New insights into the structure of organic-inorganic hybrid perovskites
Movie showing the 3D crystal structure as a function of the cell modulation phase. (grey: Pb, brown: Br, black: C, blue: N; white: H) © HZB
10.00 sIn photovoltaics, organic-inorganic hybrid perovskites have made a rapid career. But many questions about the crystalline structure of this surprisingly complex class of materials remain unanswered. Now, a team at HZB has used four-dimensional modelling to interpret structural data of methylammonium lead bromide (MAPbBr3), identifying incommensurable superstructures and modulations of the predominant structure. The study is published in the ACS Journal of Physical Chemistry Letters and was selected by the editors as an Editor's Choice.
Organic-inorganic hybrid perovskites have been intensively investigated for use in solar cells for about ten years. Thin films of such perovskites are inexpensive and already achieve high efficiencies. In addition, they can be perfectly combined with common solar cell materials such as silicon to form tandem cells. At the beginning of 2020, an HZB team was able to achieve a world record efficiency of 29.15 % with a tandem cell made of perovskite and silicon.
But despite the most intensive research, it has not yet been possible to precisely elucidate the crystal structures with their diverse modulations and superstructures as a function of temperature, even for the best-known perovskite compounds such as methylammonium and formamidinium lead halide.
Now, a team at HZB has analysed structural data of methylammonium lead bromide (MAPbBr3) with a novel model. Postdoc Dr. Dennis Wiedemann used a model that takes a fourth dimension into account in addition to the three spatial dimensions. The structural data were measured at a temperature of 150 Kelvin at the University of Columbia.
"The problem in these hybrid perovskites is the fact that the different modifications do not differ significantly in energy, so that even small temperature differences are sufficient to trigger phase transitions," explains Dr. Joachim Breternitz, co-author of the study. The data on the crystal structure therefore show an average value over many elementary cells, so that modulations and superstructures are not always recognisable. The new model explains the incommensurable superstructures observed in MAPbBr3 in a small temperature window around 150 K, which do not have the same periodicity as the crystal lattice. This complex structure comes from tilts and shifts in the crystal structure. "The new model will also provide more detailed insights into the modulated structures of other perovskite compounds," says Breternitz.
- MXene as a frame for 2D water films shows new propertiesAn international team led by Dr. Tristan Petit and Prof. Yury Gogotsi has investigated MXene with confined water and ions at BESSY II. In the MXene samples, a transition between localised ice clusters to quasi-two-dimensional water films was identified by increasing temperature. The team also discovered that the intercalated water structure drives a reversible transition from metallic to semiconducting behaviour of the MXene film. This could enable the development of novel devices or sensors based on MXenes.
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- Self assembling monolayer can improve lead-free perovskite solar cells tooTin perovskite solar cells are not only non-toxic, but also potentially more stable than lead-containing perovskite solar cells. However, they are also significantly less efficient. Now, an international team has succeeded in reducing losses in the lower contact layer of tin perovskite solar cells: The scienstists identified chemical compounds that self-assemble into a molecular layer that fits very well with the lattice structure of tin perovskites. On this monolayer, tin perovskite with excellent optoelectronic quality can be grown, which increases the performance of the solar cell.