Batteries with silicon anodes: Neutron experiments show how formation of surface structures reduces amp-hour capacity

Neutrons (red arrows) detect the presence of Lithium ions which have migrated into the silicon anode.

Neutrons (red arrows) detect the presence of Lithium ions which have migrated into the silicon anode. © HZB

In theory, silicon anodes could store ten times more lithium ions than graphite anodes, which have been used in commercial lithium batteries for many years. However, the amp-hour capacity of silicon anodes so far has been declining sharply with each additional charge-discharge cycle. Now an HZB team at BER II of the HZB in Berlin and the Institut Laue-Langevin in Grenoble has utilised neutron experiments to establish what happens at the surface of the silicon anode during charging and what processes reduce this capacity.

”With the neutron experiments and other measurements, we were able to observe how an inhibition or “blocking” layer forms on the silicon surface during charging that hinders the penetration of lithium ions”, explains HZB physicist Dr. Sebastian Risse. This 30-60 nanometre layer consists of organic molecules from the electrolyte liquid and inorganic components. When charging, the layer partially dissolves again so that the lithium ions can penetrate the silicon anode. However, energy is needed to dissolve the layer, which is then no longer available for storing. The physicists used the same electrolyte fluid in the experiment that is used in commercial lithium batteries.

Several cycles observed

After preliminary investigations with HZB’s BER II neutron source, the experiments at the Institut Laue-Langevin (ILL) in Grenoble provided a precise insight into the processes. ”Cold neutrons at very high flux are available at the ILL reactor. We were able to use them to non-destructively observe the silicon anode during several charge cycles”, explains Risse. Using a measuring cell developed at the HZB, physicists were able to examine the silicon anodes with neutrons during the charge-discharge cycles (in operando) and also record a number of other measurement values such as electrical resistance using impedance spectroscopy.

Efficiencies of 94 %

As soon as this inhibition layer is dissolved, the efficiency of the charge-discharge cycles increases to 94 per cent (94 % of the stored charge can be delivered again). This value is higher than that of lead-acid batteries (90 %), but slightly lower than that of batteries employing more highly developed lithium-ion technology, which deliver up to 99.9 %.

Outlook: Preventing the blocking layer

”We now want to investigate whether it is possible to prevent the formation of this inhibition or “blocking” layer by applying a very thin protective layer of metal oxide so that the capacity of silicon anodes decreases less over the course of many charge-discharge cycles”, says Risse.

The study was published in „Energy Storage Materials“: "Surface structure inhibited lithiation of crystalline silicon probed with operando neutron reflectivity". Arne Ronneburg, Marcus Trapp, Robert Cubitt, Luca Silvi,  Sébastien Cap, Matthias  Ballauff, Sebastian Risse.

DOI: 10.1016/j.ensm.2018.11.032

arö


You might also be interested in

  • Fractons as information storage: Not yet quite tangible, but close
    Science Highlight
    26.05.2023
    Fractons as information storage: Not yet quite tangible, but close
    A new quasiparticle with interesting properties has appeared in solid-state physics - but so far only in the theoretical modelling of solids with certain magnetic properties. An international team from HZB and Freie Universität Berlin has now shown that, contrary to expectations, quantum fluctuations do not make the quasiparticle appear more clearly, but rather blur its signature.
  • Graphene on titanium carbide triggers a novel phase transition
    Science Highlight
    25.05.2023
    Graphene on titanium carbide triggers a novel phase transition
    Researchers have discovered a Lifshitz-transition in TiC, driven by a graphene overlayer, at the photon source BESSY II. Their study sheds light on the exciting potential of 2D materials such as graphene and the effects they can have on neighboring materials through proximity interactions.
  • Alexander von Humboldt Foundation Grant for Dr. Jie Wei
    News
    16.05.2023
    Alexander von Humboldt Foundation Grant for Dr. Jie Wei
    In April, Dr. Jie Wei started his research work in the Helmholtz Young Investigator Group Nanoscale Operando CO2 Photo-Electrocatalysis at Helmholtz-Zentrum Berlin (HZB) and Fritz Haber Institute (FHI) of the Max Planck Society. Wei received one of the highly competitive Humboldt postdoctoral research fellowships and will pursue his two-year project under the guidance of the academic hosts Dr. Christopher Kley and Prof. Dr. Beatriz Roldan Cuenya.