Perovskite Solar Cells: paving the way for rational ink design for industrial-scale manufacturing

Schematic illustration: the solvants (ink) are used to produce a thin film of polycrystalline perovskite. 

Schematic illustration: the solvants (ink) are used to produce a thin film of polycrystalline perovskite.  © HZB

For the production of high-quality metal-halide perovskite thin-films for large area photovoltaic modules often optimized inks are used which contain a mixture of solvents. An HZB team at BESSY II has now analysed the crystallisation processes within such mixtures. A model has also been developed to assess the kinetics of the crystallisation processes for different solvent mixtures. The results are of high importance for the further development of perovskite inks for industrial-scale deposition processes of these semiconductors.

Hybrid organic perovskite semiconductors are a class of materials for solar cells, which promise high efficiencies at low costs. They can be processed from precursor solutions that upon evaporation on a substrate form a polycrystalline thin film. Simple manufacturing processes, such as spin coating a precursor solution, often only lead to good results on a laboratory scale, i.e. for very small samples.

Printing large areas

For the production of larger area photovoltaic modules, the team of Dr. Eva Unger develops printing and coating processes in which the perovskite semiconductor is processed from inks containing the precursors dissolved in solvents.  The composition of the ink determines the material formation mechanism with the solvent affecting the process by its rheological properties, evaporation rate and participation in intermediate phases. "Our research question in this project was: How can we rationalize the difference in crystallization kinetics when using different solvents," explains Unger, who heads the Young Investigator Group Hybrid Materials Formation and Scaling.

Different evaporation rates

In solvents with only one component, the crystallization process is determined by the evaporation rate. "In mixtures of solvents, evaporation is dominated by the most volatile component that evaporates the fastest. This changes the ratio of solvents that are present upon crystallization", says Dr. Oleksandra Shargaieva, postdoc in Unger's team. 

Crystallization analyzed at BESSY II

At the KMC-2 beamline of BESSY II, she was able to analyse the formation of the perovskite semiconductor and crystalline intermediate phases incorporating solvent molecules during the evaporation of the solvents. “I found that the formation mechanism critically depends both on the solvents evaporation rate and binding strength to the lead-halide. “These insights will help to predict the kinetics of crystallization processes of the perovskite thin film for different solvent combinations based on the properties of the precursor solutions”, says Shargaieva.

"There is still a lack of systematic knowledge when scaling up from laboratory scale to industrial area sizes. With these results we pave the way for further ink design to enable industrial-scale manufacturing or perovskite thin films of high quality”, says Unger.

arö

  • Copy link

You might also be interested in

  • Sodium-ion batteries: New storage mechanism for cathode materials
    Science Highlight
    18.07.2025
    Sodium-ion batteries: New storage mechanism for cathode materials
    Li-ion and Na-ion batteries operate through a process called intercalation, where ions are stored and exchanged between two chemically different electrodes. In contrast, co-intercalation, a process in which both ions and solvent molecules are stored simultaneously, has traditionally been considered undesirable due to its tendency to cause rapid battery failure. Against this traditional view, an international research team led by Philipp Adelhelm has now demonstrated that co-intercalation can be a reversible and fast process for cathode materials in Na-ion batteries. The approach of jointly storing ions and solvents in cathode materials provides a new handle for the designing batteries with high efficiency and fast charging capabilities. The results are published in Nature Materials.
  • 10 million euros in funding for UNITE – Startup Factory Berlin-Brandenburg
    News
    16.07.2025
    10 million euros in funding for UNITE – Startup Factory Berlin-Brandenburg
    UNITE – Startup Factory Berlin-Brandenburg has been recognised by the Federal Ministry for Economic Affairs and Energy as one of ten nationwide flagship projects for science-based start-ups. UNITE is to be established as a central transfer platform for technology-driven spin-offs from science and industry in the capital region. The Helmholtz Centre Berlin will also benefit from this.

  • Helmholtz Doctoral Award for Hanna Trzesniowski
    News
    09.07.2025
    Helmholtz Doctoral Award for Hanna Trzesniowski
    During her doctoral studies at the Helmholtz Centre Berlin, Hanna Trzesniowski conducted research on nickel-based electrocatalysts for water splitting. Her work contributes to a deeper understanding of alkaline water electrolysis and paves the way for the development of more efficient and stable catalysts. On 8 July 2025, she received the Helmholtz Doctoral Prize, which honours the best and most original doctoral theses in the Helmholtz Association.