HZB doctoral student won Young Scientist Award
Silvio Künstner (2nd from right) was awarded with five other young researchers at the EUROISMAR 2019 conference. © EUROISMAR 2019
The "Journal of Magnetic Resonance" and the ISMAR (International Society of Magnetic Resonance) awarded Silvio Künstner with a Young Scientist Award for his talk "Rapid Scan EPR-on-a-chip". The doctoral student from the HZB institute for Nanospectroscopy presented current progress in the development of a miniaturized electron spin resonance spectrometer.
Electron spin resonance or electron paramagnetic resonance (EPR) provides detailed information about the inner structure of materials, down to an atomic level. This understanding of the material is essential for research in the field of renewable energies, such as efficient solar cells or battery electrodes. Of particular importance are experiments under real process conditions (operando measurements).
The chip-sized miniaturized EPR spectrometer presented by Silvio Künstner is so small that it can be inserted directly inside the sample. This improvement simplifies the handling of operando measurements significantly. In addition, EPR-on-a-chip is far more sensitive than conventional instruments. Next to the Helmholtz Zentrum Berlin, the University of Stuttgart, the Max Planck Institute for Chemical Energy Conversion, as well as the Karlsruhe Institute of Technology (KIT) and Bruker (as part of the BMBF's "EPRoC" project) are involved in the research of the miniature spectrometer.
Silvio Künstner received the Young Scientist Award at the ISMAR EUROMAR Joint Conference (25 - 30 August 2019) in Berlin, which was attended by more than 1000 scientists. At the world's largest conference in this field, the HZB was involved as co-organizer. Furthermore, researchers of the Helmholtz-Zentrum Berlin participated with more than ten presentations.
- Battery research: visualisation of aging processes operandoLithium button cells with electrodes made of nickel-manganese-cobalt oxides (NMC) are very powerful. Unfortunately, their capacity decreases over time. Now, for the first time, a team has used a non-destructive method to observe how the elemental composition of the individual layers in a button cell changes during charging cycles. The study, now published in the journal Small, involved teams from the Physikalisch-Technische Bundesanstalt (PTB), the University of Münster, researchers from the SyncLab research group at HZB and the BLiX laboratory at the Technical University of Berlin. Measurements were carried out in the BLiX laboratory and at the BESSY II synchrotron radiation source.
- New instrument at BESSY II: The OÆSE endstation in EMILA new instrument is now available at BESSY II for investigating catalyst materials, battery electrodes and other energy devices under operating conditions: the Operando Absorption and Emission Spectroscopy on EMIL (OÆSE) endstation in the Energy Materials In-situ Laboratory Berlin (EMIL). A team led by Raul Garcia-Diez and Marcus Bär showcases the instrument’s capabilities via a proof-of-concept study on electrodeposited copper.
- Green hydrogen: A cage structured material transforms into a performant catalystClathrates are characterised by a complex cage structure that provides space for guest ions too. Now, for the first time, a team has investigated the suitability of clathrates as catalysts for electrolytic hydrogen production with impressive results: the clathrate sample was even more efficient and robust than currently used nickel-based catalysts. They also found a reason for this enhanced performance. Measurements at BESSY II showed that the clathrates undergo structural changes during the catalytic reaction: the three-dimensional cage structure decays into ultra-thin nanosheets that allow maximum contact with active catalytic centres. The study has been published in the journal ‘Angewandte Chemie’.