Atomic displacements in High-Entropy Alloys examined

The supercell is randomly filled with the five elements on the fcc-lattice positions; In the starting configuration, all layers are precisely on top of each other. The displacements of all elements in the final configuration have been revealed by a simultaneous fit of the independent experimental spectra with a use of Reverse Monte Carlo simulations.

The supercell is randomly filled with the five elements on the fcc-lattice positions; In the starting configuration, all layers are precisely on top of each other. The displacements of all elements in the final configuration have been revealed by a simultaneous fit of the independent experimental spectra with a use of Reverse Monte Carlo simulations. © A.Kuzmin / University of Latvia and A. Smekhova / HZB

High-entropy alloys of 3d metals have intriguing properties that are interesting for applications in the energy sector. An international team at BESSY II has now investigated the local order on an atomic scale in a so-called high-entropy Cantor alloy of chromium, manganese, iron, cobalt and nickel. The results from combined spectroscopic studies and statistical simulations expand the understanding of this group of materials.

 

High-entropy alloys are under discussion for very different applications: Some materials from this group are suitable for hydrogen storage, others for noble metal-free electrocatalysis, radiation shielding or as supercapacitors.

The microscopic structure of high-entropy alloys is very diverse and changeable; in particular, the local ordering and the presence of different secondary phases affect significantly the macroscopic properties such as hardness, corrosion resistance and also magnetism. The so-called Cantor alloy, which consists of the elements chromium, manganese, iron, cobalt and nickel mixed in an equimolar proportion, can be considered as a suitable model system for the whole class of these materials.

Local structure studied at BESSY II

Scientists from the Federal Institute for Materials Research (BAM, Berlin), the University of Latvia in Riga, Latvia, the Ruhr University in Bochum and the HZB have now studied the local structure of this model system in detail. Using X-ray absorption spectroscopy (EXAFS) at BESSY II, they were able to precisely track each individual element and their displacements from the ideal lattice positions for this system in the most unbiased manner with the help of statistical calculations and the reverse Monte Carlo method.

Chromium shows larger displacements

In this way, they uncovered peculiarities in the local environment of each element: Despite all five elements of the alloy are distributed at the nodes of the face-centred cubic lattice and have very close statistically averaged interatomic distances (2.54 - 2.55 Å) with their nearest neighbours, larger structural relaxations were found solely for chromium atoms. Besides, no evidence of secondary phases was detected at the atomic scale. The macroscopic magnetic properties studied with conventional magnetometry at HZB CoreLab were correlated with the revealed structural relaxations of Chromium.

"The results describe the arrangement of individual atoms at the atomic scale and how the complex magnetic order that we revealed may occur," explains HZB physicist Dr. Alevtina Smekhova, who supervised the experiments at HZB.

arö

You might also be interested in

  • New monochromator optics for tender X-rays
    Science Highlight
    30.11.2022
    New monochromator optics for tender X-rays
    Until now, it has been extremely tedious to perform measurements with high sensitivity and high spatial resolution using X-ray light in the tender energy range of 1.5 - 5.0 keV. Yet this X-ray light is ideal for investigating energy materials such as batteries or catalysts, but also biological systems. A team from HZB has now solved this problem: The newly developed monochromator optics increase the photon flux in the tender energy range by a factor of 100 and thus enable highly precise measurements of nanostructured systems. The method was successfully tested for the first time on catalytically active nanoparticles and microchips.
  • Nanodiamonds can be activated as photocatalysts with sunlight
    Science Highlight
    30.11.2022
    Nanodiamonds can be activated as photocatalysts with sunlight
    Nanodiamond materials have potential as low-cost photocatalysts. But until now, such carbon nanoparticles required high-energy UV light to become active. The DIACAT consortium has therefore produced and analysed variations of nanodiamond materials. The work shows: If the surface of the nanoparticles is occupied by sufficient hydrogen atoms, even the weaker energy of blue sunlight is sufficient for excitation. Future photocatalysts based on nanodiamonds might be able to convert CO2 or N2 into hydrocarbons or ammonia with sunlight.
  • Tomography shows high potential of copper sulphide solid-state batteries
    Science Highlight
    28.11.2022
    Tomography shows high potential of copper sulphide solid-state batteries
    Solid-state batteries enable even higher energy densities than lithium-ion batteries with high safety. A team led by Prof. Philipp Adelhelm and Dr. Ingo Manke succeeded in observing a solid-state battery during charging and discharging and creating high-resolution 3D images. This showed that cracking can be effectively reduced through higher pressure.