Catalyst research for solar fuels: Amorphous molybdenum sulphide works best
The SEM shows Molybdenum sulfide deposited at room temperature. © HZB
Experimental data show, how catalytically active nanoislands of MoS2 are formed. © HZB
Efficient and inexpensive catalysts will be required for production of hydrogen from sunlight. Molybdenum sulphides are considered good candidates. A team at HZB has now explained what processes take place in molybdenum sulphides during catalysis and why amorphous molybdenum sulphide works best. The results have been published in the journal ACS Catalysis.
Sunlight not only can be used to generate electricity, but also hydrogen. Hydrogen is a climate-neutral fuel that stores energy chemically and releases it again when needed, either directly via combustion (where only water is produced) or as electrical energy in a fuel cell. But to produce hydrogen from sunlight, catalysts are needed that accelerate the electrolytic splitting of water into oxygen and hydrogen.
Molybdenum sulphide layers explored
One particularly interesting class of catalysis materials for hydrogen generation are the molybdenum sulphides (MoSx). They are considerably cheaper than catalysts made of platinum or ruthenium. In a comprehensive study, a team led by Prof. Dr. Sebastian Fiechter at the HZB Institute for Solar Fuels has now produced and investigated a series of molybdenum sulphide layers. The samples were deposited at different temperatures on a substrate, from room temperature to 500 °C. The morphology and structure of the layers change with increasing deposition temperature (see SEM images). While crystalline regions are formed at higher temperatures, molybdenum sulphide deposited at room temperature is amorphous. It is precisely this amorphous molybdenum sulphide deposited at room temperature that has the highest catalytic activity.
Amorphous MoSx layers emit H2S initially
A catalyst made of amorphous molybdenum sulphide not only releases hydrogen during electrolysis of water, but also hydrogen sulphide gas in the initial phase. The sulphur for this had to come from the catalyst material itself, and astonishingly – this process improves the catalytic activity of the molybdenum sulphide considerably. Fiechter and his team have now taken a close look at this and are proposing an explanation for their findings.
Spectrocopic methods show what happens
They investigated amorphous molybdenum sulphide samples used as catalysts in water splitting using various spectroscopic methods, including in situ Raman spectroscopy. These measurements show that nanocrystalline regions of molybdenum disulphide (MoS2) form over time in amorphous molybdenum sulphide samples as a result of sulphur escaping from molybdenum clusters. At the same time, less and less hydrogen sulphide is produced, so that hydrogen production becomes dominant.
Islands of nanocrystalline MoS2
“We can deduce from the data that low-sulphur areas with islands of nanocrystalline MoS2 form as a result of the sulphur escaping. The islands act as catalytically active particles”, explains Fanxing Xi, who carried out the measurements as part of her doctoral work. “These insights can contribute to further improving the catalytic activity and stability of this promising catalyst for hydrogen generation in the water-splitting process, and coupling the material to an electrolyser operating solely on sunlight”, said Fiechter.
To the publication in ACS Catalysis (2019): Structural Transformation Identification of Sputtered Amorphous MoSx as an Efficient Hydrogen-Evolving Catalyst during Electrochemical Activation; Fanxing Xi, Peter Bogdanoff, Karsten Harbauer, Paul Plate, Christian Höhn, Jörg Rappich, Bin Wang, Xiaoyu Han, Roel van de Krol, and Sebastian Fiechter
Doi: 10.1021/acscatal.8b04884
- New contact material boosts the efficiency of perovskite solar cellsA newly developed material for the electron contact improves the efficiency of single perovskite solar cells and perovskite/silicon tandem solar cells. The new material is based on a carborane molecule. It offers several advantages over the standard material C60, as shown by the study led by Steve Albrecht’s team. The new material has since been patented and is already commercially available.
- BESSY II: New sample environment allows glimpse into thermocatalytic processesA novel measurement cell allows, for the first time, soft and hard X-ray investigations under high pressures of up to 20 bar and temperatures of up to 400°C. This provides new insights into thermocatalytic processes, such as the Fischer-Tropsch synthesis for producing synthetic fuels. The development of the measurement cell is considered a significant achievement within the Care-O-Sene project.
- From Colombia to Berlin: Finding My Way in a New WorldIt was almost 11 p.m. when I arrived in Berlin. After a long journey from Colombia, all I wanted was to get to my accommodation, take a shower, and finally sleep.
Instead, I missed my train. Thinking it would follow the same route as the previous one as it would in my hometown of Medellín I confidently boarded the next train. About twenty minutes later, I realized something was wrong. I was heading in the wrong direction.
As if that was not enough, my phone battery was almost empty. Suddenly, I found myself alone in a city I had never visited before, late at night, speaking a language I did not understand, with no idea how to get back.
This was not how I had imagined the beginning of my first international trip....