Dittrich, T.: Transient surface photovoltage spectroscopy of diamond. AIP Advances 12 (2022), p. 065206/1-6
10.1063/5.0089398
Open Access Version
Abstract:
Contactless and highly sensitive probing of electronic transitions in diamond over a wide spectral range from near infrared to deep ultraviolet is still challenging. Surface photovoltage (SPV) signals depend on electronic transitions and transport phenomena leading to charge separation in space and allow for a contactless study of electronic transitions. Here, transient SPV spectroscopy in an arrangement with a charge amplifier and a laser tunable over a wide range was applied to study an undoped diamond single crystal between 0.8 and 5.9 eV at room temperature in ambient air. SPV transients were measured without and with weak visible bias light, which allowed for suppression of possible parasitic contributions in SPV signals not related to diamond and distinction of processes of charge separation that were independent of band bending. Transitions at 1.0 and 3.1 eV led to preferential separation of photogenerated holes toward the surface. In contrast, a transition at 1.8 eV caused preferential separation of photogenerated electrons toward the surface. Transitions near the indirect bandgap of diamond were observed at 5.27, 5.32, 5.48, and 5.53 eV and could be assigned to absorption assisted (i) by an indirect exciton and absorption of longitudinal optical and acoustic phonons, (ii) by absorption of transverse acoustic phonons, (iii) by emission of transverse acoustic phonons, and (iv) by emission of longitudinal optical and acoustic phonons, respectively. Charge separation under excitation at 5.27 eV was caused by directed charge transfer at/near the diamond surface after exciton diffusion followed by exciton dissociation.