Russina, O.; Beiner, M.; Pappas, C.; Russina, M.; Arrighi, V.; Unruh, T.; Mullan, C.L.; Hardacre, C.; Triolo, A.: Temperature Dependence of the Primary Relaxation in 1-Hexyl-3-methylimidazolium bis{(trifluoromethyl)sulfonyl}imide. The Journal of Physical Chemistry B 113 (2009), p. 8469-8474
10.1021/jp900142m
Abstract:
We present results from complementary characterizations of the primary relaxation rate of a room temperature ionic liquid (RTIL), 1-hexyl-3-methylimidazolium is{(trifluoromethyl)sulfonyl} imide, [C6mim][Tf2N], over a wide temperature range. This extensive data set is successfully merged with existing literature data for conductivity, viscosity, and NMR diffusion coefficients thus providing, for the case of RTILs, a unique description of the primary process relaxation map over more than 12 decades in relaxation rate and between 185 and 430 K. This unique data set allows a detailed characterization of the VTF parameters for the primary process, that are: B ) 890 K, T0 ) 155.2 K, leading to a fragility index m ) 71, corresponding to an intermediate fragility. For the first time neutron spin echo data from a fully deuteriated sample of RTIL at the two main interference peaks, Q ) 0.76 and 1.4 Å-1 are presented. At high temperature (T > 250 K), the collective structural relaxation rate follows the viscosity behavior; however at lower temperatures it deviates from the viscosity behavior, indicating the existence of a faster process.