Innovative catalysts: An expert review

With the help of innovative elctrocatalytic materials, water can be split up into oxygen and hydrogen. Hydrogen is a fuel storing chemical energy as long as needed.

With the help of innovative elctrocatalytic materials, water can be split up into oxygen and hydrogen. Hydrogen is a fuel storing chemical energy as long as needed. © Dr. Ziliang Chen

Highly efficient (electro-)catalysts are essential for the production of green hydrogen, the chemical industry, fertiliser production and other sectors of the economy. In addition to transition metals, a variety of other metallic or non-metallic elements have now moved into the focus of research. In a review article, experts from CatLab and Technische Universität Berlin present an overview on current knowledge and a perspective on future research questions.

Green hydrogen is an important component in a climate-neutral energy system. It is produced by electrolytically splitting water with wind or solar power and stores this energy in chemical form. But currently, the production of green hydrogen is not yet economical or efficient enough. The key to solving this problem is through the development of innovative electrocatalysts, which should not only work with high efficiencies but should also be available and inexpensive.

In addition to transition metals, which are already well studied for their catalytic properties, a wider choice of elements has now moved into the focus such as alkali metals, alkaline earth metals, rare earth metals, lean metals and metalloids. Some of these when combined with transition metal electrocatalysts can significantly improve performance and contribute to the development of next-generation high-performance electrocatalysts.

However, many of the processes that take place during electrocatalysis -when oxygen or hydrogen is formed - are still not understood in detail. In a review article, an international team of experts guides us through this exciting research field and draws a perspective, sketching the next steps catalyst research could take. “This contribution summarises the current state of knowledge on such unconventional s-, p-, and f-block metal-based materials and makes it comprehensible to a wider community of scientists”, Dr. Prashanth W. Menezes points out and adds: "Further, the essential role of such metals during water splitting electrocatalysis is described in great depth, as well as the modification strategy that should be considered when one wants to utilize them to mediate non-noble-based electrocatalysts. We hope to significantly accelerate research and development of novel, innovative catalyst materials with this review article."

Note: Dr. Prashanth W. Menezes is Head of Materials Chemistry for Thin-Film Catalysis Group in the CatLab-Project at HZB and Head of Inorganic Materials Group at TU Berlin.

His twitterhandle is @EnergycatLab

 

CatLab: Together with the Fritz Haber Institute of the Max Planck Society, HZB is setting up the Catalysis Laboratory CatLab, which is intended to accelerate research into innovative catalysts.  CatLab is supported by the German Federal Ministry of Education and Research.

 

arö

  • Copy link

You might also be interested in

  • Green hydrogen: MXenes shows talent as catalyst for oxygen evolution
    Science Highlight
    09.09.2024
    Green hydrogen: MXenes shows talent as catalyst for oxygen evolution
    The MXene class of materials has many talents. An international team led by HZB chemist Michelle Browne has now demonstrated that MXenes, properly functionalised, are excellent catalysts for the oxygen evolution reaction in electrolytic water splitting. They are more stable and efficient than the best metal oxide catalysts currently available. The team is now extensively characterising these MXene catalysts for water splitting at the Berlin X-ray source BESSY II and Soleil Synchrotron in France.
  • SpinMagIC: 'EPR on a chip' ensures quality of olive oil and beer
    News
    04.09.2024
    SpinMagIC: 'EPR on a chip' ensures quality of olive oil and beer
    The first sign of spoilage in many food products is the formation of free radicals, which reduces the shelf-life and the overall quality of the food. Until now, the detection of these molecules has been very costly for the food companies. Researchers at HZB and the University of Stuttgart have developed a portable, small and inexpensive 'EPR on a chip' sensor that can detect free radicals even at very low concentrations. They are now working to set up a spin-off company, supported by the EXIST research transfer programme of the German Federal Ministry of Economics and Climate Protection. The EPRoC sensor will initially be used in the production of olive oil and beer to ensure the quality of these products.
  • Review on ocular particle therapy (OPT) by international experts
    Science Highlight
    03.09.2024
    Review on ocular particle therapy (OPT) by international experts
    A team of leading experts in medical physics, physics and radiotherapy, including HZB physicist Prof. Andrea Denker and Charité medical physicist Dr Jens Heufelder, has published a review article on ocular particle therapy. The article appeared in the Red Journal, one of the most prestigious journals in the field. It outlines the special features of this form of eye therapy, explains the state of the art and current research priorities, provides recommendations for the delivery of radiotherapy and gives an outlook on future developments.