BESSY II: Experimental verification of an exotic quantum phase in Au2Pb
The figure shows the measured energy-momentum relationship for Au2Pb. The linear behavior is evidence for a Dirac semimetal. In addition, a Lifshitz transition is observed: At temperatures 223 K and below, the electrons behave like positively charged particles, whereas at room temperature they behave like negatively charged ones. © HZB
A team of HZB has investigated the electronic structure of Au2Pb at BESSY II by angle-resolved photoemission spectroscopy across a wide temperature range: The results are in accordance with the electronic structure of a three-dimensional topological Dirac semimetal, in agreement with theoretical calculations.
The experimental data unveil some very special features linked to a Lifshitz transition. The study broadens the range of currently known materials exhibiting three-dimensional Dirac phases, and the observed Lifshitz transition demonstrates a viable mechanism to switch the charge carrier type in electric transport without the need for external doping. Moreover, the material becomes interesting as candidate for the realization of a topological superconductor.
The study which includes theory from San Sebastian and synthesis from Princeton was highlighted as Editor's Suggestion in the journal Physical Review Letters.
- Battery research: visualisation of aging processes operandoLithium button cells with electrodes made of nickel-manganese-cobalt oxides (NMC) are very powerful. Unfortunately, their capacity decreases over time. Now, for the first time, a team has used a non-destructive method to observe how the elemental composition of the individual layers in a button cell changes during charging cycles. The study, now published in the journal Small, involved teams from the Physikalisch-Technische Bundesanstalt (PTB), the University of Münster, researchers from the SyncLab research group at HZB and the BLiX laboratory at the Technical University of Berlin. Measurements were carried out in the BLiX laboratory and at the BESSY II synchrotron radiation source.
- New instrument at BESSY II: The OÆSE endstation in EMILA new instrument is now available at BESSY II for investigating catalyst materials, battery electrodes and other energy devices under operating conditions: the Operando Absorption and Emission Spectroscopy on EMIL (OÆSE) endstation in the Energy Materials In-situ Laboratory Berlin (EMIL). A team led by Raul Garcia-Diez and Marcus Bär showcases the instrument’s capabilities via a proof-of-concept study on electrodeposited copper.
- Green hydrogen: A cage structured material transforms into a performant catalystClathrates are characterised by a complex cage structure that provides space for guest ions too. Now, for the first time, a team has investigated the suitability of clathrates as catalysts for electrolytic hydrogen production with impressive results: the clathrate sample was even more efficient and robust than currently used nickel-based catalysts. They also found a reason for this enhanced performance. Measurements at BESSY II showed that the clathrates undergo structural changes during the catalytic reaction: the three-dimensional cage structure decays into ultra-thin nanosheets that allow maximum contact with active catalytic centres. The study has been published in the journal ‘Angewandte Chemie’.