Two Freigeist Fellows interweave their research at HZB
Fabian Weber (right) is investigating the dynamics of electron processes within graphene-oxide quantum dots as a member of the team headed by Dr. Annika Bande (left). Quantum dots like these as catalysts could help make solar water splitting more efficient. Using Weber’s theoretical model, a much greater amount of information can be obtained from the empirical data gathered by the group headed by Dr. Tristan Petit. © HZB
Initial calculations show how the electron density changes over a graphene oxide nanoparticle in solution. The electron density is below average in the areas shown in red, while it is above average in the blue areas. The graphene particle is made of carbon atoms (black) that bind in some places to the oxygen (red) , or in some to the hydrogen (white). © Fabian Weber
Two Freigeist Fellows are conducting research at the HZB Institute for Methods of Material Development through support received from the Volkswagen Foundation. Theoretical chemist Dr. Annika Bande is modelling fast electron processes, while Dr. Tristan Petit is investigating carbon nanoparticles. Annika Bande has now been awarded an ancillary grant of an additional 150,000 Euros from the Volkswagen Foundation to fund another doctoral student position for three years. The doctoral research will connect the two Freigeist research projects with one another.
Doctoral student Fabian Weber is working in Bande’s theory group and will be carrying out electron transfer calculations in a material system being investigated by Petit and his team. “We are concentrating on a special class of what are known as quantum dots, made of graphene oxide nanoparticles”, explains Weber. The group headed by Petit will be analysing nano-graphene oxide using various spectroscopic methods.
Catalyst for solar hydrogen
This is because graphene-oxide nanoparticles are good catalysts, as well for splitting water using solar energy and generating hydrogen. Hydrogen is a versatile energy medium that can be utilised as fuel or to generate environmentally friendly electric power in a fuel cell.
Understanding the system
With the help of theoretical modelling, the empirical data obtained on nanoparticles of graphene oxides can yield considerably more information and also new insights into the ultrafast dynamics of hydrogen bonding. “We start with existing theories and see how we can use them to model exactly what happens with the transfer of electrons during a catalytic reaction”, explains Annika Bande. “We are able to compare our ideas directly with the empirical results in this research project and really come to better understand the system. In addition, the topic is extremely important – not just for purposes of pure research, but also for ensuring society’s energy supply.”
- How carbonates influence CO2-to-fuel conversionResearchers from the Helmholtz Zentrum Berlin (HZB) and the Fritz Haber Institute of the Max Planck Society (FHI) have uncovered how carbonate molecules affect the conversion of CO2 into valuable fuels on gold electrocatalysts. Their findings reveal key molecular mechanisms in CO2 electrocatalysis and hydrogen evolution, pointing to new strategies for improving energy efficiency and reaction selectivity.
- Peat as a sustainable precursor for fuel cell catalyst materialsIron-nitrogen-carbon catalysts have the potential to replace the more expensive platinum catalysts currently used in fuel cells. This is shown by a study conducted by researchers from the Helmholtz-Zentrum Berlin (HZB), Physikalisch-Technische Bundesanstalt (PTB) and universities in Tartu and Tallinn, Estonia. At BESSY II, the team observed the formation of complex microstructures within various samples. They then analysed which structural parameters were particularly important for fostering the preferred electrochemical reactions. The raw material for such catalysts is well decomposed peat.
- Helmholtz Investigator Group on magnonsDr Hebatalla Elnaggar is setting up a new Helmholtz Investigator Group at HZB. At BESSY II, the materials scientist will investigate so-called magnons in magnetic perovskite thin films. The aim is to lay the foundations for future terahertz magnon technology: magnonic devices operating in the terahertz range could process data using a fraction of the energy required by the most advanced semiconductor devices, and at speeds up to a thousand times faster.