Predicting solar cell performance from terahertz and microwave spectroscopy
In the femtosecond laser laboratory of Dr. Dennis Friedrich at HZB, the transport properties of semiconductors can be determined using terahertz or microwave spectroscopy. For this purpose, a laser light pulse first excites the charge carriers in the material, which are then irradiated with electromagnetic waves (either THz or Microwave) and absorb some of them. © HZB
Many semiconducting materials are possible candidates for solar cells. In recent years, perovskite semiconductors in particular have attracted attention, as they are both inexpensive and easy to process and enable high efficiencies. Now a study with 15 participating research institutions shows how terahertz (TRTS) and microwave spectroscopy (TRMC) can be used to reliably determine the mobility and lifetime of the charge carriers in new semiconducting materials. Using these measurement data it is possible to predict the potential efficiency of the solar cell in advance and to classify the losses in the finished cell.
The most important properties of a semiconductor to be used as a solar cell include the mobility and lifetime of electrons and "holes". Both quantities can be measured without contacts with spectroscopic methods using terahertz or microwave radiation. However, measurement data found in literature often differ by orders of magnitude. This has made it difficult to use them for reliable assessments of material quality.
Reference samples measured
"We wanted to get to the bottom of these differences, and contacted experts from a total of 15 international laboratories to analyse typical sources of error and problems with the measurements," says Dr. Hannes Hempel from the HZB team led by Dr. Thomas Unold. The HZB physicists sent reference samples produced by the team of Dr. Martin Stolterfoht at University Potsdam to each laboratory with the perovskite semiconductor compound (Cs,FA,MA)Pb(I,Br)3) optimised for stability.
Better data for better prediction
One result of the joint work is the significantly more precise determination of the transport properties with terahertz or microwave spectroscopy. "We could identify some neuralgic points that have to be considered before the actual measurements takes place, which allows us to arrive at significantly better agreement of the results," Hempel emphasises.
Another result of the study: With reliable measurement data and a more advanced analysis, the characteristics of the solar cell can also be calculated more precisely. "We believe that this analysis is of great interest for photovoltaic research, because it predicts the maximum possible efficiency of the material in a solar cell and reveals the influence of various loss mechanisms, such as transport barriers," says Unold. This applies not only to the material class of perovskite semiconductors, but also to other new semiconducting materials, which can thus be tested more quickly for their potential suitability.
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- BESSY II: New sample environment allows glimpse into thermocatalytic processesA novel measurement cell allows, for the first time, soft and hard X-ray investigations under high pressures of up to 20 bar and temperatures of up to 400°C. This provides new insights into thermocatalytic processes, such as the Fischer-Tropsch synthesis for producing synthetic fuels. The development of the measurement cell is considered a significant achievement within the Care-O-Sene project.
- Precision interface chemistry pushes perovskite solar cells beyond 26% efficiencyAn international research collaboration has developed a new molecular strategy for controlling one of the most critical interfaces in perovskite solar cells. The resulting solar cells reached a power conversion efficiency of 26.19% in the n i p architecture, together with strong operational stability under prolonged illumination and elevated temperature. The results have been published in the Journal of the American Chemical Society.