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  Wei, Y.; Ma, X.; Feng, Z.; Adroja, D.; Hillier, A.; Biswas, P.; Senyshyn, A.; Hoser, A.; Mei, J.W.; Meng, Z.Y.; Luo, H.; Shi, Y.; Li, S.: Magnetic Phase Diagram of Cu_4-xZn_x(OH)₆FBr Studied by Neutron-Diffraction and μsR Techniques. Chinese Physics Letters 37 (2020), p. 107503/1-5

10.1088/0256-307x/37/10/107503
Open Access Version (externer Anbieter)

Abstract:
We systematically investigate the magnetic properties of Cu4 – xZnx(OH)6FBr using the neutron diffraction and muon spin rotation and relaxation (μSR) techniques. Neutron-diffraction measurements suggest that the long-range magnetic order and the orthorhombic nuclear structure in the x = 0 sample can persist up to x = 0.23 and 0.43, respectively. The temperature dependence of the zero-field μSR spectra provides two characteristic temperatures, TA0 and Tλ, which are associated with the initial drop close to zero time and the long-time exponential decay of the muon relaxation, respectively. Comparison between TA0 and TM from previously reported magnetic-susceptibility measurements suggest that the former comes from the short-range interlayer-spin clusters that persist up to x = 0.82. On the other hand, the doping level where Tλ becomes zero is about 0.66, which is much higher than threshold of the long-range order, i.e., ∼0.4. Our results suggest that the change in the nuclear structure may alter the spin dynamics of the kagome layers and a gapped quantum-spin-liquid state may exist above x = 0.66 with the perfect kagome planes.