Poster award for MatSEC PhD student at the MRS Spring Meeting

At the MRS Spring Meeting in San Francisco, Kai Neldner was awarded for his poster contribution.

At the MRS Spring Meeting in San Francisco, Kai Neldner was awarded for his poster contribution.

The poster contribution of Kai Neldner (HZB-Department Crystallography) was awarded a poster price of the Symposium "Thin-Film Compound Semiconductors" at the MRS Spring Meeting in San Francisco. Kai Neldner, a PhD student in the HZB Graduate School "Materials for Solar Energy Conversion" (MatSEC) has presented results on structural properties of Kesterites (Cu2ZnSnS4 - CZTS) in relation to its stoichiometry deviations.

The best performances of Kesterite-based thin film solar cells with converion efficiencies of 12.6% were obtained with an absorber material quite different from the stoichiometric compound Cu2ZnSn(S,Se)4, especially with a Cu-poor/Zn-rich composition. Because the electronic properties of a semiconductor are strongly related to its crystal structure, it is of great interest to study the nature of stoichiometry deviations systematically and to connect issues such as phase existence limits.

Kai Neldner synthesized off-stoichiometric CZTS powder samples by solid state reaction and studied the structural and chemical properties. He applied different analytical methods using also the HZB's large scale facilities BESSY II and BER II. With his obtained results he was able to prove  that CZTS can accomodate deviations from stoichiometry without collapse of the kesterite type structure by the formation of certain point defects. Thus the crystal structure of CZTS can self-adapt to Cu-poor/Zn-rich and Cu-rich/Zn-poor compositions without any structural changes except in terms of the cation distribution.

Susan Schorr

  • Copy link

You might also be interested in

  • A duo for BESSY III light source
    News
    10.03.2026
    A duo for BESSY III light source
    Since 1 March 2026, Renske van der Veen and Andreas Jankowiak have formed the leadership team of BESSY III. Together, they will drive forward HZB’s central project: the planning and realisation of BESSY III light source in Berlin-Adlershof. Here, they talk about their motivation, the next steps, and why BESSY III is a a cross-generational project.
  • Catalysis research at HZB gets new facility
    News
    06.03.2026
    Catalysis research at HZB gets new facility
    As part of the CatLab project, HZB has acquired a unique facility for measuring the catalytic performance of thin-film catalysts. Built by ILS in Adlershof, it has now been delivered. The facility consists of a total of eight chemical reactors in which catalytic systems can be tested. At over €2.5 million, this is the largest single investment in the CatLab project.
  • Protein crystallography at BESSY II: faster, better and more and more automatic
    Interview
    04.03.2026
    Protein crystallography at BESSY II: faster, better and more and more automatic
    Many diseases are linked to malfunctions of proteins in the organism. The three-dimensional architecture of these molecules is often highly complex, but it can provide valuable insights into biological processes and the development of drugs. X-ray diffraction at the MX beamlines of BESSY II can be used to decipher the 3D structure of proteins. To date, more than 5000 structures have been solved at the three MX beamlines. Here, we present a review and an outlook with  Manfred Weiss, head of the research group for macromolecular crystallography.