Kölbach, M.; Pereira, I.; Harbauer, K.; Plate, P.; Höflich, K.; Berglund, S.; Friedrich, D.; Van de Krol, R.; Abdi, F.: Revealing the Performance-Limiting Factors in α-SnWO4 Photoanodes for Solar Water Splitting. Chemistry of Materials 30 (2018), p. 8322-8331
10.1021/acs.chemmater.8b03883
Open Accesn Version

Abstract:
α-SnWO4 is an n-type metal oxide semiconductor that has recently attracted attention as a top absorber material in a D4-tandem device for highly efficient solar water splitting due to the combination of an ideal bandgap (~1.9 eV) and a relatively negative photocurrent onset potential (~0 V vs. RHE). However, up to now, α-SnWO4 photoanodes have not shown high photoconversion efficiencies for reasons that have not yet been fully elucidated. In this work, phase-pure α-SnWO4 films are successfully prepared by pulsed laser deposition. The favorable band alignment is confirmed and key carrier transport properties, such as charge carrier mobility, lifetime, and diffusion length are reported for the first time. In addition, a hole-conducting NiOx layer is introduced to protect the surface of the α-SnWO4 films from oxidation. The NiOx layer is found to increase the photocurrent for sulfite oxidation by a factor of ~100, setting a new benchmark for the photocurrent and quantum efficiency of α-SnWO4. These results provide important insights into the photoelectrochemical properties and limitations of α-SnWO4 and point toward new strategies to further improve the performance of this promising material.