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  Pirogov, A.N.; Bogdanov, S.G.; Rosenfeld, E.V.; Park, J.-G.; Choi, Y.N.; Lee, S.; Prokes, K.; Golosova, N.O.; Sashin, I.L.; Kudrevatykh, N.V.; Skryabin, Yu.N.; Vokhmyanin, A.P.: Effects of magnetic anisotropy and exchange in Tm₂Fe₁₇. Journal of Experimental and Theoretical Physics 115 (2012), p. 837-848

10.1134/S106377611210010X

Abstract:
Neutron diffraction experiments have been carried out to study the magnetocrystalline anisotropy of two (2b and 2d) Tm sublattices and four (4f, 6g, 12j, and 12k) Fe sublattices in ferrimagnetic compound Tm2Fe17 (space group P63/mmc). We have determined the temperature dependence of the magnitude and orientation of magnetization for each of the thulium and iron sublattices in the range (10–300) K. A spontaneous rotation (at about 90 K) of the Tm and Fe sublattice magnetizations from the caxis to the basal plane is accompanied by a drastic change in the magnetization magnitude, signifying a large magnetization anisotropy. Both Tm sublattices exhibit an easyaxis type of the magnetocrystalline anisotropy. The Fe sublattices manifest both the uniaxial and planar anisotropy types. The sublattice formed by Fe atoms at the 4f position reveals the largest planar anisotropy constant. The Fe atoms at the 12j position show a uniaxial anisotropy. We find that the inelastic neutron scattering spectra measured below and above the spinreorientation transition are remarkably different.