Predicting solar cell performance from terahertz and microwave spectroscopy

In the femtosecond laser laboratory of Dr. Dennis Friedrich at HZB, the transport properties of semiconductors can be determined using terahertz or microwave spectroscopy. For this purpose, a laser light pulse first excites the charge carriers in the material, which are then irradiated with electromagnetic waves (either THz or Microwave) and absorb some of them.

In the femtosecond laser laboratory of Dr. Dennis Friedrich at HZB, the transport properties of semiconductors can be determined using terahertz or microwave spectroscopy. For this purpose, a laser light pulse first excites the charge carriers in the material, which are then irradiated with electromagnetic waves (either THz or Microwave) and absorb some of them. © HZB

Many semiconducting materials are possible candidates for solar cells. In recent years, perovskite semiconductors in particular have attracted attention, as they are both inexpensive and easy to process and enable high efficiencies. Now a study with 15 participating research institutions shows how terahertz (TRTS) and microwave spectroscopy (TRMC) can be used to reliably determine the mobility and lifetime of the charge carriers in new semiconducting materials. Using these measurement data it is possible to predict the potential efficiency of the solar cell in advance and to classify the losses in the finished cell.  

The most important properties of a semiconductor to be used as a solar cell include the mobility and lifetime of electrons and "holes". Both quantities can be measured without contacts with spectroscopic methods using terahertz or microwave radiation. However, measurement data found in literature often differ by orders of magnitude. This has made it difficult to use them for reliable assessments of  material quality.

Reference samples measured

"We wanted to get to the bottom of these differences, and contacted experts from a total of 15 international laboratories to analyse typical sources of error and problems with the measurements," says Dr. Hannes Hempel from the HZB team led by Dr. Thomas Unold. The HZB physicists sent reference samples produced by the team of Dr. Martin Stolterfoht at University Potsdam to each laboratory with the perovskite semiconductor compound (Cs,FA,MA)Pb(I,Br)3) optimised for stability.

Better data for better prediction

One result of the joint work is the significantly more precise determination of the transport properties with terahertz or microwave spectroscopy. "We could identify some neuralgic points that have to be considered before the actual measurements takes place, which allows us to arrive at significantly better agreement of the results," Hempel emphasises.  

Another result of the study: With reliable measurement data and a more advanced analysis, the characteristics of the solar cell can also be calculated more precisely. "We believe that this analysis is of great interest for photovoltaic research, because it predicts the maximum possible efficiency of the material in a solar cell and reveals the influence of various loss mechanisms, such as transport barriers," says Unold. This applies not only to the material class of perovskite semiconductors, but also to other new semiconducting materials, which can thus be tested more quickly for their potential suitability.

arö

You might also be interested in

  • HZB researcher Olga Kasian honored as young scientist
    News
    24.06.2022
    HZB researcher Olga Kasian honored as young scientist
    The Werner-von-Siemens-Ring Foundation has accepted Prof. Dr. Olga Kasian into its network in recognition of her outstanding scientific achievements. Olga Kasian heads a junior research group on electrocatalysis at HZB and is a professor at the University of Erlangen-Nürnberg (FAU). The foundation has been honoring young researchers in the technical and natural sciences since 1977 and offers them unique opportunities for interdisciplinary networking.

  • Deputy Prime Minister of Singapore visits HZB
    News
    21.06.2022
    Deputy Prime Minister of Singapore visits HZB
    On Friday, 17 June, a delegation from Singapore visited HZB. Heng Swee Keat, Deputy Prime Minister of Singapore, was accompanied by the Ambassador to Singapore in Berlin, Laurence Bay, as well as representatives from research and industry.
  • Calculating the "fingerprints" of molecules with artificial intelligence
    Science Highlight
    13.06.2022
    Calculating the "fingerprints" of molecules with artificial intelligence
    With conventional methods, it is extremely time-consuming to calculate the spectral fingerprint of larger molecules. But this is a prerequisite for correctly interpreting experimentally obtained data. Now, a team at HZB has achieved very good results in significantly less time using self-learning graphical neural networks.