Martini, A.; Timoshenko, J.; Grosse, P.; Rettenmaier, C.; Hursán, D.; Deplano, G.; Jeon, H. S.; Bergmann, A.; Roldan Cuenya, B.: Adsorbate Configurations in Ni Single-Atom Catalysts during CO2 Electrocatalytic Reduction Unveiled by Operando XAS, XES, and Machine Learning. Physical Review Letters 133 (2024), p. 228001/1-7
10.1103/PhysRevLett.133.228001
Open Access Version
Abstract:
Nickel and nitrogen co-doped carbon (Ni-N-C) catalysts are attracting attention due to their exceptionally high performance in the electrocatalytic reduction of CO2(CO2RR) to CO. However, the direct experimental insight into the working mechanism of these catalysts is missing, hindering our fundamental understanding and their further improvement. This work sheds light on the nature of adsorbates forming under CO2RR at singly dispersed Ni sites. In particular, operando high energy resolution fluorescence detected x-ray absorption near edge structure (HERFD-XANES) at the Ni 𝐾-edge together with valence-to-core x-ray emission spectroscopy (vtc-XES) and x-ray absorption (XAS) at the Ni 𝐿3-edge were employed to unveil the structure and electronic properties of the reaction intermediates. These techniques, coupled with unsupervised and supervised machine learning methodologies and density functional theory, enabled a comprehensive characterization of the local atomistic and electronic structure of the working Ni-N-C catalysts. Specifically, we were able to distinguish between the structural and electronic changes of the Ni sites associated with the CO2RR functionality from the effect of radiation-induced damage, providing direct insight into the bond formation between the Ni centers and CO2RR intermediates such as CO adsorbates.