Accelerator physics: alternative material investigated for superconducting radio-frequency cavity resonators
The photomontage shows a sample of solid, pure niobium before coating (left), and coated with a thin layer of Nb3Sn (right). © HZB
In modern synchrotron sources and free-electron lasers, superconducting radio-frequency cavity resonators are able to supply electron bunches with extremely high energy. These resonators are currently constructed of pure niobium. Now an international collaboration has investigated the potential advantages a niobium-tin coating might offer in comparison to pure niobium.
At present, niobium is the material of choice for constructing superconducting radio-frequency cavity resonators. These will be used in projects at the HZB such as bERLinPro and BESSY-VSR, but also for free-electron lasers such as the XFEL and LCLS-II. However, a coating of niobium-tin (Nb3Sn) could lead to considerable improvements.
Coatings may save money and energy
Superconducting radio-frequency cavity resonators made of niobium must be operated at 2 Kelvin (-271 degrees Celsius), which requires expensive and complicated cryogenic engineering. In contrast, a coating of Nb3Sn might make it possible to operate resonators at 4 Kelvin instead of 2 Kelvin and possibly withstand higher electromagnetic fields without the superconductivity collapsing. In the future, this could save millions of euros in construction and electricity costs for large accelerators, as the cost of cooling would be substantially lower.
Experiments in the USA, Canada, Switzerland and HZB
A team led by Prof. Jens Knobloch, who heads the SRF Institute at HZB, has now carried out tests of superconducting samples coated with Nb3Sn by Cornell University, USA, in collaboration with colleagues from the USA, Canada, and Switzerland. The experiments took place at the Paul Scherrer Institute, Switzerland, at TRIUMF, Canada, and the HZB.
“We measured the critical magnetic field strengths of superconducting Nb3Sn samples in both static and radio-frequency fields”, says Sebastian Keckert, first author of the study, who is doing his doctorate as part of the Knobloch team. By combining different measurement methods, they were able to confirm the theoretical prediction that the critical magnetic field of Nb3Sn in radio-frequency fields is higher than that for static magnetic fields. However, the coated material should display a very much higher critical magnetic field level in a radio-frequency field. Thus, the tests have also shown that the coating process used currently for the production of Nb3Sn might be improved upon in order to more closely approach the theoretical values.
The publication has been mentioned on the Cover of „Superconductor Science and Technology“ , (2019): Critical fields of Nb3Sn prepared for superconducting cavities; S. Keckert, T. Junginger, T. Buck, D. Hall, P. Kolb, O. Kugeler, R. Laxdal, M. Liepe, S. Posen , T. Prokscha, Z. Salman, A. Suter and J. Knobloch.
doi:10.1088/1361-6668/ab119e
- Battery research: visualisation of aging processes operandoLithium button cells with electrodes made of nickel-manganese-cobalt oxides (NMC) are very powerful. Unfortunately, their capacity decreases over time. Now, for the first time, a team has used a non-destructive method to observe how the elemental composition of the individual layers in a button cell changes during charging cycles. The study, now published in the journal Small, involved teams from the Physikalisch-Technische Bundesanstalt (PTB), the University of Münster, researchers from the SyncLab research group at HZB and the BLiX laboratory at the Technical University of Berlin. Measurements were carried out in the BLiX laboratory and at the BESSY II synchrotron radiation source.
- New instrument at BESSY II: The OÆSE endstation in EMILA new instrument is now available at BESSY II for investigating catalyst materials, battery electrodes and other energy devices under operating conditions: the Operando Absorption and Emission Spectroscopy on EMIL (OÆSE) endstation in the Energy Materials In-situ Laboratory Berlin (EMIL). A team led by Raul Garcia-Diez and Marcus Bär showcases the instrument’s capabilities via a proof-of-concept study on electrodeposited copper.
- Green hydrogen: A cage structured material transforms into a performant catalystClathrates are characterised by a complex cage structure that provides space for guest ions too. Now, for the first time, a team has investigated the suitability of clathrates as catalysts for electrolytic hydrogen production with impressive results: the clathrate sample was even more efficient and robust than currently used nickel-based catalysts. They also found a reason for this enhanced performance. Measurements at BESSY II showed that the clathrates undergo structural changes during the catalytic reaction: the three-dimensional cage structure decays into ultra-thin nanosheets that allow maximum contact with active catalytic centres. The study has been published in the journal ‘Angewandte Chemie’.