HZB part of new metal oxide/water systems CRC

A team of HZB researchers is part of the new collaborative research center, "Molecular insights into metal oxide/water systems" funded by the German Research Association. As part of this CRC, Dr. Bernd Winter of Prof. Dr. Emad Aziz's junior research group will be studying metal ions and metal oxide complexes in aqueous solution at BESSY II.

Spokesman of the CRC is Prof. Dr. Christian Limberg of the Humboldt University Berlin. Other partners include the Freie Universität Berlin, the Technical University of Berlin, Potsdam University, the Federal Institute for Materials Research and Testing Berlin, and the Fritz Haber Institute of the Max Planck Society Berlin.

The researchers are using a liquid microjet under vacuum conditions allowing them to obtain measurements of aqueous solutions using photoelectron spectroscopy at BESSY II. Their measurements allow for conclusions to be drawn on the binding energies and on electronic relaxation processes and thus provide clues as to the interaction between metal oxide complexes and the surrounding water molecules. In addition, the technique can be used to determine precursor molecules that will go on to form larger metal-oxo networks.

These insights are key to our ability to synthesize metal oxides for specific applications, which is typically done in aqueous solution. The reason being that metal oxides are highly interesting in terms of their technological applicability: they upgrade building materials and special types of glass, improve the properties of ceramic implants in medicine, and are considered interesting candidates for use in fuel cells, solar cells, microelectronics, and as novel kinds of catalysts.

Spokesman of the CRC "Molecular insights into metal oxide/water systems: Structural evolution, interface, and resolution" is Prof. Dr. Christian Limberg of the Humboldt University Berlin. Other partners include the Freie Universität Berlin, the Technical University of Berlin, Potsdam University, the Federal Institute for Materials Research and Testing Berlin, and the Fritz Haber Institute of  the Max Planck Society Berlin. Together, the participating research groups are hoping to investigate different fundamental processes relating to metal oxide interactions with water on all relevant length scales using a combination of chemical synthesis and cutting-edge experimental and theoretical methods. In late November 2013, the German Research Association established nine new collaborative research centers (CRC's), which, through mid-2017, will receive federal funding in the amount of 64.4 million Euros total.

arö

  • Copy link

You might also be interested in

  • Battery research: visualisation of aging processes operando
    Science Highlight
    29.04.2025
    Battery research: visualisation of aging processes operando
    Lithium button cells with electrodes made of nickel-manganese-cobalt oxides (NMC) are very powerful. Unfortunately, their capacity decreases over time. Now, for the first time, a team has used a non-destructive method to observe how the elemental composition of the individual layers in a button cell changes during charging cycles. The study, now published in the journal Small, involved teams from the Physikalisch-Technische Bundesanstalt (PTB), the University of Münster, researchers from the SyncLab research group at HZB and the BLiX laboratory at the Technical University of Berlin. Measurements were carried out in the BLiX laboratory and at the BESSY II synchrotron radiation source.
  • New instrument at BESSY II: The OÆSE endstation in EMIL
    Science Highlight
    23.04.2025
    New instrument at BESSY II: The OÆSE endstation in EMIL
    A new instrument is now available at BESSY II for investigating catalyst materials, battery electrodes and other energy devices under operating conditions: the Operando Absorption and Emission Spectroscopy on EMIL (OÆSE) endstation in the Energy Materials In-situ Laboratory Berlin (EMIL). A team led by Raul Garcia-Diez and Marcus Bär showcases the instrument’s capabilities via a proof-of-concept study on electrodeposited copper.
  • Green hydrogen: A cage structured material transforms into a performant catalyst
    Science Highlight
    17.04.2025
    Green hydrogen: A cage structured material transforms into a performant catalyst
    Clathrates are characterised by a complex cage structure that provides space for guest ions too. Now, for the first time, a team has investigated the suitability of clathrates as catalysts for electrolytic hydrogen production with impressive results: the clathrate sample was even more efficient and robust than currently used nickel-based catalysts. They also found a reason for this enhanced performance. Measurements at BESSY II showed that the clathrates undergo structural changes during the catalytic reaction: the three-dimensional cage structure decays into ultra-thin nanosheets that allow maximum contact with active catalytic centres. The study has been published in the journal ‘Angewandte Chemie’.