World record back at HZB: Tandem solar cell achieves 32.5 percent efficiency
Photo of the perovskite/silicon tandem solar cell. You can see the active bluish area in the middle of the wafer, which is enclosed by the metallic, silvery electrode. © Johannes Beckedahl/Lea Zimmerman/HZB
The illustration shows the schematic structure of the tandem solar cell with a bottom cell made of silicon and a top cell made of perovskite. While the top cell can utilise blue light components, the bottom cell converts the red and near-infrared components of the spectrum. Different thin layers help to optimally utilise the light and minimise electrical losses. © Eike Köhnen/HZB
Among the emerging technologies, silicon/perovskite tandem cells are at the absolute top. The last world record by HZB is a big leap forward. © NREL
The current world record of tandem solar cells consisting of a silicon bottom cell and a perovskite top cell is once again at HZB. The new tandem solar cell converts 32.5 % of the incident solar radiation into electrical energy. The certifying institute European Solar Test Installation (ESTI) in Italy measured the tandem cell and officially confirmed this value which is also included in the NREL chart of solar cell technologies, maintained by the National Renewable Energy Lab, USA.
Scientists from HZB could significantly improve on the efficiency of perovskite/silicon tandem solar cells. "This is a really big leap forward that we didn't foresee a few months ago. All the teams involved at HZB, especially the PV Competence Center (PVComB) and the HySPRINT Innovation lab teams have worked together successfully and with passion," says Prof. Steve Albrecht.
Interface modifications
His team used an advanced perovskite composition with a very smart interface modification. The lead authors, postdocs Dr. Silvia Mariotti, and Dr. Eike Köhnen in Albrecht’s team, developed an interface modification to reduce charge carrier recombination losses and applied detailed analysis to understand the specific properties of the interface modification. These developments were then successfully implemented in tandem solar cells, and with help of Master’s student Lea Zimmermann, combined with further optical improvements.
In addition, many more scientists and technicians helped to develop and fabricate the tandem cells to achieve this success. Altogether, the interface and optical modifications enabled highest photovoltages (open-circuit voltage) and resulted in the new record efficiency for this fascinating tandem technology.
Fast progress
There is an ongoing efficiency development by various research institutes and companies over the last years and especially the last month were quite exciting for the field: Various teams from HZB had achieved a record value in late 2021 with an efficiency of 29.8% that was realized by periodic nanotextures. More recently, in summer 2022, the Ecole Polytechnique Fédérale de Lausanne, Switzerland, first reported a certified tandem cell above the 30% barrier at 31.3%, which is a remarkable efficiency jump over the 2021 value.
With the new certified value of 32.5%, the record is again back at HZB. "We are very excited about the new value as it shows that the perovskite/silicon tandem technology is highly promising for contributing to a sustainable energy supply," says Albrecht.
HZB's scientific director, Prof. Bernd Rech, emphasises: "At 32.5 percent, the solar cell efficiency of the HZB tandems is now in ranges previously only achieved by expensive III/V semiconductors. The NREL graph clearly shows how spectacular the last two increases from EPFL and HZB really are."
- Self assembling monolayer can improve lead-free perovskite solar cells tooTin perovskite solar cells are not only non-toxic, but also potentially more stable than lead-containing perovskite solar cells. However, they are also significantly less efficient. Now, an international team has succeeded in reducing losses in the lower contact layer of tin perovskite solar cells: The scienstists identified chemical compounds that self-assemble into a molecular layer that fits very well with the lattice structure of tin perovskites. On this monolayer, tin perovskite with excellent optoelectronic quality can be grown, which increases the performance of the solar cell.
- Berlin Science Award goes to Philipp AdelhelmBattery researcher Prof. Dr. Philipp Adelhelm has been awarded the 2024 Berlin Science Award. He is a professor at the Institute of Chemistry at Humboldt University in Berlin (HU) and heads a joint research group at HU and the Helmholtz Zentrum Berlin (HZB). The materials scientist and electrochemist is investigating sustainable batteries, which play a key role in the success of the energy transition. He is one of the leading international experts in the field of sodium-ion batteries.
- Long-term test shows: Efficiency of perovskite cells varies with the seasonScientists at HZB run a long-term experiment on the roof of a building at the Adlershof campus. They expose a wide variety of solar cells to the weather conditions, recording their performance over a period of years. These include perovskite solar cells, a new photovoltaic material offering high efficiency and low manufacturing costs. Dr Carolin Ulbrich and Dr Mark Khenkin evaluated four years of data and presented their findings in Advanced Energy Materials. This is the longest series of measurements on perovskite cells in outdoor use to date. The scientists found that standard perovskite solar cells perform very well during the summer months, even over several years, but decline in efficiency during the darker months.