Recommended reading: Bunsen magazine with focus on molecular water research
Water not only has some well-known anomalies, but is still full of surprises. The first issue 2023 of the Bunsen Magazine is dedicated to molecular water research, from the ocean to processes in electrolysis. The issue presents contributions from researchers cooperating within the framework of a European research initiative in the "Centre for Molecular Water Science" (CMWS). A team at HZB presents results from the synchrotron spectroscopy of water. Modern X-ray sources can be used to study molecular and electronic processes in water in detail.
With their report on "Local and collective properties of water", Annette Pietzsch, Robert Seidel and Alexander Föhlisch from HZB describe insights on the nature of water, gained with synchrotron spectroscopy at BESSY II. For example, water, which is normally a perfect insulator, can become metallic under certain conditions.
Other contributions explain the challenges of desalinating seawater, processes in electrolysis or structures in ice on the nanoscale.
These insights help in the design of even better climate models, in environmental research, the design of drugs and vaccines, but also in the development of novel catalysts for green hydrogen or other important technologies.
- Magnetic field during catalyst synthesis triples ammonia yieldApplying an external magnetic field during the synthesis of CoFe₂O₄ electrocatalysts triples the ammonia yield during electrocatalytic conversion. The magnetic field alters the surface states of the spinel oxide thin films, making catalytically active sites more accessible. In the journal 'Advanced Functional Materials', a team led by Marcel Risch at HZB and Sanjay Mathur at University of Cologne demonstrates a scalable strategy for developing next-generation electrocatalysts for efficient and sustainable chemical production.
- Materials chemistry shapes the future of catalysisThe synthesis of materials can serve as a tool for developing smart, adaptive electrocatalysts. This rapidly evolving field of research involves in-situ analytics, data-driven discoveries and autonomous robotics. These new approaches could accelerate the discovery of long-lasting and efficient catalysts for future energy conversion and the decarbonisation of the chemical industry. A recent article by Dr Prashanth Menezes and his team in the renowned journal Angewandte Chemie provides an overview of this research.
- BESSY II: How intrinsic oxygen shortens the lifespan of solid-state batteriesAlthough solid-state batteries (SSBs) demonstrate high performance and are intrinsically safe, their capacity currently declines rapidly. A team from the TU Wien, Humboldt-University Berlin and HZB has now analysed a TiS₂|Li₃YCl₆ solid-state half-cell in operando at BESSY II using a special sample environment that allows for non-destructive investigation under real operating conditions. Data obtained by combination of soft and hard X-ray photoelectron spectroscopy (XPS and HAXPES) revealed a new degradation mechanism that had not previously been identified in solid-state batteries. They have gained some surprising insights, particularly regarding the harmful role played by intrinsic oxygen. This study provides valuable information for improving design and handling of such batteries.