BESSY II: Neutralising electronic inhomogeneity in cleaved bulk MoS₂
The illustration shows the MoS2 lattice structure (green: Mo, yellow: S). The material after cleaving is shown in the forefront, the surface is jagged, and the measured surface electronic structure is inhomogeneous (coloured map). In the back is the cleaved material after exposure to atomic hydrogen (represented by the white balls). The measured surface electronic structure, shown in the map, is more homogenous. © Martin Künsting/HZB
Molybdenum disulphide (MoS₂) is a highly versatile material that can function, for example, as a gas sensor or as a photocatalyst in green hydrogen production. Although the understanding of a material usually starts from investigating its bulk crystalline form, for MoS₂ much more studies have been devoted to mono and few layer nanosheets. The few studies conducted thus far show diverse and irreproducible results for the electronic properties of cleaved bulk MoS₂ surfaces, highlighting the need for a more systematic study.
Dr. Erika Giangrisostomi and her team at HZB carried such a systematic study at the LowDosePES end-station of the BESSY II light source. They utilised X-ray photoelectron spectroscopy technique to map the core-level electron energies across extensive surface areas of MoS2 samples. Using this method, they were able to monitor the changes in the surface electronic properties after in-situ ultra-high-vacuum cleaving, annealing and exposure to atomic and molecular hydrogen.
The results from this study point to two main findings. Firstly, the study unambiguously reveals sizeable variations and instabilities in electron energies for the freshly cleaved surfaces, demonstrating how easy it is to come to diverse and irreproducible outcomes. Secondly, the study shows that room temperature atomic hydrogen treatment is remarkably effective in neutralising the surface electronic inhomogeneity and instability. This is rationalised by the ability of hydrogen atoms to either accept or give away an electron, and calls for further characterisations of the functional properties of the hydrogenated material. “We hypothesise that atomic hydrogen helps rearranging sulphur vacancies and excess of sulphur atoms yielding a more ordered structure”. Erika Giangrisostomi says.
This study marks a fundamental step in the investigation of MoS2. Due to the extensive use of MoS2 in all kinds of applications, the findings of this research have the potential to reach a wide audience in the fields of electronics, photonics, sensors and catalysis.
- Energy of charge carrier pairs in cuprate compoundsHigh-temperature superconductivity is still not fully understood. Now, an international research team at BESSY II has measured the energy of charge carrier pairs in undoped La₂CuO₄. Their findings revealed that the interaction energies within the potentially superconducting copper oxide layers are significantly lower than those in the insulating lanthanum oxide layers. These results contribute to a better understanding of high-temperature superconductivity and could also be relevant for research into other functional materials.
- Electrocatalysis with dual functionality – an overviewHybrid electrocatalysts can produce green hydrogen, for example, and valuable organic compounds simultaneously. This promises economically viable applications. However, the complex catalytic reactions involved in producing organic compounds are not yet fully understood. Modern X-ray methods at synchrotron sources such as BESSY II, enable catalyst materials and the reactions occurring on their surfaces to be analysed in real time, in situ and under real operating conditions. This provides insights that can be used for targeted optimisation. A team has now published an overview of the current state of knowledge in Nature Reviews Chemistry.
- Successful master's degree in IR thermography on solar facadesWe are delighted to congratulate our student employee Luca Raschke on successfully completing her Master's degree in Renewable Energies at the Hochschule für Technik und Wirtschaft Berlin - and with distinction!