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  Landsgesell, S.; Blumenröther, E.; Prokes, K.: Magnetic structure of La₂O₃FeMnSe₂: neutron diffraction and physical property measurements. Journal of Physics: Condensed Matter 25 (2013), p. 086004/1-6

10.1088/0953-8984/25/8/086004

Abstract:
We report on the characterization of the mixed layered lanthanum iron manganese oxyselenide La2O3FeMnSe2, where Fe and Mn share the same crystallographic position. The susceptibility data show a magnetic transition temperature of 76 K and a strong difference between field cooled and zero field cooled (ZFC) data at low fields. While the ZFC magnetization curve exhibits negative values below about 45 K, hysteresis measurement reveals, after an initial negative magnetic moment, a hysteresis loop typical for ferromagnetic material, pointing to competing ferromagnetic and antiferromagnetic interactions. Resistivity and dielectric permittivity measurements indicate that La2O3FeMnSe2 is a semiconductor. We performed x-ray diffraction at 295 K and neutron diffraction at 90 and 1.7 K. The nuclear and magnetic structure was refined in the space group I4/mmm with a = 4.11031 (3) angstrom and c = 18.7613 (2) angstrom at 295 K. We did not detect a structural distortion and the Fe and Mn atoms were randomly distributed. The magnetic order was found to be antiferromagnetic, with a propagation vector q = (0, 0, 0) and magnetic moments of 3.44 (5) mu(B) per Fe/Mn atom aligned within the a-b plane. This magnetic order is different with respect to the pure Fe or Mn compositions reported in other studies.