HZB Newsroom

As part of the CatLab project, HZB has acquired a unique facility for measuring the catalytic performance of thin-film catalysts. Built by ILS in Adlershof, it has now been delivered. The facility consists of a total of eight chemical reactors in which catalytic systems can be tested. At over €2.5 million, this is the largest single investment in the CatLab project.

Researchers from the Helmholtz Zentrum Berlin (HZB) and the Fritz Haber Institute of the Max Planck Society (FHI) have uncovered how carbonate molecules affect the conversion of CO₂ into valuable fuels on gold electrocatalysts. Their findings reveal key molecular mechanisms in CO₂ electrocatalysis and hydrogen evolution, pointing to new strategies for improving energy efficiency and reaction selectivity.

Iron-nitrogen-carbon catalysts have the potential to replace the more expensive platinum catalysts currently used in fuel cells. This is shown by a study conducted by researchers from the Helmholtz-Zentrum Berlin (HZB), Physikalisch-Technische Bundesanstalt (PTB) and universities in Tartu and Tallinn, Estonia. At BESSY II, the team observed the formation of complex microstructures within various samples. They then analysed which structural parameters were particularly important for fostering the preferred electrochemical reactions. The raw material for such catalysts is well decomposed peat.

Hybrid electrocatalysts can produce green hydrogen, for example, and valuable organic compounds simultaneously. This promises economically viable applications. However, the complex catalytic reactions involved in producing organic compounds are not yet fully understood. Modern X-ray methods at synchrotron sources such as BESSY II, enable catalyst materials and the reactions occurring on their surfaces to be analysed in real time, in situ and under real operating conditions. This provides insights that can be used for targeted optimisation. A team has now published an overview of the current state of knowledge in Nature Reviews Chemistry.

The Ministry of Science and Technology, Government of India, has announced the recipients of the Vaishvik Bhartiya Vaigyanik (VAIBHAV) Fellowship, a flagship initiative aimed at fostering collaboration between the Indian STEMM (Science, Technology, Engineering, Mathematics, and Medicine) diaspora and leading research institutions in India. Among the 2025 awardees is Dr. Prashanth W. Menezes, Head of the Department of Materials Chemistry for Catalysis at Helmholtz-Zentrum Berlin (HZB).

Sasol Research & Technology and Helmholtz Zentrum Berlin (HZB) are expanding their partnership into the realm of digitalisation, building on their joint efforts in the CARE-O-SENE project and an Industrial Fellowship launched earlier this year. This new initiative marks a significant step forward in leveraging digital technologies to accelerate catalyst innovation and deepen scientific collaboration.

A team led by Prof. Yan Lu, HZB, and Prof. Arne Thomas, Technical University of Berlin, has developed a material that enhances the capacity and stability of lithium-sulphur batteries. The material is based on polymers that form a framework with open pores (known as radical-cationic covalent organic frameworks or COFs). Catalytically accelerated reactions take place in these pores, firmly trapping polysulphides, which would shorten the battery life. Some of the experimental analyses were conducted at the BAMline at BESSY II.

Using a combination of spectromicroscopy at BESSY II and microscopic analyses at DESY's NanoLab, a team has gained new insights into the chemical behaviour of nanocatalysts during catalysis. The nanoparticles consisted of a platinum core with a rhodium shell. This configuration allows a better understanding of structural changes in, for example, rhodium-platinum catalysts for emission control. The results show that under typical catalytic conditions, some of the rhodium in the shell can diffuse into the interior of the nanoparticles. However, most of it remains on the surface and oxidises. This process is strongly dependent on the surface orientation of the nanoparticle facets.

Metal oxides are abundant in nature and central to technologies such as photocatalysis and photovoltaics. Yet, many suffer from poor electrical conduction, caused by strong repulsion between electrons in neighboring metal atoms. Researchers at HZB and partner institutions have shown that light pulses can temporarily weaken these repulsive forces, lowering the energy required for electrons mobility, inducing a metal-like behavior. This discovery offers a new way to manipulate material properties with light, with high potential to more efficient light-based devices.

In June and July 2025, catalyst researcher Nico Fischer spent some time at HZB. It was his sabbatical, he was relieved of his duties as Director of the Catalysis Institute in Cape Town for several months and was able to focus on research only. His institute is collaborating with HZB on two projects that aim to develop environmentally friendly alternatives using innovative catalyst technologies. The questions were asked by Antonia Rötger, HZB.

Hydrogen will play an important role, both as a fuel and as a raw material for industry. However, in order to produce relevant quantities of hydrogen, water electrolysis must become feasible on a multi-gigawatt scale. One bottleneck is the catalysts required, with iridium in particular being an extremely rare element. An international collaboration has therefore investigated iridium-free catalysts for acidic water electrolysis based on the element cobalt. Through investigations with various methods, among them experiments at the LiXEdrom at the BESSY II X-ray source in Berlin, they were able to elucidate processes that take place during water electrolysis in a cobalt-iron-lead oxide material as the anode. The study is published in Nature Energy.

MXenes are adept at hosting catalytically active particles. This property can be exploited to create more potent catalyst materials that significantly accelerate and enhance the oxygen evolution reaction, which is one of the bottlenecks in the production of green hydrogen via electrolysis using solar or wind power. A detailed study by an international team led by HZB chemist Michelle Browne shows the potential of these new materials for future large-scale applications. The study is published in Advanced Functional Materials.

The South African chemist Denzil Moodley is the first Industrial Research Fellow at HZB. He is playing a leading role in the CARE-O-SENE project. The Fellowship program aims to further accelerate the development of an efficient catalyst for a sustainable aviation fuel. An interview about the CARE-O-SENE project and why it is so important for scientists from industry and public research to work together.

A new instrument is now available at BESSY II for investigating catalyst materials, battery electrodes and other energy devices under operating conditions: the Operando Absorption and Emission Spectroscopy on EMIL (OÆSE) endstation in the Energy Materials In-situ Laboratory Berlin (EMIL). A team led by Raul Garcia-Diez and Marcus Bär showcases the instrument’s capabilities via a proof-of-concept study on electrodeposited copper.

Clathrates are characterised by a complex cage structure that provides space for guest ions too. Now, for the first time, a team has investigated the suitability of clathrates as catalysts for electrolytic hydrogen production with impressive results: the clathrate sample was even more efficient and robust than currently used nickel-based catalysts. They also found a reason for this enhanced performance. Measurements at BESSY II showed that the clathrates undergo structural changes during the catalytic reaction: the three-dimensional cage structure decays into ultra-thin nanosheets that allow maximum contact with active catalytic centres. The study has been published in the journal ‘Angewandte Chemie’.

Contrary to what we learned at school, some catalysts do change during the reaction: for example, certain electrocatalysts can change their structure and composition during the reaction when an electric field is applied. The X-ray microscope TXM at BESSY II in Berlin is a unique tool for studying such changes in detail. The results help to develop innovative catalysts for a wide range of applications. One example was recently published in Nature Materials. It involved the synthesis of ammonia from waste nitrates.

Dr. Moses Alfred Oladele is working on photocatalysis for CO₂ conversion in a joint project with the group of Dr. Matt Mayer, HZB, and Prof. Andreas Taubert at the University of Potsdam. The chemist from Redeemer's University in Ede, Nigeria, came to Berlin in the summer of 2024 with a Georg Forster Research Fellowship from the Alexander von Humboldt Foundation and will work at HZB for two years.

Michelle Browne heads a Helmholtz Young Investigators Group on electrocatalysis at HZB. She has now been selected as a fellow of the Daimler and Benz Foundation. She will receive 40,000 euros over the next two years and, in addition, access to an excellent research network.

In a small manganese oxide cluster, teams from HZB and HU Berlin have discovered a particularly exciting compound: two high spin manganese centres in two very different oxidation states and. This complex is the simplest model of a catalyst that occurs as a slightly larger cluster in natural photosynthesis, where it enables the formation of molecular oxygen. The discovery is considered an important step towards a complete understanding of photosynthesis.

Within the CARE-O-SENE project, HZB is cooperating with the South African company Sasol on innovative catalysts for sustainable aviation fuels (SAF). Now, the collaboration is intensifying: Dr. Denzil Moodley, a leading scientist in the field of Fischer-Tropsch at Sasol Research and Technology, is being appointed as Industrial Research Fellow at HZB. Moodley will contribute his expertise at HZB with the aim of accelerating the innovation cycle for sustainable fuel technologies.

A novel catalyst platform, known as Laterally Condensed Catalysts (LCC), has been developed to enable design and analysis of the functional interface connecting the active mass to its support. This interface not only influences the chemical properties of the reactive interface but also controls its stability and hence the sustainability of the catalytic materials. The development was significantly supported by the use of operando spectroscopy at the BESSY II synchrotron, which made it possible to observe and understand the dynamic processes and structures under reaction conditions.

The development of efficient catalysts for the Oxygen Evolution Reaction (OER) is crucial for advancing Proton Exchange Membrane (PEM) water electrolysis, with iridium-based OER catalysts showing promise despite the challenges related to their dissolution. Collaborative research by the Helmholtz-Zentrum Berlin für Materialien und Energie GmbH and the Fritz-Haber-Institut has provided insights into the mechanisms of OER performance and iridium dissolution for amorphous hydrous iridium oxides, advancing the understanding of this critical process.

Iridium-based catalysts are needed to produce hydrogen using water electrolysis. Now, a team at HZB has shown that the newly developed P2X catalyst, which requires only a quarter of the Iridium, is as efficient and stable over time as the best commercial catalyst. Measurements at the EMIL lab at BESSY II have now revealed how the special chemical environment in the P2X catalyst during electrolysis promotes the oxygen evolution reaction during water splitting.

A team from the Technical University of Berlin, HZB, IMTEK (University of Freiburg) and Siemens Energy has developed a highly efficient alkaline membrane electrolyser that approaches the performance of established PEM electrolysers. What makes this achievement remarkable is the use of inexpensive nickel compounds for the anode catalyst, replacing costly and rare iridium. At BESSY II, the team was able to elucidate the catalytic processes in detail using operando measurements, and a theory team (USA, Singapore) provided a consistent molecular description. In Freiburg, prototype cells were built using a new coating process and tested in operation. The results have been published in the prestigious journal Nature Catalysis.

The MXene class of materials has many talents. An international team led by HZB chemist Michelle Browne has now demonstrated that MXenes, properly functionalised, are excellent catalysts for the oxygen evolution reaction in electrolytic water splitting. They are more stable and efficient than the best metal oxide catalysts currently available. The team is now extensively characterising these MXene catalysts for water splitting at the Berlin X-ray source BESSY II and Soleil Synchrotron in France.

At first glance, the plan sounds compelling: invent and develop future electrolysers capable of producing hydrogen directly from unpurified seawater. But a closer look reveals that such direct seawater electrolysers would require years of high-end research. And what is more: DSE electrolyzers are not even necessary - a simple desalination process is sufficient to prepare seawater for conventional electrolyzers. In a commentary in Joule, international experts compare the costs and benefits of the different approaches and come to a clear recommendation.

In his search for the perfect catalyst, HZB researcher Robert Seidel is now getting a tailwind – thanks to a ERC Consolidator Grant. In the cover story, we explain why the X-ray source BESSY II plays an important role for his research.

An international research team has succeeded in observing an intermediate step in the catalysis of alkanes. By understanding these reactions, existing catalysts can be optimized in the future and new ones found, for example to convert the greenhouse gas methane into valuable raw materials for industry.

A team of researchers in Berlin has developed a laboratory spectrometer for analysing chemical processes in solution - with a time resolution of 500 ps. This is of interest not only for the study of molecular processes in biology, but also for the development of new catalyst materials. Until now, however, this usually required synchrotron radiation, which is only available at large, modern X-ray sources such as BESSY II. The process now works on a laboratory scale using a plasma light source.

Indium phosphide is a versatile semiconductor. The material can be used for solar cells, for hydrogen production and even for quantum computers – and with record-breaking efficiency. However, little research has been conducted into what happens on its surface. Researchers have now closed this gap and used ultra-fast lasers to scrutinise the dynamics of the electrons in the material.

Freeze casting is an elegant, cost-effective manufacturing technique to produce highly porous materials with custom-designed hierarchical architectures, well-defined pore orientation, and multifunctional surface structures. Freeze-cast materials are suitable for many applications, from biomedicine to environmental engineering and energy technologies. An article in "Nature Reviews Methods Primer" now provides a guide to freeze-casting methods that includes an overview on current and future applications and highlights characterization techniques with a focus on X-ray tomoscopy.

The interactions between phosphoric acid and the platinum catalyst in high-temperature PEM fuel cells are more complex than previously assumed. Experiments at BESSY II with tender X-rays have decoded the multiple oxidation processes at the platinum-electrolyte interface. The results indicate that variations in humidity can influence some of these processes in order to increase the lifetime and efficiency of fuel cells. 

At the end of February 2024, a team at HZB published an article in Synchrotron Radiation News (SRN). They describe the next development goals for the light source as well as the BESSY II+ upgrade programme and the successor source BESSY III.

Physicist Dr Robert Seidel has been awarded a Consolidator Grant by the European Research Council (ERC). Over the next five years, he will receive a total of two million euros for his research project WATER-X. Seidel will use state-of-the-art X-ray techniques at BESSY II to study nanoparticles in aqueous solution for the photocatalytic production of "green" hydrogen.

The production of green hydrogen requires catalysts that control the process of splitting water into oxygen and hydrogen. However, the structure of the catalyst changes under electrical tension, which also influences the catalytic activity. A team from the universities of Duisburg-Essen and Twente has investigated at BESSY II and elsewhere how the transformation of surfaces in perovskite oxide catalysts controls the activity of the oxygen evolution reaction. 

Anodes for the electrolytic splitting of water are usually iridium-based materials. In order to increase the stability of the iridium catalyst, a team at HZB and a group at HI-ERN have now produced a so-called material library: a sample in which the concentration of iridium and titanium oxides is systematically varied. Analyses of the individual sample segments at BESSY II in the EMIL laboratory showed that the presence of titanium oxides can increase the stability of the iridium catalyst significantly.

It already works: there are several approaches to using solar energy to split water and produce hydrogen. Unfortunately, this green hydrogen has so far been more expensive than grey hydrogen from natural gas. A study by Helmholtz-Zentrum Berlin (HZB) and Technische Universität Berlin now shows how green hydrogen from sunlight can become profitable.

It sounds like magic: photoelectrodes could convert the greenhouse gas CO₂ back into methanol or N2 molecules into valuable fertiliser – using only the energy of sunlight. An HZB study has now shown that diamond materials are in principle suitable for such photoelectrodes. By combining X-ray spectroscopic techniques at BESSY II with other measurement methods, Tristan Petit’s team has succeeded for the first time in precisely tracking which processes are excited by light as well as the crucial role of the surface of the diamond materials.

In April, Dr. Jie Wei started his research work in the Helmholtz Young Investigator Group Nanoscale Operando CO₂ Photo-Electrocatalysis at Helmholtz-Zentrum Berlin (HZB) and Fritz Haber Institute (FHI) of the Max Planck Society. Wei received one of the highly competitive Humboldt postdoctoral research fellowships and will pursue his two-year project under the guidance of the academic hosts Dr. Christopher Kley and Prof. Dr. Beatriz Roldan Cuenya.

The greenhouse gas carbon dioxide can be converted into useful hydrocarbons by electrolysis. The design of the electrolysis cell is crucial in this process. The so-called zero-gap cell is particularly suitable for industrial processes. But there are still problems: The cathodes clog up quickly. At the HZB, Matthew Mayer and his team has now investigated what causes this and how this undesirable process can be prevented.

Sunlight can be used to produce green hydrogen directly from water in photoelectrochemical (PEC) cells. So far, systems based on this "direct approach" have not been energetically competitive. However, the balance changes as soon as some of the hydrogen in such PEC cells is used in-situ for a catalytic hydrogenation reaction, resulting in the co-production of chemicals used in the chemical and pharmaceutical industries. The energy payback time of photoelectrochemical "green" hydrogen production can be reduced dramatically, the study shows.

A further development in atomic force microscopy now makes it possible to simultaneously image the height profile of nanometre-fine structures as well as the electric current and the frictional force at solid-liquid interfaces. A team from the Helmholtz-Zentrum Berlin (HZB) and the Fritz Haber Institute (FHI) of the Max Planck Society has succeeded in analysing electrocatalytically active materials and gaining insights that will help optimise catalysts. The method is also potentially suitable for studying processes on battery electrodes, in photocatalysis or on active biomaterials.

For the past two years, Dr Renske van der Veen has led a research group in time-resolved X-ray spectroscopy and electron microscopy at HZB. Her research focuses on catalytic processes that enable, for example, the production of green hydrogen. She has now been appointed to a S-W2 professorship at the Institute of Optics and Atomic Physics (IOAP) at the Technische Universität Berlin.

A team led by Dr. Prashanth W. Menezes (HZB/TU-Berlin) has now gained insights into the chemistry of one of the most active anode catalysts for green hydrogen production. They examined a series of Cobalt-Iron Oxyhydroxides at BESSY II and were able to determine the oxidation states of the active elements in different configurations as well as to unveil the geometrical structure of the active sites. Their results might contribute to the knowledge based design of new highly efficient and low cost catalytical active materials.

Water not only has some well-known anomalies, but is still full of surprises. The first issue 2023 of the Bunsen Magazine is dedicated to molecular water research, from the ocean to processes in electrolysis. The issue presents contributions from researchers cooperating within the framework of a European research initiative in the "Centre for Molecular Water Science" (CMWS). A team at HZB presents results from the synchrotron spectroscopy of water. Modern X-ray sources can be used to study molecular and electronic processes in water in detail.

Nanodiamond materials have potential as low-cost photocatalysts. But until now, such carbon nanoparticles required high-energy UV light to become active. The DIACAT consortium has therefore produced and analysed variations of nanodiamond materials. The work shows: If the surface of the nanoparticles is occupied by sufficient hydrogen atoms, even the weaker energy of blue sunlight is sufficient for excitation. Future photocatalysts based on nanodiamonds might be able to convert CO₂ or N₂ into hydrocarbons or ammonia with sunlight.

Until now, it has been extremely tedious to perform measurements with high sensitivity and high spatial resolution using X-ray light in the tender energy range of 1.5 - 5.0 keV. Yet this X-ray light is ideal for investigating energy materials such as batteries or catalysts, but also biological systems. A team from HZB has now solved this problem: The newly developed monochromator optics increase the photon flux in the tender energy range by a factor of 100 and thus enable highly precise measurements of nanostructured systems. The method was successfully tested for the first time on catalytically active nanoparticles and microchips.

Quantum computers promise significantly shorter computing times for complex problems. But there are still only a few quantum computers worldwide with a limited number of so-called qubits. However, quantum computer algorithms can already run on conventional servers that simulate a quantum computer. A team at HZB has succeeded to calculate the electron orbitals and their dynamic development on the example of a small molecule after a laser pulse excitation. In principle, the method is also suitable for investigating larger molecules that cannot be calculated using conventional methods.

Photoelectrodes based on BiVO₄ are considered top candidates for solar hydrogen production. But what exactly happens when they come into contact with water molecules? A study in the Journal of the American Chemical Society has now partially answered this crucial question:  Excess electrons from dopants or defects aid the dissociation of water which in turn stabilizes so-called polarons at the surface. This is shown by data from experiments conducted at the Advanced Light Source at Lawrence Berkeley National Laboratory. These insights might foster a knowledge-based design of better photoanodes for green hydrogen production.

Certain metal oxides are considered good candidates for photocatalysts to produce green hydrogen with sunlight. A Chinese team has now published exciting results on copper(I) oxide particles in Nature, to which a method developed at HZB contributed significantly. Transient surface photovoltage spectroscopy showed that positive charge carriers on surfaces are trapped by defects in the course of microseconds. The results provide clues to increase the efficiency of photocatalysts.

In the research consortium CARE-O-SENE, scientists are looking for more efficient ways to produce synthetic kerosene for use in aviation. We interviewed Tobias Sontheimer of HZB and Dirk Schär of the participating company Sasol about what has to be done, what obstacles there are, and how aviation can be decarbonised.

The international research project CARE-O-SENE (Catalyst Research for Sustainable Kerosene) was granted 30 million euros in funding by the German Federal Ministry of Education and Research (BMBF). Additionally, the industrial consortium partners contribute 10 million euros. The aim of the project is to develop novel, next-generation Fischer-Tropsch catalysts and thus to optimise the production of sustainable kerosene – or Sustainable Aviation Fuel (SAF) – on an industrial scale. Helmholtz-Zentrum Berlin (HZB) is part of this collaboration.

In order to produce green hydrogen, water can be split up via electrocatalysis, powered by renewable sources such as sun or wind. A review article in the journal Angewandte Chemie Int. Ed. shows how modern X-ray sources such as BESSY II can advance the development of suitable electrocatalysts. In particular, X-ray absorption spectroscopy can be used to determine the active states of catalytically active materials for the oxygen evolution reaction. This is an important contribution to developing efficient catalysts from inexpensive and widely available elements.

Transition metals have many applications in engineering, electrochemistry and catalysis. To understand their properties, the interplay between atomic localisation and delocalisation of the outer electrons in the d orbitals is crucial. This insight is now provided by a special end station at BESSY II with highest precision, as demonstrated by a study of copper, nickel and cobalt with interesting quantitative results. The Royal Society of Chemistry has selected the paper as a HOT Article 2022.

Press release _ Berlin, 14 September: For decades, science in Berlin has been an important driver of innovation and progress. Creative, talented people from all over the world come together here and develop new ideas from which we all benefit as a society. Many discoveries – from fundamental insights to marketable products – are made by doing research with synchrotron light. Researchers have had access to this intense light in Berlin for 40 years. It inspires many scientific disciplines and is an advantage for Germany.

Thin films of molybdenum and sulfur belong to a class of materials that can be considered for use as photocatalysts. Inexpensive catalysts such as these are needed to produce hydrogen as a fuel using solar energy. However, they are still not very efficient as catalysts. A new instrument at the Helmholtz-Berlin Zentrum’s BESSY II now shows how a light pulse alters the surface properties of the thin film and activates the material as a catalyst.

Helmholtz-Zentrum Berlin (HZB) and Humboldt-Universität zu Berlin (HU) have signed a cooperation agreement with the aim of establishing a joint research laboratory for catalysis in the IRIS research building of HU in Adlershof. The IRIS research building offers optimal conditions for the research and development of complex material systems.

An innovative laboratory and office building for catalysis research will be built in Berlin-Adlershof: CatLab is to become an international beacon for catalysis research and drive forward the development of novel catalyst materials, which are urgently required for the production of green hydrogen for the energy transition. In an architectural competition four winning designs have now been selected. All designs include climate friendly solutions.