Al-Ashouri, A.; Magomedov, A.; Roß, M.; Jost, M.; Talaikis, M.; Chistiakova, G.; Bertram, T.; Márquez, J.A.; Köhnen, E.; Kasparavicius, E.; Levcenco, S.; Gil-Escrig, L.; Hages, C.; Schlatmann, R.; Rech, B.; Malinauskas, T.; Unold, T.; Kaufmann, C.A.; Korte, L.; Niaura, G.; Getautis, V.; Albrecht, S.: Conformal monolayer contacts with lossless interfaces for perovskite single junction and monolithic tandem solar cells. Energy & Environmental Science 12 (2019), p. 3356-3369
Open Accesn Version

The rapid rise of perovskite solar cells (PSCs) is increasingly limited by the available charge-selective contacts. This work introduces two new hole-selective contacts for p–i–n PSCs that outperform all typical p-contacts in versatility, scalability and PSC power-conversion efficiency (PCE). The molecules are based on carbazole bodies with phosphonic acid anchoring groups and can form self-assembled monolayers (SAMs) on various oxides. Besides minimal material consumption and parasitic absorption, the self-assembly process enables conformal coverage of arbitrarily formed oxide surfaces with simple process control. The SAMs are designed to create an energetically aligned interface to the perovskite absorber without non-radiative losses. For three different perovskite compositions, one of which is prepared by co-evaporation, we show dopant-, additive- and interlayer-free PSCs with stabilized PCEs of up to 21.1%. Further, the conformal coverage allows to realize a monolithic CIGSe/perovskite tandem solar cell with as-deposited, rough CIGSe surface and certified efficiency of 23.26% on an active area of 1 cm2. The simplicity and diverse substrate compatibility of the SAMs might help to further progress perovskite photovoltaics towards a low-cost, widely adopted solar technology.