User research at BESSY II: Graphite electrodes for rechargeable batteries investigated
The tomogram during the charging process shows the spatially resolved changes in the graphite electrode thickness of a rechargeable aluminium ion battery in a discharged and charged state. © HZB
Rechargeable graphite dual ion batteries are inexpensive and powerful. A team of the Technical University of Berlin has investigated at the EDDI Beamline of BESSY II how the morphology of the graphite electrodes changes reversibly during cycling (operando). The 3D X-ray tomography images combined with simultaneous diffraction now allow a precise evaluation of the processes, especially of changes in the volume of the electrodes. This can help to further optimise graphite electrodes.
Published in Advanced Functional Materials (2020); Simultaneous X‐Ray Diffraction and Tomography Operando Investigation of Aluminum/Graphite Batteries; Giuseppe Antonio Elia, Giorgia Greco, Paul Hans Kamm, Francisco García‐Moreno, Simone Raoux, Robert Hahn
DOI: 10.1002/adfm.202003913
Abstract: Rechargeable graphite dual‐ion batteries are extremely appealing for grid‐level stationary storage of electricity, thanks to the low‐cost and high‐performance metrics, such as high‐power density, energy efficiency, long cycling life, and good energy density. An in‐depth understanding of the anion intercalation mechanism in graphite is fundamental for the design of highly efficient systems. In this work, a comparison is presented between pyrolytic (PG) and natural (NG) graphite as positive electrode materials in rechargeable aluminum batteries, employing an ionic liquid electrolyte. The two systems are characterized by operando synchrotron energy‐dispersive X‐ray diffraction and time‐resolved computed tomography simultaneously, establishing a powerful characterization methodology, which can also be applied more in general to carbon‐based energy‐related materials. A more in‐depth insight into the AlCl4−/graphite intercalation mechanism is obtained, evidencing a mixed‐staged region in the initial phase and a two‐staged region in the second phase. Moreover, strain analysis suggests a correlation between the irreversibility of the PG electrode and the increase of the inhomogenous strain. Finally, the imaging analysis reveals the influence of graphite morphology in the electrode volume expansion upon cycling.
- Sasol and HZB deepen collaboration with strategic focus on digitalisationSasol Research & Technology and Helmholtz Zentrum Berlin (HZB) are expanding their partnership into the realm of digitalisation, building on their joint efforts in the CARE-O-SENE project and an Industrial Fellowship launched earlier this year. This new initiative marks a significant step forward in leveraging digital technologies to accelerate catalyst innovation and deepen scientific collaboration.
- Technology Transfer Prize Ceremony 2025This year’s Technology Transfer Prize Ceremony will take place on October 13 at 2 pm in the Lecture Hall, BESSY II Building, Adlershof.
- Novel technique shines light on next-gen nanomaterials: how MXenes truly workResearchers have for the first time measured the true properties of individual MXene flakes — an exciting new nanomaterial with potential for better batteries, flexible electronics, and clean energy devices. By using a novel light-based technique called spectroscopic micro-ellipsometry, they discovered how MXenes behave at the single-flake level, revealing changes in conductivity and optical response that were previously hidden when studying only stacked layers. This breakthrough provides the fundamental knowledge and tools needed to design smarter, more efficient technologies powered by MXenes.