From Dublin to Berlin as a Humboldt Research Fellow
Dr. Katarzyna Siewierska joins the group of Prof. Alexander Föhlisch as a postdoctoral Humboldt Research fellow. © Privat
Dr. Katarzyna Siewierska joins the group of Prof. Alexander Föhlisch as a postdoctoral Humboldt Research fellow. She has earned her PhD at Trinity College in Dublin, Ireland, and plans in the next two years to explore the electronic structure and spin dynamics of half-metallic thin films at BESSY II. Understanding these spintronic materials better may pave the way for more energy efficient data storage technologies.
Katarzyna Siewierska describes her project herself very clearly:
A dream material for spintronics would have low/zero net moment, no stray fields, high resonance frequency, low damping and be 100 % spin polarised, combining the best features of a metallic ferromagnet and an antiferromagnet. Such materials have the potential to revolutionise magnetic data storage and data transfer. They are called zero moment half-metals (ZMHM). This new material class was theoretically predicted in 1995, but it took almost 20 years before the first member, Mn2RuxGa, was demonstrated in 2014.
Up to now, the few other examples of ZMHMs are all Mangan-based Heusler alloys, revealing the critical role of Mangan for obtaining the uniquely desirable combination of properties. It is of great research interest to understand why this is so.
Synchrotron radiation-based techniques provide important insights into the electronic and magnetic properties of spintronic materials due to their sensitivity to spin and crystal structure, coupled with element specificity.
In this work we will combine the expertise of researchers at BESSY II in resonant inelastic X-ray scattering (RIXS) with the high quality ZMHM thin films I fabricated and studied at Trinity College Dublin (TCD) during my thesis. The goal is to confirm the half-metallic band structure of MRG, explore the spin-lattice relaxation and investigating magnon excitations to obtain information about their dispersion and the energy of ferrimagnetic resonance modes.
- Battery research: visualisation of aging processes operandoLithium button cells with electrodes made of nickel-manganese-cobalt oxides (NMC) are very powerful. Unfortunately, their capacity decreases over time. Now, for the first time, a team has used a non-destructive method to observe how the elemental composition of the individual layers in a button cell changes during charging cycles. The study, now published in the journal Small, involved teams from the Physikalisch-Technische Bundesanstalt (PTB), the University of Münster, researchers from the SyncLab research group at HZB and the BLiX laboratory at the Technical University of Berlin. Measurements were carried out in the BLiX laboratory and at the BESSY II synchrotron radiation source.
- New instrument at BESSY II: The OÆSE endstation in EMILA new instrument is now available at BESSY II for investigating catalyst materials, battery electrodes and other energy devices under operating conditions: the Operando Absorption and Emission Spectroscopy on EMIL (OÆSE) endstation in the Energy Materials In-situ Laboratory Berlin (EMIL). A team led by Raul Garcia-Diez and Marcus Bär showcases the instrument’s capabilities via a proof-of-concept study on electrodeposited copper.
- Green hydrogen: A cage structured material transforms into a performant catalystClathrates are characterised by a complex cage structure that provides space for guest ions too. Now, for the first time, a team has investigated the suitability of clathrates as catalysts for electrolytic hydrogen production with impressive results: the clathrate sample was even more efficient and robust than currently used nickel-based catalysts. They also found a reason for this enhanced performance. Measurements at BESSY II showed that the clathrates undergo structural changes during the catalytic reaction: the three-dimensional cage structure decays into ultra-thin nanosheets that allow maximum contact with active catalytic centres. The study has been published in the journal ‘Angewandte Chemie’.