HZB part of new metal oxide/water systems CRC
A team of HZB researchers is part of the new collaborative research center, "Molecular insights into metal oxide/water systems" funded by the German Research Association. As part of this CRC, Dr. Bernd Winter of Prof. Dr. Emad Aziz's junior research group will be studying metal ions and metal oxide complexes in aqueous solution at BESSY II.
Spokesman of the CRC is Prof. Dr. Christian Limberg of the Humboldt University Berlin. Other partners include the Freie Universität Berlin, the Technical University of Berlin, Potsdam University, the Federal Institute for Materials Research and Testing Berlin, and the Fritz Haber Institute of the Max Planck Society Berlin.
The researchers are using a liquid microjet under vacuum conditions allowing them to obtain measurements of aqueous solutions using photoelectron spectroscopy at BESSY II. Their measurements allow for conclusions to be drawn on the binding energies and on electronic relaxation processes and thus provide clues as to the interaction between metal oxide complexes and the surrounding water molecules. In addition, the technique can be used to determine precursor molecules that will go on to form larger metal-oxo networks.
These insights are key to our ability to synthesize metal oxides for specific applications, which is typically done in aqueous solution. The reason being that metal oxides are highly interesting in terms of their technological applicability: they upgrade building materials and special types of glass, improve the properties of ceramic implants in medicine, and are considered interesting candidates for use in fuel cells, solar cells, microelectronics, and as novel kinds of catalysts.
Spokesman of the CRC "Molecular insights into metal oxide/water systems: Structural evolution, interface, and resolution" is Prof. Dr. Christian Limberg of the Humboldt University Berlin. Other partners include the Freie Universität Berlin, the Technical University of Berlin, Potsdam University, the Federal Institute for Materials Research and Testing Berlin, and the Fritz Haber Institute of the Max Planck Society Berlin. Together, the participating research groups are hoping to investigate different fundamental processes relating to metal oxide interactions with water on all relevant length scales using a combination of chemical synthesis and cutting-edge experimental and theoretical methods. In late November 2013, the German Research Association established nine new collaborative research centers (CRC's), which, through mid-2017, will receive federal funding in the amount of 64.4 million Euros total.
- New instrument at BESSY II: The OÆSE endstation in EMILA new instrument is now available at BESSY II for investigating catalyst materials, battery electrodes and other energy devices under operating conditions: the Operando Absorption and Emission Spectroscopy on EMIL (OÆSE) endstation in the Energy Materials In-situ Laboratory Berlin (EMIL). A team led by Raul Garcia-Diez and Marcus Bär showcases the instrument’s capabilities via a proof-of-concept study on electrodeposited copper.
- Green hydrogen: A cage structured material transforms into a performant catalystClathrates are characterised by a complex cage structure that provides space for guest ions too. Now, for the first time, a team has investigated the suitability of clathrates as catalysts for electrolytic hydrogen production with impressive results: the clathrate sample was even more efficient and robust than currently used nickel-based catalysts. They also found a reason for this enhanced performance. Measurements at BESSY II showed that the clathrates undergo structural changes during the catalytic reaction: the three-dimensional cage structure decays into ultra-thin nanosheets that allow maximum contact with active catalytic centres. The study has been published in the journal ‘Angewandte Chemie’.
- Solar cells on moon glass for a future base on the moonFuture settlements on the moon will need energy, which could be supplied by photovoltaics. However, launching material into space is expensive – transporting one kilogram to the moon costs one million euros. But there are also resources on the moon that can be used. A research team led by Dr. Felix Lang of the University of Potsdam and Dr. Stefan Linke of the Technical University of Berlin have now produced the required glass from ‘moon dust’ (regolith) and coated it with perovskite. This could save up to 99 percent of the weight needed to produce PV modules on the moon. The team tested the radiation tolerance of the solar cells at the proton accelerator of the HZB.