A new way to control the magnetic properties of rare earth elements
The image shows the terbium orbitals between which the excitation takes placeand a schematic sketch of the excitation process. © HZB
The special properties of rare earth magnetic materials are due to the electrons in the 4f shell. Until now, the magnetic properties of 4f electrons were considered almost impossible to control. Now, a team from HZB, Freie Universität Berlin and other institutions has shown for the first time that laser pulses can influence 4f electrons- and thus change their magnetic properties. The discovery, which was made through experiments at EuXFEL and FLASH, opens up a new way to data storage with rare earth elements.
The strongest magnets we know of are based on rare earths. Their 4f electrons are responsible for their magnetic properties: they generate a large magnetic moment that is maintained even when their chemical environment changes. This means that rare earths can be used in very different compounds and alloys without changing their special magnetic properties. Until now, it was assumed that the magnetic properties of 4f electrons could not be changed even if the material was excited with a laser pulse. But indeed, this is possible, as a team from HZB, Freie Universität Berlin, DESY, the European X-ray laser XFEL and other institutions has now shown: The spatial arrangement of the 4f electrons can be briefly switched by laser excitation. This also changes their magnetism. This effect opens up new possibilities for the fast and energy-efficient control of magnetic rare-earth materials. The work has now been published in the journal Science Advances.
Terbium studied at the X-ray lasers EuXFEL and FLASH
The team carried out experiments at the X-ray lasers EuXFEL and FLASH and analysed samples of terbium, a rare earth element with atomic number 65 and a total of 8 electrons in 4f orbitals. The sample was excited with an ultrashort laser pulse and analysed by X-ray spectroscopy. The soft X-ray radiation used in the study is able to determine the electronic structure of a material very sensitively. The experiment shows that after laser excitation, 4f electrons briefly switch to an orbital with a different spatial distribution. This is due to a scattering process with 5d electrons, which had not been considered before. The redistribution of the 4f electrons by the laser excitation causes a brief switch in their magnetic properties.
Rare earth materials as data storage devices
This controlled switching opens up new applications for rare earth materials, such as energy-efficient and fast information storage devices. Until now, rare earths have not been used in magnetic storage media. The latest storage media are so-called HAMR (Heat-Assisted Magnetic Recording) data storage devices, in which magnetic structures are heated by a laser pulse in order to be switched by a magnet. With the much stronger rare-earth magnets, an ultrashort laser pulse could now excite the 4f electrons and enable switching - an electronic effect that would be even faster and more efficient than the heating mechanism in HAMR memory.
High-resolution spectroscopy with ultrashort X-ray pulses at BESSY II
This research has been made possible by the development of accelerator-based X-ray sources for generating ultrashort X-ray pulses in recent decades. These X-ray sources allow to observe elementary processes in magnetic materials on time scales of a few femtoseconds. A femtosecond (10-15 s) is one millionth of a billionth of a second. Light travels by about a hair's breadth in 300 femtoseconds.
The work was carried out at the European X-ray laser EuXFEL and at FLASH in Hamburg. The HZB also operates a short-pulse X-ray source, which will be expanded by the end of this year specifically for experiments with high spectroscopic resolution. BESSY II will then also offer optimal conditions for this type of experiment. Berlin is one of the world's leading centres for research into ultrafast magnetic effects.
Note: The work at Freie Universität, Technische Universität, HZB, Fritz-Haber-Institut and Max-Born-Institut together with partners in Halle is funded by the German Research Foundation as part of a Transregional Collaborative Research Centre (Transregio-SFB 227 "Ultrafast Spin Dynamics").
- Electrocatalysts: New model for charge separation at the solid-liquid interfaceHydrogen is at the heart of the transition to carbon neutrality, as both an energy carrier and a reagent for green chemistry. However, large-scale production of hydrogen via electrolysis, as well as the production of many other chemical products, requires significantly cheaper and more efficient catalysts. A precise understanding of the electrochemical processes that take place at the interface between the solid catalyst and the liquid medium is highly useful for developing better electrocatalysts. In the journal Nature Communications, an European team has now presented a powerful model that determines charge separation at the interface, the formation of the electric double layer and local electric potential variations, and the resulting influence on the catalytic activity.
- Environmental Chemistry at BESSY II: Radicals in waterwaysHow do radicals form in aqueous solutions when exposed to UV light? This question is important for health research and environmental protection, for example with regard to the overfertilisation of water bodies by intensive agriculture. A team at BESSY II has now developed a new method of investigating hydroxyl radicals in solution. By using a clever trick, the scientists gained surprising insights into the reaction pathway.
- Theory meets practice – We’re heading back to HTW Berlin!The HZB’s BIPV consultancy office (BAIP) is once again coordinating and delivering the lecture series “Building-Integrated Photovoltaics”.