Perovskite solar cells: Hydrogen bonds measured

Orbital hybridization between organic and inorganic components of MAPI perovskite in ground-state geometry.

Orbital hybridization between organic and inorganic components of MAPI perovskite in ground-state geometry. © HZB

The evaluation of X-ray measurements on methylammonium perovskite semiconductors now shows what role hydrogen bonds play in these materials. In addition, the HZB team showed that radiation damage by soft X-rays to this sensitive class of materials occurs even faster than often expected. Both results provide important information for perovskites materials research for solar cells.

Metal halide perovskite (MHP) solar cells are being rapidly and intensively developed in labs around the world. This class of materials is inexpensive, easy to process, and has achieved efficiencies of over 20 percent after only a few years of development. By varying the chemical composition, the optoelectronic properties can be precisely matched to the sunlight and to the particular application. The highest efficiencies are achieved by hybrid perovskites containing methylammonium cations (MA), but the presence of MA is also associated with instability.

Signature of hydrogen bonds unveiled

Now, an international collaboration including the HZB’s Department Interface Design, led by Marcus Bär, has used soft x-ray emission spectroscopy (XES) combined with advanced theoretical modelling to gain new insights into the electronic structure and, in particular, the hydrogen bonds within methylammonium-lead-iodide perovskite films. The samples came from the laboratory of perovskite pioneer Henry Snaith, Oxford University, and the measurements were performed during (pre-pandemic) beamtime at the Advanced Light Source at Lawrence Berkeley National Laboratory. They have now published the results of the study which draws on modelling of the electronic structure and the ultrafast movement of hydrogen atoms within the structure by Swedish collaborator Michael Odelius, Stockholm University.

"By combining site- and element-specific soft X-ray spectroscopic measurements with molecular dynamics and density functional theory modelling, we have now been able to provide new insights into the electronic structure and dynamics of the organic MHP component," says Regan Wilks, HZB physicist and first author of the study. In particular, the group succeeded in detecting spectral signatures of the hydrogen bonds between the organic methylammonium molecule and the inorganic framework of the perovskite, and saw evidence for significant dynamic changes in the structure induced during the measurement on the femtosecond time scale.  

Speedy damage

To separate these ultrafast signals from the effects of damage by the high intensity synchrotron x-ray beam, the group also thoroughly characterized these damage effects, showing that they can occur on the time scale of 100 ms, much faster than the duration of a standard experiment. The speed of this damage effect means that it can in effect be “invisible” unless the experiment is conducted with great care – by the time the measurement begins to yield results, the damage is already done. "It’s important to document these effects in a publication, even if it is not the most scientifically interesting result, because it can be very important information to other groups who might want to perform similar experiments or confirm our results," Wilks points out. To avoid the radiation damage and thus artefacts during the measurement, the sample under the soft X-ray beam was moved perpendicular to the photon beam during the measurement keeping the irradiation of any point to a fraction of a second.


You might also be interested in

  • Spintronics at BESSY II: Domain walls in magnetic nanowires
    Science Highlight
    Spintronics at BESSY II: Domain walls in magnetic nanowires
    Magnetic domains walls are known to be a source of electrical resistance due to the difficulty for transport electron spins to follow their magnetic texture. This phenomenon holds potential for utilization in spintronic devices, where the electrical resistance can vary based on the presence or absence of a domain wall. A particularly intriguing class of materials are half metals such as La2/3Sr1/3MnO3 (LSMO) which present full spin polarization, allowing their exploitation in spintronic devices. Still the resistance of a single domain wall in half metals remained unknown. Now a team from Spain, France and Germany has generated a single domain wall on a LSMO nanowire and measured resistance changes 20 times larger than for a normal ferromagnet such as Cobalt.
  • Bauwerkintegrierte Photovoltaik (BIPV) - Lösungen & Dienstleistungen
    Bauwerkintegrierte Photovoltaik (BIPV) - Lösungen & Dienstleistungen
    Im Rahmen der The smarter-e Europe/Intersolar Europe 2023 findet eine Vortragssession organisiert von der Allianz BIPV und dem Solarenergieförderverein Bayern e.V. zum Thema "Bauwerkintegrierte Photovoltaik (BIPV) - Lösungen und Dienstleistungen" statt.

    Datum: 14. Juni 2023, 15:30 -17:15 Uhr
    Ort:       Messe München, Halle A3, Stand A3.150/151

  • Fractons as information storage: Not yet quite tangible, but close
    Science Highlight
    Fractons as information storage: Not yet quite tangible, but close
    A new quasiparticle with interesting properties has appeared in solid-state physics - but so far only in the theoretical modelling of solids with certain magnetic properties. An international team from HZB and Freie Universität Berlin has now shown that, contrary to expectations, quantum fluctuations do not make the quasiparticle appear more clearly, but rather blur its signature.