Solid Liquid Analysis System



Wu, Q.; Alkemper, A.; Lauterbach, S.; Hofmann, J.P.; Einert, M.: Fabrication of nanocrystalline high-entropy oxide CoNiFeCrMnOx thin film electrodes by dip-coating for oxygen evolution electrocatalysis. , Energy Advances 3 (2024), p. 765-773
doi: 10.1039/D4YA00026A


Muñoz, A.G.; Meyer, T.; Schild, D.; Calvet, W.: Early stages of corrosion of stainless steel 309 S in geological brines studied by sychrotron radiation photoelectron spectroscopy. , Corrosion Science 212 (2023), p. 110934/1-13
doi: 10.1016/j.corsci.2022.110934


Abrenica, G.; Lebedev, M.; Fingerle, M.; Arnauts, S.; Calvet, W.; Mayer, T.; de Gendt, S.; van Dorp, D.: A synchrotron radiation photoelectron spectroscopy study on atomicscale wet etching of InAs (111)-A and (111)-B in acidic peroxide solutions: surface chemistry versus kinetics. , Materials Today Chemistry 23 (2022), p. 100728/1-7
doi: 10.1016/j.mtchem.2021.100728


Abrenica, G.H.A.; Lebedev, M.V.; Fingerle, M.; Arnauts, S.; Bazzazian, N.; Calvet, W.; Porret, C.; Bender, H.; Mayer, T.; de Gend, S.; van Dorp, D.H.: Atomic-scale investigations on the wet etching kinetics of Ge versus SiGe in acidic H2O2 solutions: a post operando synchrotron XPS analysis. , Journal of Materials Chemistry C 8 (2020), p. 10060-10070
doi: 10.1039/d0tc02763d

Cherkashinin, G.; Schuch, J.; Kaiser, B.; Alff, L.; Jaegermann, W.: High Voltage Electrodes for Li-Ion Batteries and Efficient Water Electrolysis: An Oxymoron. , The Journal of Physical Chemistry Letters 11 (2020), p. 3754-3760
doi: 10.1021/acs.jpclett.0c00778


Lebedev, M.V.; Dementev, P.A.; Lvova, T.V.; Berkovits, V.L.: Modification of the p-GaP(001) work function by surface dipole bonds formed in sulfide solution. , Journal of Materials Chemistry C 7 (2019), p. 7327-7335
doi: 10.1039/c9tc00210c

Cherkashinin, G.; Hausbrand, R.; Jaegermann, W.: Performance of Li-Ion Batteries: Contribution of Electronic Factors to the Battery Voltage. , Journal of The Electrochemical Society 166 (2019), p. A5308-A5312
doi: 10.1149/2.0441903jes


Hajduk, A.; Lebedev, M.V.; Kaiser, B.; Jaegermann, W.: Interaction of liquid water with the p-GaInP2(100) surface covered with submonolayer oxide. , Physical Chemistry Chemical Physics 20 (2018), p. 21144-21150
doi: 10.1039/c8cp03337d

Cherkashinin, G.; Eilhardt, R.; Lebedev, M.; Nappini, S.; Magnano, E.; Jaegermann, W.: Olivine-LiNiPO4 Thin Films: Chemical Compatibility with Liquid Electrolyte and Interface Stability at High Potential. , Journal of The Electrochemical Society 165 (2018), p. H3143-H3147
doi: 10.1149/2.0211804jes

Guhl, Conrad Rudolf: Photoelektronenspektroskopische Untersuchung von Natriumkobaltoxidkathoden : Messungen an Feststoffbatterien unter operando Bedingungen im Ultrahochvakuum. , Darmstadt, Technische Universität Darmstadt, Diss., 2018

Muñoz, A.G.; Heine, Ch.; Hannappel, Th.; Lewerenz, H.-J.: Solar Tandem water Splitting from efficient III-V photovoltaics: implications of electrochemical surface activation. , Electrochimica Acta 260 (2018), p. 861-871
doi: 10.1016/j.electacta.2017.12.057


Fingerle, M.; Spaeth, T.; Schulz, N.; Hausbrand, R.: Adsorption of ethylene carbonate on lithium cobalt oxide thin films: A synchrotron-based spectroscopic study of the surface chemistry. , Chemical Physics 498-499 (2017), p. 19-24
doi: 10.1016/j.chemphys.2017.09.004

Lebedev, M.V.; Lvova, T.V.; Pavlov, S.I.; Sedova, I.V.: Effect of ammonium-sulfide solvent on the surface passivation of GaSb (100). , Semiconductors = Физика и техника полупроводников 51 (2017), p. 1093-1100
doi: 10.1134/S106378261708019X

Komissarova, T.A.; Lebedev, M.V.; Sorokin, S.V.; Klimko, G.V.; Sedova, I.V.; Gronin, S.V.; Komissarov, K.A.; Calvet, W.; Drozdov, M.N.; Ivanov, S.V.: Electronic, structural and chemical properties of GaAs/ZnSe heterovalent interfaces as dependent on MBE growth conditions and ex situ annealing. , Semiconductor Science and Technology 32 (2017), p. 045012/1-9
doi: 10.1088/1361-6641/aa5fd1

Fingerle, M.; Buchheit, R.; Sicolo, S.; Albe, K.; Hausbrand, R.: Reaction and Space Charge Layer Formation at the LiCoO2-LiPON Interface: Insights on Defect Formation and Ion Energy Level Alignment by a Combined Surface Science Simulation Approach. , Chemistry of Materials 29 (2017), p. 7675-7685
doi: 10.1021/acs.chemmater.7b00890

Mayer, T.; Schwanitz, K.; Kaiser, B.; Hajduk, A.; Lebedev, M.V.; Jaegermann, W.: Semiconductor/electrolyte interfaces for solar energy conversion: Interface studies by synchrotron induced photoelectron spectroscopy. , Journal of Electron Spectroscopy and Related Phenomena 221 (2017), p. 116-133
doi: 10.1016/j.elspec.2017.04.004

Hausbrand, R.; Cherkashinin, G.; Fingerle, M.; Jaegermann, W.: Surface and Bulk Properties of Li-ion Electrodes – a Surface Science Approach. , Journal of Electron Spectroscopy and Related Phenomena 221 (2017), p. 65-78
doi: 10.1016/j.elspec.2017.04.001

Lebedev, M.; Calvet, W.; Kaiser, B.; Jägermann, W.: Synchrotron Photoemission Spectroscopy Study of p-GaInP2(100) Electrodes Emersed from Aqueous HCl Solution under Cathodic Conditions. , The Journal of Physical Chemistry C 121 (2017), p. 8889-8901
doi: 10.1021/acs.jpcc.7b01343

Späth, T.; Becker, D.; Schulz, N.; Hausbrand, R.; Jaegermann, W.: Understanding the SEI Formation at Pristine Li-Ion Cathodes: Chemisorption and Reaction of DEC on LiCoO2 Surfaces Studied by a Combined SXPS/HREELS Approach. , Advanced Materials Interfaces 4 (2017), p. 1700567/1-9
doi: 10.1002/admi.201700567


Spaeth, T.; Fingerle, M.; Schulz, N.; Jaegermann, W.; Hausbrand, R.: Adsorption of Dimethyl Sulfoxide on LiCoO2 Thin Films: Interface Formation Studied by Photoemission Spectroscopy. , The Journal of Physical Chemistry C 120 (2016), p. 20142-20148
doi: 10.1021/acs.jpcc.6b05881

Lebedev, M.V; Kalyuzhnyy, N.A.; Mintairov, S.A.; Calvet, W.; Kaiser, B.; Jaegermann, W.: Comparison of wet chemical treatment and Ar-ion sputtering for GaInP2(100) surface preparation. , Materials Science in Semiconductor Processing 51 (2016), p. 81-88
doi: 10.1016/j.mssp.2016.05.005

Cherkashinin, G.; Jaegermann, W.: Dissociative adsorption of H2O on LiCoO2 (00l) surfaces: Co reduction induced by electron transfer from intrinsic defects. , The Journal of Chemical Physics 144 (2016), p. 184706/1-7
doi: 10.1063/1.4948610

Klett, Joachim: Interface and catalyst investigation for solar water splitting. , Darmstadt, Technische Universität Darmstadt, Diss., 2016

Schwöbel, A.; Jaegermann, W.; Hausbrand, R.: Interfacial energy level alignment and energy level diagrams for all-solid Li-ion cells: Impact of Li-ion transfer and double layer formation. , Solid State Ionics 288 (2016), p. 224-228
doi: 10.1016/j.ssi.2015.12.029

Hu, Y.; Boudoire, F.; Herrmann-Geppert, I.; Bogdanoff, P.; Tsekouras, G.; Mun, B.S.; Fortunato, G.; Graetzel, M.; Braun, A.: Molecular Origin and Electrochemical Influence of Capacitive Surface States on Iron Oxide Photoanodes. , The Journal of Physical Chemistry C 120 (2016), p. 3250-3258
doi: 10.1021/acs.jpcc.5b08013

Klett, J.; Elger, B.; Krähling, S.; Kaiser, B.; Jaegermann, W.; Schäfer, R.: Water dissociation on silica in the presence of atomic platinum. , Applied Surface Science 375 (2016), p. 85-89
doi: 10.1016/j.apsusc.2016.03.041


Reckers, P.; Dimamay, M.; Klett, J.; Trost, S.; Zilberberg, K.; Riedl, T.; Parkinson, B.A.; Broetz, J.; Jaegermann, W.; Mayer, T.: Deep and Shallow TiO2 Gap States on Cleaved Anatase Single Crystal (101) Surfaces, Nanocrystalline Anatase Films, and ALD Titania Ante and Post Annealing. , The Journal of Physical Chemistry C 119 (2015), p. 9890-9898
doi: 10.1021/acs.jpcc.5b01264

Cherkashinin, G.; Motzko, M.; Schulz, N.; Späth, T.; Jaegermann, W.: Electron Spectroscopy Study of Li[Ni,Co,Mn]O2/Electrolyte Interface: Electronic Structure, Interface Composition, and Device Implications. , Chemistry of Materials 27 (2015), p. 2875-2887
doi: 10.1021/cm5047534

Hausbrand, R.; Cherkashinin, G.; Ehrenberg, H.; Gröting, M.; Albe, K.; Hess, C.; Jaegermann, W.: Fundamental degradation mechanisms of layered oxide Li-ion battery cathode materials: Methodology, insights and novel approaches. , Materials Science and Engineering B 192 (2015), p. 3-25
doi: 10.1016/j.mseb.2014.11.014

Fertig, D.: Optimierung von p-GaP-Halbleitermaterialien zur photoelektrochemischen Wasserspaltung = Optimization of p-GaP semiconductor materials for photoelectrochemical water splitting. , Technische Universität Darmstadt, 2015

Motzko, M.; Solano, M.A.C.; Jaegermann, W.; Hausbrand, R.: Photoemission Study on the Interaction Between LiCoO2 Thin Films and Adsorbed Water. , The Journal of Physical Chemistry C 119 (2015), p. 23407-23412
doi: 10.1021/acs.jpcc.5b05793

Hillebrand, Philipp: Structure function relationships of cobalt and manganese oxides as catalysts for (photo) electrochemical water splitting. , Berlin, Technische Universität, Diss., 2015

Hillebrand, Philipp: Structure-function relationships of cobalt and manganese oxides as catalysts for (photo-) electrochemical water splitting = Struktur-Funktions-Beziehungen von Kobalt- und Manganoxid als Katalysatoren für die (photo-) elektrochemische Wasserspaltung. , Technische Universität Berlin, 2015

Hausbrand, R.; Schwöbel, A.; Jaegermann, W.; Motzko, M.; Ensling, D.: Surface and Interface Analysis of LiCoO2 and LiPON Thin Films by Photoemission: Implications for Li-Ion Batteries. , Zeitschrift für Physikalische Chemie 229 (2015), p. 1387-1414
doi: 10.1515/zpch-2014-0664


Hausbrand, R.; Becker, D.; Jaegermann, W.: A surface science approach to cathode/electrolyte interfaces in Li-ion batteries: Contact properties, charge transfer and reactions. , Progress in Solid State Chemistry 42 (2014), p. 175–183
doi: 10.1016/j.progsolidstchem.2014.04.010

Becker, D.; Cherkashinin, G.; Hausbrand, R.; Jaegermann, W.: Adsorption of Diethyl Carbonate on LiCoO2 Thin Films: Formation of the Electrochemical Interface. , The Journal of Physical Chemistry C 118 (2014), p. 962-967
doi: 10.1021/jp405714x

Schwöbel, A.; Precht, R.; Motzko, M.; Solano, M.A.C.; Calvet, W.; Hausbrand, R.; Jaegermann, W.: Determination of the valence band structure of an alkali phosphorus oxynitride glass: A synchrotron XPS study on LiPON. , Applied Surface Science 321 (2014), p. 55-60
doi: 10.1016/j.apsusc.2014.09.174

Östman, E.; Arnalds, U.B.; Melander, E.; Kapaklis, V.; Palsson, G.K.; Saw, A.Y.; Verschuuren, M.A.; Kronast, F.; Papaioannou, E.Th.; Fadley, C.S.; Hjorvarsson, B.: Hysteresis-free switching between vortex and collinear magnetic states. , New Journal of Physics 16 (2014), p. 053002/1-9
doi: 10.1088/1367-2630/16/5/053002

Ensling, D.; Cherkashinin, G.; Schmid, S.; Bhuvaneswari, S.; Thissen, A.; Jaegermann, W.: Nonrigid Band Behavior of the Electronic Structure of LiCoO2 Thin Film during Electrochemical Li Deintercalation. , Chemistry of Materials 26 (2014), p. 3948-3956
doi: 10.1021/cm501480b

Hillebrand, P.; Ramírez-Caro, A.; Calvet, W.; Bogdanoff, P.; Fiechter, S.: On the Structure-Function Relationship of Cobalt and Manganese Oxides as Oxygen Evolving Catalysts for Light-Driven Water Electrolysis: An In-Line Synchrotron Radiation Photoelectron Spectroscopy Study. , ECS Transactions 61 (2014), p. 9-20
doi: 10.1149/06114.0009ecst

Lebedev, M.V.; Calvet, W.; Mayer, T.; Jaegermann, W.: Photoelectrochemical Processes at n-GaAs(100)/Aqueous HCl Electrolyte Interface: A Synchrotron Photoemission Spectroscopy Study of Emersed Electrodes. , The Journal of Physical Chemistry C 118 (2014), p. 12774-12781
doi: 10.1021/jp500564c

Lebedev, M.V.; Mayer, T.: Superior electronic passivation of n-GaP(100) surface using alcoholic as compared to aqueous ammonium sulfide solution: Wet processing studied with synchrotron photoelectron spectroscopy. , Physica Status Solidi A 211 (2014), p. 2005-2012
doi: 10.1002/pssa.201330402

Klett, J.; Krähling, S.; Elger, B.; Schäfer, R.; Kaiser, B.; Jaegermann, W.: The Electronic Interaction of Pt-Clusters with ITO and HOPG Surfaces upon Water Adsorption. , Zeitschrift für Physikalische Chemie 228 (2014), p. 503-520
doi: 10.1515/zpch-2013-0499


Bora, D.K.; Hu, Y.; Thiess, S.; Erat, S.; Feng, X.; Mukherjee, S.; Fortunato, G.; Gaillard, N.; Toth, R.; Gajda-Schrantz, K.; Drube, W.; Graetzel, M.; Guo, J.; Zhu, J.; Constable, E.C.; Sarma, D.D.; Wang, H.; Braun, A.: Between photocatalysis and photosynthesis: Synchrotron spectroscopy methods on molecules and materials for solar hydrogen generation. , Journal of Electron Spectroscopy and Related Phenomena 190 (2013), p. 93-105
doi: 10.1016/j.elspec.2012.11.009

Hannappel, Th.; May, M.M.; Lewerenz, H.-J.: Epitaxial III-V Thin Film Absorbers: Preparation, Efficient InP Photocathodes and Routes to High Efficiency Tandem Structures. , In: Lewerenz, H.-J.; Laurence, P. [Eds.] : Photoelectrochemical Water Splitting : Materials, Processes and ArchitecturesLondon: RSC Publ., 2013. - ISBN 978-1-84973-647-3, p. 223-265
doi: 10.1039/9781849737739-00223

Gajda-Schrantz, K.; Tymen, S.; Boudoire, F.; Toth, R.; Bora, D.K.; Calvet, W.; Gratzel, M.; Constable, E.C.; Braun, A.: Formation of an electron hole doped film in the α-Fe2O3 photoanode upon electrochemical oxidation. , Physical Chemistry Chemical Physics 15 (2013), p. 1443-1451
doi: 10.1039/c2cp42597a

Trost, S.; Zilberberg, K.; Behrendt, A.; Polywka, A.; Görrn, P.; Reckers, P.; Maibach, J.; Mayer, T.; Riedl, T.: Overcoming the “Light-Soaking” Issue in Inverted Organic Solar Cells by the Use of Al:ZnO Electron Extraction Layers. , Advanced Energy Materials 3 (2013), p. 1437-1444
doi: 10.1002/aenm.201300402

G., A.; Heine, C.; Lublow, M.; W., H.; Szabo, N.; Hannappel, T.: Photoelectrochemical Conditioning of MOVPE p-InP Films for Light-Induced Hydrogen Evolution: Chemical, Electronic and Optical Properties. , ECS Journal of Solid State Science and Technology 2 (2013), p. Q51-Q58
doi: 10.1149/2.016304jss

Lebedev, M.V.; Kunitsyna, E.V.; Calvet, W.; Mayer, T.; Jaegermann, W.: Sulfur Passivation of GaSb(100) Surfaces: Comparison of Aqueous and Alcoholic Sulfide Solutions Using Synchrotron Radiation Photoemission Spectroscopy. , The Journal of Physical Chemistry C 117 (2013), p. 15996-16004
doi: 10.1021/jp401942p

Maibach, J.; Mankel, E.; Mayer, T.; Jaegermann, W.: Synchrotron induced photoelectron spectroscopy on drop casted donor/acceptor bulk heterojunction: Orbital energy line up in DH6T/PCBM blends. , Surface Science 612 (2013), p. L9-L11
doi: 10.1016/j.susc.2013.02.003

Maibach, J.; Mankel, E.; Mayer, T.; Jaegermann, W.: The band energy diagram of PCBM-DH6T bulk heterojunction solar cells: synchrotron-induced photoelectron spectroscopy on solution processed DH6T:PCBM blends and in situ prepared PCBM/DH6T interfaces. , Journal of Materials Chemistry C 1 (2013), p. 7635-7642
doi: 10.1039/c3tc31745e

Becker, D.; Cherkashinin, G.; Hausbrand, R.; Jaegermann, W.: XPS study of diethyl carbonate adsorption on LiCoO2 thin films. , Solid State Ionics 230 (2013), p. 83-85
doi: 10.1016/j.ssi.2012.08.004


Yang, F.; Roodenko, K.; Hunger, R.; Hinrichs, K.; Rademann, K.; Rappich, J.: Near-Ideal Complete Coverage of CD3 onto Si(111) Surfaces Using One-Step Electrochemical Grafting: An IR Ellipsometry, Synchrotron XPS, and Photoluminescence Study. , The Journal of Physical Chemistry C 116 (2012), p. 18684-18690
doi: 10.1021/jp301013t

Ziegler, J.; Fertig, D.; Kaiser, B.; Jaegermann, W.; Blug, M.; Hoch, S.; Busse, J.: Preparation and characterization of GaP semiconductor electrodes for photoelectrochemical water splitting. , Energy Procedia 22 (2012), p. 108-113
doi: 10.1016/j.egypro.2012.05.220

Kaiser, B.; Fertig, D.; Ziegler, J.; Klett, J.; Hoch, S.; Jaegermann, W.: Solar Hydrogen Generation with Wide-Band-Gap Semiconductors: GaP(100) Photoelectrodes and Surface Modification. , ChemPhysChem 13 (2012), p. 3053-3060
doi: 10.1002/cphc.201200432


Skorupska, K.; Pettenkofer, Ch.; Sadewasser, S.; Streicher, F.; Haiss, W.; Lewerenz, H.-J.: Electronic and morphological properties of the electrochemically prepared step bunched silicon (111) surface. , Physica Status Solidi B 248 (2011), p. 361 - 369
doi: 10.1002/pssb.201046454

Ziegler, Jürgen: Präparation und Charakterisierung von GaP-Halbleiterelektroden für die photoelektrochemische Wasserspaltung. , Technische Universität Darmstadt, 2011

Decker, A.; Suraru, S.L.; Rubio-Pons, O.; Mankel, E.; Bockstedte, M..; Thoss, M; Würthner, F.; Mayer, T.; Jaegermann, W.: Toward Functional Inorganic/Organic Hybrids: Phenoxy-allyl-PTCDI Synthesis, Experimentally and Theoretically Determined Properties of the Isolated Molecule, Layer Characteristics, and the Interface Formation of Phenoxy-allyl-PTCDI on Si(111):H Determined by SXPS and DFT. , The Journal of Physical Chemistry C 115 (2011), p. 21139-21150
doi: 10.1021/jp205294h


Hein, C.; Mankel, E.; Mayer, T.; Jaegermann, W.: Engineering the electronic structure of the ZnPc/C60 heterojunction by temperature treatment. , Solar Energy Materials and Solar Cells 94 (2010), p. 662-667
doi: 10.1016/j.solmat.2009.10.022

Lebedev, M.V.; Mankel, E.; Mayer, T.; Jaegermann, W.: Etching of GaAs(100) with Aqueous Ammonia Solution: A Synchrotron-Photoemission Spectroscopy Study. , The Journal of Physical Chemistry C 114 (2010), p. 21385-21389
doi: 10.1021/jp104321e

Roodenko, K.; Yang, F.; Hunger, R.; Esser, N.; Hinrichs, K.; Rappich, J.: Passivation of Si(111) surfaces with electrochemically grafted thin organic films. , Surface Science 604 (2010), p. 1623-1627
doi: 10.1016/j.susc.2010.06.005

Feng, X.J.; Hock, R.; Mankel, E.; Lingenfelser, D.; Völker, B.; Mayer, T.; Jaegermann, W.: Processing Temperature and Surface Na Content of TiO2 Nanocrystallites in Films for Solid-State Dye-Sensitized Solar Cells. , The Journal of Physical Chemistry C 114 (2010), p. 20049 - 20054
doi: 10.1021/jp1063676

Lebedev, M.V.; Mankel, E.; Mayer, T.; Jaegermann, W.: SXPS study of model GaAs(100)/electrolyte interface. , Physica Status Solidi C 7 (2010), p. 193-196
doi: 10.1002/pssc.200982439


Lebedev, M.V.; Mankel, E.; Mayer, T.; Jägermann, W.: Interaction of 2-Propanol with the GaAs(100) Surface. , The Journal of Physical Chemistry C 113 (2009), p. 20421-20428
doi: 10.1021/jp907251w

Yang, F.; Hunger, R.; Roodenko, K.; Hinrichs, K.; Rademann, K.; Rappich, J.: Vibrational and Electronic Characterization of Ethynyl Derivatives Granted onto Hydrogenated Si(111) Surfaces. , Langmuir 25 (2009), p. 9313-9318
doi: 10.1021/la900871g