Review: X-ray scattering methods with synchrotron radiation
Resonant X-ray excitation (purple) core excites the oxygen atom within a H2O molecule. This causes ultrafast proton dynamics. The electronic ground state potential surface (bottom) and the bond dynamics is captured by distinct spectral features in resonant inelastic X-ray scattering (right).
© Martin Künsting /HZB
Synchrotron light sources provide brilliant light with a focus on the X-ray region and have enormously expanded the possibilities for characterising materials. In the Reviews of Modern Physics, an international team now gives an overview of elastic and inelastic X-ray scattering processes, explains the theoretical background and sheds light on what insights these methods provide in physics, chemistry as well as bio- and energy related themes.
"X-ray scattering can be used to investigate and resolve a wide variety of issues from the properties and excitations of fuctional solids, to homogeneous and heterogeneous chemical processes and reactions or even the proton pathway during the splitting of water," explains Prof. Dr. Alexander Föhlisch, who heads the Institute Methods and Instrumentation for Research with Synchrotron Radiation at HZB.
The article gives an overview of experimental and theoretical results in the field of resonant scattering of tunable soft and hard X-rays. The focus is on resonant inelastic X-ray scattering (RIXS) and resonant Auger scattering (RAS). In the review, the authors outline the most important achievements from the last two decades at Synchrotrons up to the latest advances in time-resolved studies with X-ray free-electron lasers.
- Green hydrogen: A cage structured material transforms into a performant catalystClathrates are characterised by a complex cage structure that provides space for guest ions too. Now, for the first time, a team has investigated the suitability of clathrates as catalysts for electrolytic hydrogen production with impressive results: the clathrate sample was even more efficient and robust than currently used nickel-based catalysts. They also found a reason for this enhanced performance. Measurements at BESSY II showed that the clathrates undergo structural changes during the catalytic reaction: the three-dimensional cage structure decays into ultra-thin nanosheets that allow maximum contact with active catalytic centres. The study has been published in the journal ‘Angewandte Chemie’.
- An elegant method for the detection of single spins using photovoltageDiamonds with certain optically active defects can be used as highly sensitive sensors or qubits for quantum computers, where the quantum information is stored in the electron spin state of these colour centres. However, the spin states have to be read out optically, which is often experimentally complex. Now, a team at HZB has developed an elegant method using a photo voltage to detect the individual and local spin states of these defects. This could lead to a much more compact design of quantum sensors.
- Solar cells on moon glass for a future base on the moonFuture settlements on the moon will need energy, which could be supplied by photovoltaics. However, launching material into space is expensive – transporting one kilogram to the moon costs one million euros. But there are also resources on the moon that can be used. A research team led by Dr. Felix Lang of the University of Potsdam and Dr. Stefan Linke of the Technical University of Berlin have now produced the required glass from ‘moon dust’ (regolith) and coated it with perovskite. This could save up to 99 percent of the weight needed to produce PV modules on the moon. The team tested the radiation tolerance of the solar cells at the proton accelerator of the HZB.