Schäfer, B.; Rajnak, C.; Salitros, I.; Fuhr, O.; Klar, D.; Schmitz-Antoniak, C.; Weschke, E.; Wende, H.; Ruben, M.: Room temperature switching of a neutral molecular iron(II) complex. Chemical Communications 49 (2013), p. 10986-10988
10.1039/c3cc46624h
Abstract:
Abrupt room temperature switching (Tc = 295 K with a 5 K hysteresis) was achieved in a neutral FeII complex based on a 2-(1H-pyrazol-1-yl)- 6-(1H-tetrazol-5-yl)pyridine ligand. Structural characterization and spin crossover study (via SQUID magnetometry, photoexcitation and X-ray absorption spectroscopy) in the solid state are described.