BESSY II: Experimental verification of an exotic quantum phase in Au2Pb
The figure shows the measured energy-momentum relationship for Au2Pb. The linear behavior is evidence for a Dirac semimetal. In addition, a Lifshitz transition is observed: At temperatures 223 K and below, the electrons behave like positively charged particles, whereas at room temperature they behave like negatively charged ones. © HZB
A team of HZB has investigated the electronic structure of Au2Pb at BESSY II by angle-resolved photoemission spectroscopy across a wide temperature range: The results are in accordance with the electronic structure of a three-dimensional topological Dirac semimetal, in agreement with theoretical calculations.
The experimental data unveil some very special features linked to a Lifshitz transition. The study broadens the range of currently known materials exhibiting three-dimensional Dirac phases, and the observed Lifshitz transition demonstrates a viable mechanism to switch the charge carrier type in electric transport without the need for external doping. Moreover, the material becomes interesting as candidate for the realization of a topological superconductor.
The study which includes theory from San Sebastian and synthesis from Princeton was highlighted as Editor's Suggestion in the journal Physical Review Letters.
- Energy of charge carrier pairs in cuprate compoundsHigh-temperature superconductivity is still not fully understood. Now, an international research team at BESSY II has measured the energy of charge carrier pairs in undoped La₂CuO₄. Their findings revealed that the interaction energies within the potentially superconducting copper oxide layers are significantly lower than those in the insulating lanthanum oxide layers. These results contribute to a better understanding of high-temperature superconductivity and could also be relevant for research into other functional materials.
- Electrocatalysis with dual functionality – an overviewHybrid electrocatalysts can produce green hydrogen, for example, and valuable organic compounds simultaneously. This promises economically viable applications. However, the complex catalytic reactions involved in producing organic compounds are not yet fully understood. Modern X-ray methods at synchrotron sources such as BESSY II, enable catalyst materials and the reactions occurring on their surfaces to be analysed in real time, in situ and under real operating conditions. This provides insights that can be used for targeted optimisation. A team has now published an overview of the current state of knowledge in Nature Reviews Chemistry.
- BESSY II: Phosphorus chains – a 1D material with 1D electronic propertiesFor the first time, a team at BESSY II has succeeded in demonstrating the one-dimensional electronic properties in phosphorus. The samples consisted of short chains of phosphorus atoms that self-organise at specific angles on a silver substrate. Through sophisticated analysis, the team was able to disentangle the contributions of these differently aligned chains. This revealed that the electronic properties of each chain are indeed one-dimensional. Calculations predict an exciting phase transition to be expected as soon as these chains are more closely packed. While material consisting of individual chains with longer distances is semiconducting, a very dense chain structure would be metallic.