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  Alam, M.S.; Kelm, M.; Rao, B.S.M.; Janata, E.: Reaction of H* with H₂O₂ as observed by optical absorption of perhydroxyl radicals or aliphatic alcohol radicals and of *OH with H₂O₂ : a pulse radiolysis study. Radiation Physics and Chemistry 71 (2004), p. 1087-1093

10.1016/j.radphyschem.2003.11.007

Abstract:
Two new procedures were employed for studying the reaction of hydrogen atoms with hydrogen peroxide. The absorption in the UV-range was observed either for an acidic aqueous solution containing only hydrogen peroxide or for a similar solution but also containing an aliphatic alcohol. From the increase in absorption of various alcohol radicals, a rate constant of 3.5 x 107 dm3 mol-1 s-1 was determined. In addition, the rate constant for the reaction of hydroxyl radicals with hydrogen peroxide was determined to be 3.0 x 107 dm3 mol-1 s-1.