published in Applied Physics Letters.

A HZB team has examined thin films of Dysprosium-Cobalt sputtered onto a nanostructured membrane at BESSY II. They showed that new patterns of magnetization could be written in a quick and easy manner after warming the sample to only 80 °Celsius, which is a much lower temperature as compared to conventional Heat Assisted Magnetic Recording systems. This paves the way to fast and energy efficient ultrahigh density data storage. The results are published now in the new journal Physical Review Applied.

An HZB team has combined two different analytical methods at the BESSY II synchrotron source in order to extract more information about the chemistry of transition-metal compounds in solution. These kinds of compounds can act as catalysts to promote desirable reactions in energy materials, but their behaviour has not been completely understood thus far.  The team demonstrated how a detailed picture of the electronic states can be ascertained by systematically comparing all of the interactive electronic processes in a simple system of aqueous iron(II).  The results have now been published in Scientific Reports, the open access journal from Nature Group publishing.

HZB will be setting up the new Helmholtz HySPRINT Innovation Lab for jointly developing new combinations of materials and processes in energy applications with commercial partners. Silicon and metal-organic perovskite crystals will be the centre point of the Lab’s work. The Helmholtz Association is supporting the project for the next five years with 1.9 million Euros from its Initiative and Networking Fund, with additional contributions from HZB itself as well as from industry.

An international team headed by HZB researcher Jaime Sánchez-Barriga has shown how spin-polarised currents can be initiated in a controlled manner within samples of topological insulator material. In addition, they were able to manipulate the orientation of the spins of these currents. They thereby demonstrated that this class of materials is suitable for data processing based on spin. The work has been published in the renowned periodical Physical Review B and was selected as “Editor’s Suggestion” article.

Applicants for support funds to conduct research on topological insulators met at HZB Adlershof on February 15th and 16th. This meeting dealt with the second period of funding for the SPP 1666 Priority programme of the German Research Foundation (DFG) that runs from mid-2016 to 2019. Researchers from across Germany contribute their specific expertise and work together in these Priority programmes (SPPs).

A team at the HZB Institute for Solar Fuels has developed a process for providing sensitive semiconductors for solar water splitting (“artificial leaves”) with an organic, transparent protective layer. The extremely thin protective layer made of carbon chains is stable, conductive, and covered with catalysing nanoparticles of metal oxides. These accelerate the splitting of water when irradiated by light. The team was able to produce a hybrid silicon-based photoanode structure that evolves oxygen at current densities above 15 mA/cm². The results have now been published in Advanced Energy Materials.

A team from Helmholtz-Zentrum Berlin has been able for the first time to measure how new bonds influence molecules: they have reconstructed the “energy landscape” of acetone molecules using measurement data from the Swiss Light Source (SLS) of the Paul Scherrer Institut, and thereby empirically established the formation of hydrogen bonds between acetone and chloroform molecules. The results have been published in Nature Scientific Reports and assist in understanding fundamental phenomena of chemistry.

A Franco-German cooperation has investigated a sandwich system of transition metal oxides at BESSY II. The scientists discovered a new option to control properties of the interface between the two layers, for instance the amount of charge transferred from one layer to the other or the emergence of ferromagnetism.  Their insights might help to create new properties at the interface, not present in the primary materials, maybe even novel forms of High Tc superconductivity.

Also Raman microspectroscopy in an optical microscope provides the means to determine local crystal orientations of polycrystalline materials over large sample areas. This method can be used alternatively to electron backscatter diffraction in a scanning electron microscope. It was shown by a team from Helmholtz-Zentrum Berlin and the Federal Institute for Materials Research and Testing (BAM) that both characterization techniques result in similar orientation distribution maps on areas of several hundreds of square micrometers.

Silicon, a semiconducting material, reveals new talents when reduced to nanoscopic dimensions. A joint team at the HZB Institute of Nanoarchitectures for Energy Conversion and the Max Planck Institute for the Science of Light (MPL) has demonstrated this. Silicon nanocones generate 200 times as much infrared luminescence as comparably sized nanocolumns when excited by visible light. Modelling and experimental results show that due to their geometry, cones are able to sustain what is referred to as whispering gallery modes at infrared wavelengths which can intensify the silicon luminescence. New applications are conceivable, including silicon-based nanolasers.

The EDDI beamline at BESSY II is now offering even more options. It has recently become possible to also obtain high-resolution three-dimensional images of microscopic structure with it, up to four such tomographies per second are possible. X-ray diffraction (energy-dispersive diffraction) can simultaneously be carried out to draw conclusions about the crystal structure of the material just as before.

The particle accelerator team at Helmholtz-Zentrum Berlin (HZB) has demonstrated that BESSY II, the 3rd generation synchrotron radiation source in Berlin, can be operated with not just one, but two simultaneous electron paths. By precisely tuning the magnetic components, physicists can create an additional orbital path. Packets of electrons can travel along it and emit intense light pulses at the experiment stations. This could provide the user community with the option to select light pulses from either path as needed in their experiments. The newly developed orbital mode has already been stably implemented and initial tests at the experiment stations (beamlines) show promising results. HZB is the first to enter this new territory and at the same time has reached another milestone in its pioneering BESSY-VSR project.

At the International Conference on X-Ray Absorption Fine Structure Markus Kubin has been selected to receive one out of five poster awards. More than 300 posters have been presented at the poster session.

CIGSe solar cells  are made of a thin chalcopyrite layer consisting of Copper, Indium, Gallium and Selenium and can reach high efficiencies. Since Indium is becoming scarce and expensive, it is interesting to reduce the active CIGSe layer, which however decreases the efficiency quite strongly.  Now, scientists at Helmholtz-Zentrum Berlin have produced high quality ultrathin CIGSe layers and increased their efficiency by an array of tiny nanoparticles between the back contact and the active layer.

HZB team develops elegant process for coating fragile perovskite layers with graphene for the first time. Subsequent measurements show that the graphene layer is an ideal front contact in several respects.

The Einstein Foundation will fund the new Einstein Center for Catalysis (EC²) beginning in 2016 in which Technical University Berlin (TU Berlin) and selected non-university institutions in Berlin will be participating. Prof. Emad Aziz, head of the HZB Institute for Methods of Materials Research at Helmholtz-Zentrum Berlin will be taking part in setting up the institution. His team will be contributing particular expertise in analytics of ultrafast processes in catalytic reactions.

An HZB team headed by Prof. Silke Christiansen has made a surprising discovery about hybrid organic/inorganic solar cells. Contrary to expectations, a diode composed of the conductive organic PEDOT:PSS and an n-type silicon absorber material behaves more like a pn junction between two semiconductors than like a metal-semiconductor contact (Schottky diode). Their results have now been published in the Nature journal Scientific Reports and could point the way toward improvements in hybrid solar cells.

A team headed by Prof. Silke Christiansen has developed a transparent electrode with high electrical conductivity for solar cells and other optoelectronic components – that uses minimal amounts of material. It consists of a random network of silver nanowires that is coated with aluminium-doped zinc oxide. The novel electrode requires about 70 times less silver than conventional silver grid electrodes, but possesses comparable electrical conductivity.

X-ray spectroscopy at BESSY II reveals inhomogenous distribution of chlorine in a special class of perovskite materials. The discovery could help to enhance efficiencies of perovskite thin film solar cells by controlled processing to optimize the chlorine distribution.

The annual "International Conference on Thermoelectrics (ICT)” and the "European Conference on Thermoelectrics (ECT)” took place together from 29 June to 02 July 2015 in Dresden, Germany. For the first time, HZB participated in this international multidisciplinary meeting. The HZB Department "Methods for Characterization of Transport Phenomena in Energy Materials" headed by Dr. Klaus Habicht presented their research in two talks and one poster.

An international collaboration has succeeded in using synchrotron light to detect and record the complex 3D magnetisation in wound magnetic layers. This technique could be important in the development of devices that are highly sensitive to magnetic fields, such as in medical diagnostics for example. Their results are published now in Nature Communications.

HZB team decodes relationship between magnetic interactions and the distortions in crystal structure within a geometrically “frustrated” spinel system

Horizon 2020 invests 3.9 million Euro in research project to convert CO₂ into fuels using sunlight and diamond materials

For the first time, a team of scientists has succeeded in precisely measuring and controlling the thickness of an organic compound that has been bound to a graphene layer. This might enable graphene to be used as a sensitive detector for biological molecules in the future.

A research team has developed a new approach for more realistic computer models of battery electrodes. They combined images from synchrotron tomography that capture three-dimensional structure at micron resolution with those from an electron microscope that can even resolve nanometre-scale features over a small section. They were able to transfer these nano-features to areas beyond the section using a mathematical model. Properties and processes within battery electrodes can now be simulated highly realistically using this method.

The poster contribution of Kai Neldner (HZB-Department Crystallography) was awarded a poster price of the Symposium "Thin-Film Compound Semiconductors" at the MRS Spring Meeting in San Francisco. Kai Neldner, a PhD student in the HZB Graduate School "Materials for Solar Energy Conversion" (MatSEC) has presented results on structural properties of Kesterites (Cu₂ZnSnS₄ - CZTS) in relation to its stoichiometry deviations.

The Berlin Joint EPR Laboratory (BeJEL) operated by HZB and Freie Universität Berlin has pulled in six of 27 subprojects within a DFG priority program to address“New Frontiers in Sensitivity for EPR Spectroscopy – from Biological Cells to Nano Materials”.

During the spring meeting 2015 of the European Materials Research Society the Poster contribution of  Dr. Ah Reum Jeong (HZB-Institute for Heterogeneous Material Systems) was selected for an award.  The young scientist has presented results on electronic and structural properties in relation to chemical composition of molybdenum oxide layers, which are widely applied in photovoltaic as well as optoelectronic devices.

Scientists from Paris and Helmholtz-Zentrum Berlin have been able to switch ferromagnetic domains on and off with low voltage in a structure made of two different ferroic materials. The switching works slightly above room temperature. Their results, which are published online in  Scientific Reports, might inspire future applications in low-power spintronics, for instance for fast and efficient data storage.

A team at the HZB Institute for Solar Fuels has developed a new composite photocathode for generating hydrogen with high quantum efficiency using sunlight. This enables solar energy to be stored chemically.The photocathode consists of a thin film of chalcopyrite produced by HZB/PVcomB coated with a newly developed thin film of photoresistant titanium dioxide containing platinum nanoparticles. This layer does not only protect the chalcopyrite thin film from corrosion, it additionally acts as a catalyst to speed-up the formation of hydrogen as well as being a novel photodiode itself that even shows photoelectric current density and voltage comparable to those of a chalcopyrite-based thin film solar cell.

A research team at HZB has developed an inkjet printing technology to produce kesterite thin film absorbers (CZTSSe). Based on the inkjet-printed absorbers, solar cells with total area conversion efficiency of up to 6.4 % have been achieved. Although this is lower than the efficiency records for this material class, the inkjet printing minimizes waste and has huge advantages for industrial production.

Marcus Bär and his team are participating in two international projects being funded under the EU Horizon 2020 research programme. Both research projects are concerned with development and optimisation of high-efficiency thin-film solar cells based on chalcopyrites (“Sharc 25") and kesterites (“SWInG”). These two projects will together bring in about 900,000 EUR of additional research funding for solar cell research.

A biological structure in mammalian eyes has inspired a team headed by Silke Christiansen to design an inorganic counterpart for use in solar cells. With the help of conventional semiconductor processes, they etched micron-sized vertical funnels shoulder-to-shoulder in a silicon substrate. Using mathematical models and experiments, they tested how these kind of funnel arrays collect incident light and conduct it to the active layer of a silicon solar cell. Their result: this arrangement of funnels increases photo absorption by about 65% in a thin-film solar cell fitted with such an array and is reflected in considerably increased solar cell efficiency, among other improved parameters.

An international team of scientists from Berlin, Freiburg and Fukuoka has provided the first direct experimental insight into the secret quantum life of dichromium. Whereas in its normal state the 12 valence electrons form a strong multiple bond between the two chromium atoms, removing only one electron changes the situation dramatically: 10 electrons localize and align their spins, thus resulting in ferromagnetic behavior of the dichromium-kation. The bonding is done by one electron only, resulting in a much weaker bond. The scientists used the unique Nanocluster Trap experimental station at the BESSY II synchrotron radiation source at Helmholtz-Zentrum Berlin and published their results in the Journal Angewandte Chemie.

An international team has observed the elusive intermediates that form when carbon monoxide is oxidized on a hot ruthenium metal surface. They used ultrafast X-ray and optical laser pulses at the SLAC National Accelerator Laboratory, Menlo Park, California. The reaction between carbon monoxide and adsorbed oxygen atoms was initiated by heating the ruthenium surface with optical laser pulses. Directly afterwards, changes in the electronic structure of oxygen atoms were probed via X-ray absorption spectroscopy as they formed bonds with the carbon atoms.The observed transition states are consistent with density functional theory and quantum oscillator models.

Together with HZB, teams from the Universität Regensburg, from the Freie Universität Berlin and from  the  Ruhr Universität Bochum have jointly set up a unique measurement station at BESSY II: a vector electromagnet consisting of three mutually perpendicular Helmholtz coils which enables  setting the local magnetic field at the sample position  to any orientation desired. The first measurements of magnetic materials, spin systems, and nanostructured magnetic samples are scheduled for early 2015.