Titanium dioxide nanoreactor
The titanium dioxide nanoparticles crystallize in a polymer network at room temperature.
Tiny particles of titanium dioxide are found as key ingredients in wall paints, sunscreens, and toothpaste; they act as reflectors of light or as abrasives. However with decreasing particle size and a corresponding change in their surface-to-volume ratio, their properties change so that crystalline titanium dioxide nanoparticles acquire catalytic ability: Activated by the UV component in sunlight, they break down toxins or catalyze other relevant reactions.
Now, Dr. Katja Henzler and a team of chemists at the Helmholtz Centre Berlin have developed a synthesis to produce nanoparticles at room temperature in a polymer network. Their analysis, conducted at BESSY II, Berlin's synchrotron radiation source, has revealed the crystalline structure of the nanoparticles. This represents a major step forward in the usage of polymeric nanoreactors since, until recently, the nanoparticles had to be thoroughly heated to get them to crystallize. The last synthesis step can be spared due to the special environment inside the PNIPAM network.
The Henzler team's polymeric nanoreactors consist of a polystyrene core surrounded by a network of PNIPAM chains. A titanium compound was added to an ethanolic solution of the polymer colloids, which did trigger the formation of small titanium dioxide particles within the PNIPAM network. The BESSY II experiments showed that the chemists were able to control the speed of these processes while at the same time affecting the quality of the nanocrystals that had formed.
Using the novel combination of x-ray microscopy and spectroscopy (NEXAFS-TXM, U41-SGM) at BESSY II, Henzler and the microscopy team were able to show that the nanoparticles are homogeneously distributed over the polymeric nanoreactors. The researchers examined their samples in a cryogenic aqueous environment, which prevents artifact formation due to sample drying. Their analysis showed that the nanoparticles have a crystalline structure. "The nanocrystals have a tetragonal anatase structure and this crystalline structure is a key to their catalytic performance. Additionally, our new analytic method allows us to control the quality of the synthesized particles so that we can optimize them for relevant applications," says Katja Henzler.
Nano Letters, 2013, 13 (2), pp 824–828;
DOI: 10.1021/nl3046798
- Green hydrogen: MXenes shows talent as catalyst for oxygen evolutionThe MXene class of materials has many talents. An international team led by HZB chemist Michelle Browne has now demonstrated that MXenes, properly functionalised, are excellent catalysts for the oxygen evolution reaction in electrolytic water splitting. They are more stable and efficient than the best metal oxide catalysts currently available. The team is now extensively characterising these MXene catalysts for water splitting at the Berlin X-ray source BESSY II and Soleil Synchrotron in France.
- Review on ocular particle therapy (OPT) by international expertsA team of leading experts in medical physics, physics and radiotherapy, including HZB physicist Prof. Andrea Denker and Charité medical physicist Dr Jens Heufelder, has published a review article on ocular particle therapy. The article appeared in the Red Journal, one of the most prestigious journals in the field. It outlines the special features of this form of eye therapy, explains the state of the art and current research priorities, provides recommendations for the delivery of radiotherapy and gives an outlook on future developments.
- "BESSY is of immense importance for Berlin"At the end of August, the Senator for Research, Health, and Long-Term Care, Dr Ina Czyborra, together with the State Secretary for Science, Dr Henry Marx, ended her summer tour with a visit to HZB in Adlershof. She publicly declared her political support for the new construction of BESSY III.